38 research outputs found
Optical Sensors Based on Single Arm Thin Film Waveguide Interferometer
All the goals of the research effort for the first year were met by the accomplishments. Additional efforts were done to speed up the process of development and construction of the experimental gas chamber which will be completed by the end of 1997. This chamber incorporates vacuum sealed multimode optical fiber lines which connect the sensor to the remote light source and signal processing equipment. This optical fiber line is a prototype of actual optical communication links connecting real sensors to a control unit within an aircraft or spacecraft. An important problem which we are planning to focus on during the second year is coupling of optical fiber line to the sensor. Currently this problem is solved using focusing optics and prism couplers. More reliable solutions are planned to be investigated
Optical Sensors based on single arm thin film Waveguide Interferometer
The second achievement meets the second objective for the second year. We choose adjustable prism couplers for connecting the sensor to optical fiber lines in our design of a breadboard prototype of the sensor. These couplers have good coupling efficiency at relatively low cost comparing to any other alternatives such as grating couplers. The third accomplishment meets the third objective for the second year. We performed testing the breadboard prototype of the sensor using heating as a technique of changing its refractive index. The only difference is that we ruled out the channel waveguides as irrelevant to the final goals of the project. The feasibility of the sensor can be shown for the slab waveguide configuration without usage of relatively expensive technologies of channel waveguide delineation
Bimorphic polymeric photomechanical actuator
A bimorphic polymeric photomechanical actuator, in one embodiment using polyvinylidene fluoride (PVDF) as a photosensitive body, transmitting light over fiber optic cables, and controlling the shape and pulse duration of the light pulse to control movement of the actuator. Multiple light beams are utilized to generate different ranges of motion for the actuator from a single photomechanical body and alternative designs use multiple light beams and multiple photomechanical bodies to provide controlled movement. Actuator movement using one or more ranges of motion is utilized to control motion to position an actuating element in three dimensional space
Dynamic refractometer
A refractometer computer controls the rotation of a rotary plate upon which are mounted a prism optically coupled via an optical window to a spectroscopic cell holding a resin exhibiting a dynamic refractive index during photocuring. The computer system positions the prism and spectroscopic cell relative to a visible light laser which illuminates the prism-resin interface at selected incidence angles. A photodetector mounted on the plate generates a signal to the computer proportional to intensity of an internally reflected light beam. A curing light is selectively transmitted through the prism and into the photocurable resin. The refractometer determines the intensity of the internally reflected beam a selected incidence angles and determines the effective refractive index curve of the resin at an uncured state and, optionally, at a completely cured state. Next, an amount of uncured resin and selected optical components to be joined by the resin is placed in the spectroscopic cell and irradiated with the UV light. The refractometer is fixed at a selected incidence angle and measures the intensity of an internally reflected light beam of light throughout the cure cycle. The refractometer determines the resin's refractive index of the polymeric mixture by means of extrapolation of a horizontal shift in the effective refractive index curve of the resin from an uncured state to a selected point in the cure cycle
Single-wall carbon nanotubes oriented by gas flow at synthesis by aerosol CVD method as terahertz polarizers
Light-Driven Polymeric Bimorph Actuators
Light-driven polymeric bimorph actuators are being developed as alternatives to prior electrically and optically driven actuators in advanced, highly miniaturized devices and systems exemplified by microelectromechanical systems (MEMS), micro-electro-optical-mechanical systems (MEOMS), and sensor and actuator arrays in smart structures. These light-driven polymeric bimorph actuators are intended to satisfy a need for actuators that (1) in comparison with the prior actuators, are simpler and less power-hungry; (2) can be driven by low-power visible or mid-infrared light delivered through conventional optic fibers; and (3) are suitable for integration with optical sensors and multiple actuators of the same or different type. The immediate predecessors of the present light-driven polymeric bimorph actuators are bimorph actuators that exploit a photorestrictive effect in lead lanthanum zirconate titanate (PLZT) ceramics. The disadvantages of the PLZT-based actuators are that (1) it is difficult to shape the PLZT ceramics, which are hard and brittle; (2) for actuation, it is necessary to use ultraviolet light (wavelengths < 380 nm), which must be generated by use of high-power, high-pressure arc lamps or lasers; (3) it is difficult to deliver sufficient ultraviolet light through conventional optical fibers because of significant losses in the fibers; (4) the response times of the PLZT actuators are of the order of several seconds unacceptably long for typical applications; and (5) the maximum mechanical displacements of the PLZT-based actuators are limited to those characterized by low strains beyond which PLZT ceramics disintegrate because of their brittleness. The basic element of a light-driven bimorph actuator of the present developmental type is a cantilever beam comprising two layers, at least one of which is a polymer that exhibits a photomechanical effect (see figure). The dominant mechanism of the photomechanical effect is a photothermal one: absorption of light energy causes heating, which, in turn, causes thermal expansion
Concurrent Multi-Target Laser Ablation for Making Nano-Composite Films
New method of using laser ablation for film deposition that can be called as concurrent multi-beam multi-target matrix-assisted pulsed laser evaporation and pulsed laser deposition (MBMT-MAPLE/PLD) is described. Practical MBMT-MAPLE/PLD system built at Dillard University has three separate laser beams, three targets and the remotely controlled plume overlapping mechanism that provides even mixing of the target materials during their deposition on the substrate. The system accommodates MAPLE targets in the form of polymer solutions frozen with flowing liquid nitrogen. The feasibility of the method was demonstrated when it was used for making polymer nano-composite films with two inorganic additives: upconversion fluorescent phosphor NaYF4:Yb3+, Er3+ and aluminum-doped ZnO (AZO). Three laser beams, an infrared 1064-nm beam for the MAPLE and two 532-nm beams for the PLD targets, were concurrently used in the process. The fabricated nano-composite films were characterized using X-ray diffraction, scanning electron microscopy (SEM), optical fluorescent spectroscopy, and the measurement of the quantum efficiency (QE) of the upconversion fluorescence. The size of the inorganic nanoparticles varied in the range 10–200 nm. The AZO additive increased QE by 1.6 times. The conclusion was made on the feasibility of MBMT-MAPLE/PLD method for making multi-component nano-composite films for various applications
Multi-Beam Multi-Target Pulsed Laser Deposition of AZO Films with Polymer Nanoparticles for Thermoelectric Energy Harvesters
In comparison with metallic thermoelectric films, oxide films with artificial nanodefects have been seldom studied. And there has been no report on the incorporation of island-shaped organic nanoparticles. We describe a new approach to introduce nanometer-sized phonon scatterers in aluminum-doped ZnO (AZO) thermoelectric thin films–concurrent multi-beam multi-target-pulsed laser deposition and the matrix-assisted pulsed laser evaporation (MBMT-PLD/MAPLE). The approach was used to make nanocomposite thin films of AZO matrix with evenly dispersed poly(methyl methacrylate) (PMMA) nanoparticles. The introduction of the nanoparticles enhanced phonon scattering with consequent decrease of thermal conductivity by 20%. The electrical conductivity did not decrease after the addition of the second phase, as it would be predicted by Wiedemann-Franz law, but improved by 350% over pure AZO film. The thermoelectric figure of merit of the nanocomposite film became twice that of the pure AZO film. Taking advantage of room-temperature deposition, optimized AZO nanocomposite films are expected to be used in real applications, such as thin film modules deposited on flexible polymeric substrates for ubiquitous harvesting of the waste heat
1-Benzyl-3,5-bis(4-chlorobenzylidene)piperidin-4-one
The title compound, C26H21Cl2NO, crystallizes with two symmetry-independent molecules (A and B) in the asymmetric unit. In both molecules, the central heterocyclic ring adopts a sofa conformation. The dihedral angles between the planar part of this central heterocyclic ring [maximum deviations of 0.011 (1) and 0.036 (1) Å in molecules A and B, respectively] and the two almost planar [maximum deviations of 0.020 (1) and 0.008 (1) Å in A and 0.007 (1) and 0.011 (1) in B] side-chain fragments that include the aromatic ring and bridging atoms are 20.1 (1) and 31.2 (1)° in molecule A, and 26.4 (1) and 19.6 (1)° in molecule B. The dihedral angles between the planar part of the heterocyclic ring and the benzyl substituent are 79.7 (1) and 53.2 (1)° in molecules A and B, respectively. In the crystal, weak intermolecular C—H⋯O hydrogen bonds link the two independent molecules into dimers