Desalination by Membrane Distillation using Electrospun Polyamide Fiber Membranes with Surface Fluorination by Chemical Vapor Deposition

Fibrous membranes of poly(trimethyl hexamethylene terephthalamide) (PA6(3)T) were fabricated by electrospinning and rendered hydrophobic by applying a conformal coating of poly(1H,1H,2H,2H-perfluorodecyl acrylate) (PPFDA) using initiated chemical vapor deposition (iCVD). A set of iCVD-treated electrospun PA6(3)T fiber membranes with fiber diameters ranging from 0.25 to 1.8 μm were tested for desalination using the air gap membrane distillation configuration. Permeate fluxes of 2–11 kg/m²/h were observed for temperature differentials of 20–45 °C between the feed stream and condenser plate, with rejections in excess of 99.98%. The liquid entry pressure was observed to increase dramatically, from 15 to 373 kPa with reduction in fiber diameter. Contrary to expectation, for a given feed temperature the permeate flux was observed to increase for membranes of decreasing fiber diameter. The results for permeate flux and salt rejection show that it is possible to construct membranes for membrane distillation even from intrinsically hydrophilic materials after surface modification by iCVD and that the fiber diameter is shown to play an important role on the membrane distillation performance in terms of permeate flux, salt rejection, and liquid entry pressure

Modeling and implementation of solder-activated joints for single actuator, centimeter-scale robotic mechanisms

Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, 2010.Cataloged from PDF version of thesis.Includes bibliographical references (p. 139-140).This thesis explains when, and why, solder-based phase change materials (PCMs) are best-suited as a means to modify a robotic mechanism's kinematic and elastomechanic behavior. The preceding refers to mechanisms that possess joints which may be thermally locked and unlocked via a material phase change within the joint. Different combinations of locked and unlocked joints yield different one-DOF mechanisms states. A single actuator is used to control motion allowed by the different states. By reducing the number of required actuators, solderlocking joints enable the creation of compliant centimeter-scale mechanisms that can perform a multiplicity of tasks. Herein, this thesis presents physics-based design insights that provide understanding of how solder-based material properties and joint design dominate joint performance characteristics. First order models are used to demonstrate selection of suitable PCMs and how to set initial joint geometry prior to fine tuning via detailed FEA models and experiments. The first order models result in order-of-magnitude estimates of the locking and unlocking times for the joints. The insights and models are discussed in the context of two case studies. Squishbot1 is a crawling robot that uses a single spooler motor and three solder-locking joints to crawl and steer. Squishbot 1 is able to reconfigure its joints in approximately 10 seconds. SquishTendons utilizes solder-locking joints to actuate a compliant structure with a single motor. The second robot used the complete set of models and rules to improve on the performance of Squishbotl. SquishTendons can unlock and lock its joints in less than 6 seconds.by Maria J. Telleria.S.M

The Combined Effect of Air Layers and Membrane Superhydrophobicity on Biofouling in Membrane Distillation

Previous studies of membrane distillation (MD) have shown that superhydrophobic membranes experience dramatically less inorganic and particulate fouling. However, little explanation for this improved performance has been given in the literature. Furthermore, studies comparing membrane superhydrophobicity and biofouling are lacking, though superhydrophobic surfaces are known to be more vulnerable to biofouling than other types. In non-membrane surfaces, visible air layers on superhydrophobic surfaces have been correlated with significant decreases in biofouling. Therefore, it was proposed here to use superhydrophobic MD membranes with periodic introduction of air to maintain an air layer on the membrane surface. Superhydrophobic membranes were created with initiated chemical vapor deposition (iCVD) of a fluorinated compound, perfluorodecyl acrylate (PFDA). The substrate membrane was PVDF. To test MD fouling, an MD membrane was placed on top of a fouling solution, with a heater and stirrer to caus e evaporation of water through the membrane. Results were analyzed with foulant mass measurements. Alginate gel fouling was examined, as this compound is a common proxy for biological fouling in ocean w ater. The introduction of air layers was found to dramatically decrease foulant adhesion to the membrane, by 95-97%. Membrane superhydrophobicity made a much smaller impact in reducing fouling. Keywords membrane distillation, superhydrophobic surfaces, alginate, air layers, anti-foulin

The effects of iCVD film thickness and conformality on the permeability and wetting of MD membranes

Membranes possessing high permeability to water vapor and high liquid entry pressure (LEP) are necessary for efficient membrane distillation (MD) desalination. A common technique to prepare specialized MD membranes consists of coating a hydrophilic or hydrophobic base membrane with a low surface-energy material. This increases its liquid entry pressure, making the membrane suitable for MD. However, in addition to increasing LEP, the surface-coating may also decrease permeability of the membrane by reducing its average pore size. In this study, we quantify the effects of initiated chemical vapor deposition (iCVD) polymer coatings on membrane permeability and LEP. We consider whether the iCVD films should have minimized thickness or maximized non-conformality, in order to maximize the permeability achieved for a given value of LEP. We determined theoretically that permeability of a single pore is maximized with a highly non-conformal iCVD coating. However, the overall permeability of a membrane consisting of many pores is maximized when iCVD film thickness is minimized. We applied the findings experimentally, preparing an iCVD-treated track-etched polycarbonate (PCTE) membrane and testing it in a permeate gap membrane distillation (PCMD) system. This study focuses on membranes with clearly defined, cylindrical pores. However, we believe that the principles we discuss will extend to membranes with more complex pore architectures. Overall, this work indicates that the focus of surface-coating development should be on minimizing film thickness, not on increasing their non-conformality.MIT & Masdar Institute Cooperative Program (02/MI/MI/CP/11/07633/GEN/G/00)Massachusetts Institute of Technology. Institute for Soldier Nanotechnologies (W911NF-13-d-0001

Reversing membrane wetting in membrane distillation: comparing dryout to backwashing with pressurized air

The critical failure mode for membrane distillation (MD) desalination is wetting through the pores of the hydrophobic membrane, which allows the saline solution to leak through and contaminate the permeate. The standard practice for reversing membrane wetting is to dry out the membrane for several hours before resuming the desalination process. An alternative method for mitigating MD membrane wetting is examined in this study, wherein pressurized air is pushed through the membrane from the permeate side for several seconds, forcing trapped water out before it can evaporate. To compare the wetting reversal methods, the liquid entry pressure (LEP) was surpassed with saline water at varied salinity. Then, either a 24+ hour dryout, a 10 second pressurized air treatment, or both were applied, followed by remeasuring the LEP. Pressurized air backwashing restored the LEP to 75% of the original value for lower salinity feeds. The backwashing method is hypothesized to achieve this superior result because it removes saline solution from the membrane without separating water and salts by vaporization, whereas the dryout method causes seawater within the membrane to evaporate, leaving crystalline solutes trapped within the membrane. Such trapped particles may act as a path for rewetting, and also impair permeate flux and system energy efficiency. For all three methods, membranes tested with higher salinity water had lower LEP restoration irrespective of the restoration technique used. A method for testing LEP with more accuracy was also developed, using stepwise pressure increases. SEM images showed that the restoration methods did not alter the membranes themselves, although there remains a possibility that the air backwashing can cause superficial tears. Keywords: membrane distillation, wetting, dryout, air backwash, cleaning, crystallizationMIT Masdar Program (Reference 02/MI/MI/CP/11/07633/GEN/G/00

Combining air recharging and membrane superhydrophobicity for fouling prevention in membrane distillation

In previous studies of the desalination technology membrane distillation (MD), superhydrophobicity of the membrane has been shown to dramatically decrease fouling in adverse conditions, but the mechanism for this is not well understood. Additionally, air layers present on submerged solid superhydrophobic surfaces have been shown to dramatically reduce biofouling, and air-bubbling has been used to reducing fouling and increase flux and efficiency in MD. The present work studies the effect of maintaining air layers on the membrane surface and superhydrophobicity as a new method for preventing fouling of MD membranes by salts, particulates, and organic particles. Superhydrophobic MD membranes were prepared using initiated chemical vapor deposition (iCVD) of perfluorodecyl acrylate (PFDA) on poly(vinyldene fluoride) PVDF membranes and used to study the effects of surface energy on fouling. A static MD setup with evaporation through an MD membrane but no condensing of permeate was used to examine the effect of air exposure on fouling, by measuring the increase in weight of the membrane caused by scale deposition. Theory was derived for the reduction of fouling on superhydrophobic surfaces, and a review of related theory was included. Air layers may displace fouling gels, reduce the area of feed in contact with the membrane, reduce foulant adhesion, and enhance superhydrophobicity in a Cassie–Baxter state. The study shows that the presence of air on the membrane surface significantly reduces biological fouling, but in some cases had mildly exacerbating effects by increasing crystal formation of salts, especially when the air was not saturated with water vapor. Air recharging combined with superhydrophobicity reduced fouling in several cases where hydrophobic membranes alone did little.National Science Foundation (U.S.). Materials Research Science and Engineering Centers (Program) (DMR-1120296)Masdar Institute of Science and Technology/MIT/UAE (Cooperative agreement, Reference no.02/MI/MI/ CP/11/07633/GEN/G/00