Optimisation method for automatic selection of rate constants of global reaction mechanisms

Optimisation approach to automate selection of global reaction mechanisms rate constants is proposed and studied. The objective of optimisation is to find reaction rate constants minimising deviation of some flame characteristics (e.g. laminar burning velocity, ignition delay time, etc.) calculated by global mechanism from their reference values known from experiments or computed by detailed mechanisms. Examples of one, two and four step mechanisms optimisation with respect to laminar burning velocity and concentration distributions in counterflow diffusion flame are given. Computer codes implementing optimisation algorithm for these examples are also afforded and can be modified and used for reaction constants selection in various applications. Uniqueness of singlecriteria and multicriteria optimisation solutions is studied numerically by computations with different initial guesses and by direct evaluation of the objective functions. Particularly, it is found that for considered global mechanisms the minimum value of objective function is reached in some subdomain of the parametric space. This means that any values of rate parameters from this subdomain results in almost the same deviations of chosen flame characteristic from its reference value.</p

The polymer–polymorphoid nature of glass aging process

Based on the concept of polymeric–polymorphous structure of glass and glass-forming liquid experimental data have been analyzed revealing the nature of glass aging. We show that the glass forming substance is a copolymer consisting of structural nano-fragments (polymorphoids) in different polymorphous modifications (PM) of the material having no translational symmetry (long-range order). The study revealed that the process and degree of glass aging influences the properties of glasses, including a change in enthalpy, manifested in the exothermic and endothermic effects observed in thermograms of differential scanning calorimetry of heated and cooled glasses. We have shown that the physicochemical essence of aging is the transformation of polymorphoids from high-temperature PM (HTPM) to low-temperature PM (LTPM) which results, under certain conditions, in LTPM crystallization

A multiwavelength analysis of a collection of short-duration GRBs observed between 2012 and 2015

We investigate the prompt emission and the afterglow properties of short-duration gamma-ray burst (sGRB) 130603B and another eight sGRB events during 2012-2015, observed by several multiwavelength facilities including the Gran Canarias Telescope 10.4 m telescope. Prompt emission high energy data of the events were obtained by INTEGRAL-SPI-ACS, Swift-BAT, and Fermi-GBM satellites. The prompt emission data by INTEGRAL in the energy range of 0.1-10 MeV for sGRB 130603B, sGRB 140606A, sGRB 140930B, sGRB 141212A, and sGRB 151228A do not show any signature of the extended emission or precursor activity and their spectral and temporal properties are similar to those seen in case of other short bursts. For sGRB 130603B, our new afterglow photometric data constrain the pre-jet-break temporal decay due to denser temporal coverage. For sGRB 130603B, the afterglow light curve, containing both our new and previously published photometric data is broadly consistent with the ISM afterglow model. Modeling of the host galaxies of sGRB 130603B and sGRB 141212A using the LePHARE software supports a scenario in which the environment of the burst is undergoing moderate star formation activity. From the inclusion of our late-time data for eight other sGRBs we are able to: place tight constraints on the non-detection of the afterglow, host galaxy, or any underlying 'kilonova' emission. Our late-time afterglow observations of the sGRB 170817A/GW170817 are also discussed and compared with the sub-set of sGRBs.© 2019 The Author(s) Published by Oxford University Press on behalf of the Royal Astronomical SocietyAJCT acknowledges support from the Junta de Andalucia (Project P07-TIC-03094) and support from the Spanish Ministry Projects AYA2012-39727-C03-01 and 201571718R. This work has been supported by the Spanish Science Ministry 'Centro de Excelencia SeveroOchoa' Program under grant SEV-2017-0709. FEDER funds are acknowledged. E.S. acknowledges assistance from the Scientific and Technological Research Council of Turkey (TUBITAK) through project 112T224. We thank TUBITAK for a partial support in using T100 telescope with project number 10CT100-95. A.S.P acknowledges partial support grants RFBR 17-02-01388, 17-51-44018, and 1752-80139. E.D.M., A.A.V., and P.Yu.M. are grateful to RSCF grant 18-12-00522 for support. B.-B.Z. acknowledges support from National Thousand Young Talents program of China and National Key Research and Development Program of China (2018YFA0404204). R.Ya.I. is grateful for partial support by the grant RUSTAVELI/FR/379/6-300/14. R.S.R. acknowledges support from ASI (Italian Space Agency) through the Contract No. 2015-046R.0 and from European Union Horizon 2020 Programme under the AHEAD project (grant agreement No. 654215). SJ acknowledges the support of the Korea Basic Science Research Program through NRF-2015R1D1A4A01020961.Peer Reviewe