AlGaAs/GaAs Quantum Well Infrared Photodetectors

In this article, we present an overview of a focal plane array (FPA) with 640 × 512 pixels based on the AlGaAs quantum well infrared photodetector (QWIP). The physical principles of the QWIP operation and their parameters for the spectral range of 8–10 μm have been discussed. The technology of the manufacturing FPA based on the QWIP structures with the pixels 384 × 288 and 640 × 512 has been demonstrated. The parameters of the manufactured 640 × 512 FPA with a step of 20 μm have been given. At the operating temperature of 72 K, the temperature resolution of QWIP focal plane arrays is less than 35 mK. The number of defective elements in the matrix does not exceed 0.5%. The stability and uniformity of the FPA have been demonstrated

Magnetic quantum ratchet effect in (Cd,Mn)Te- and CdTe-based quantum well structures with a lateral asymmetric superlattice

We report on the observation of magnetic quantum ratchet effect in (Cd, Mn) Te-and CdTe-based quantum well structures with an asymmetric lateral dual grating gate superlattice subjected to an external magnetic field applied normal to the quantum well plane. A dc electric current excited by cw terahertz laser radiation shows 1/B oscillations with an amplitude much larger as compared to the photocurrent at zero magnetic field. We show that the photocurrent is caused by the combined action of a spatially periodic in-plane potential and the spatially modulated radiation due to the near-field effects of light diffraction. Magnitude and direction of the photocurrent are determined by the degree of the lateral asymmetry controlled by the variation of voltages applied to the individual gates. The observed magneto-oscillations with enhanced photocurrent amplitude result from Landau quantization and, for (Cd, Mn) Te at low temperatures, from the exchange enhanced Zeeman splitting in diluted magnetic heterostructures. Theoretical analysis, considering the magnetic quantum ratchet effect in the framework of semiclassical approach, describes quite well the experimental results

Determination of smoldering time and thermal characteristics of firebrands under laboratory conditions

The laboratory experiment was conducted to simulate the transfer of smouldering particles produced in forest wildfires by a heated gas flow. The pine bark pieces with the linear dimensions L=(15; 20; 30) mm and a thickness of h=(4−5) mm were selected as model particles. The rate and temperature of the incident flow varied in the range of 1–3 m/s and 80–85 °C, respectively. The temperature of the samples was recorded using a thermal imager. To determine the minimum smouldering temperature of pine bark, the thermal analysis was conducted. The minimum smouldering temperature of pine bark was found to be 190 °C. This temperature will cause thermal decomposition of bark only at the first stage (oxidation of resinous components). In the study the smouldering time, the temperature and the weight of samples were obtained and analyzed under various experimental conditions. The data analysis shows that the increase in the particle size leads to the decrease in their mass loss, and the rate change of the incident flow does not practically influence the mass change. For particles with the linear dimensions of 10 mm and 20 mm, the mass varies from 6% to 25%. The maximum mass loss is observed for the flows with a rate of 1 and 2 m/s. The results have shown that the increase in the particle size leads to the increase in the smouldering time. The position of the particle plays an important role, the effect of which increases with increasing the particle size. The calculations showed that the smouldering time of bark samples is long enough for the particles to serve as new sources of spot fires. The particles were found to be transported to a distance of 218 m from the fire line which can certainly influence the propagation of the fire front

Determination of smoldering time and thermal characteristics of firebrands under laboratory conditions

The laboratory experiment was conducted to simulate the transfer of smouldering particles produced in forest wildfires by a heated gas flow. The pine bark pieces with the linear dimensions L=(15; 20; 30) mm and a thickness of h=(4−5) mm were selected as model particles. The rate and temperature of the incident flow varied in the range of 1–3 m/s and 80–85 °C, respectively. The temperature of the samples was recorded using a thermal imager. To determine the minimum smouldering temperature of pine bark, the thermal analysis was conducted. The minimum smouldering temperature of pine bark was found to be 190 °C. This temperature will cause thermal decomposition of bark only at the first stage (oxidation of resinous components). In the study the smouldering time, the temperature and the weight of samples were obtained and analyzed under various experimental conditions. The data analysis shows that the increase in the particle size leads to the decrease in their mass loss, and the rate change of the incident flow does not practically influence the mass change. For particles with the linear dimensions of 10 mm and 20 mm, the mass varies from 6% to 25%. The maximum mass loss is observed for the flows with a rate of 1 and 2 m/s. The results have shown that the increase in the particle size leads to the increase in the smouldering time. The position of the particle plays an important role, the effect of which increases with increasing the particle size. The calculations showed that the smouldering time of bark samples is long enough for the particles to serve as new sources of spot fires. The particles were found to be transported to a distance of 218 m from the fire line which can certainly influence the propagation of the fire front

Solubility of Hybrid Halide Perovskites in DMF and DMSO

Solution methods remain the most popular means for the fabrication of hybrid halide perovskites. However, the solubility of hybrid perovskites has not yet been quantitively investigated. In this study, we present accurate solubility data for MAPbI3, FAPbI3, MAPbBr3 and FAPbBr3 in the two most widely used solvents, DMF and DMSO, and demonstrate huge differences in the solubility behavior depending on the solution compositions. By analyzing the donor numbers of the solvents and halide anions, we rationalize the differences in the solubility behavior of hybrid perovskites with various compositions, in order to take a step forward in the search for better processing conditions of hybrid perovskites for solar cells and optoelectronics

New Acidic Precursor and Acetone-Based Solvent for Fast Perovskite Processing via Proton-Exchange Reaction with Methylamine

A new solvent system for PbI2 based on HI solution in acetone with a low boiling point is proposed. High solubility of PbI2 is caused by the formation of iodoplumbate complexes, and reaches a concentration of 1.6 M. Upon its crystallization metastable solvate phases PbI2∙HI∙n{(CH3)2CO} are formed. The latter allows for their easy deposition on substrates in a form of smooth and uniform thin films by spin-coating. Through a fast acid-base reaction with a gaseous amine, the films of the intermediate phase can be completely converted to single-phase perovskite films. The developed method allows one to form smooth perovskite films with high crystallinity with a thickness up to 1 μm. Due to easy and fast processing, the developed method can be promising for perovskite technology upscaling

CNF-supported platinum electrocatalysts synthesized using plasma-assisted sputtering in pulse conditions for the application in a high-temperature PEM fuel cell

Nanostructured platinum catalysts for a high-temperature proton-exchange membrane (PEM) fuel cell based on polybenzimidazole (PBI) doped by H3PO4 were synthesized by magnetron-ion sputtering of platinum on carbon nano-fibers (CNF) in an impulse mode. The resulting catalysts were studied by transmission electron microscopy and X-ray diffraction. These catalysts with platinum particles size from 4 to 6 nm uniformly distributed over the CNF surface exhibit high efficiency. The electrodes based on the synthesized electrocatalysts were tested in a liquid electrolyte and as a component of PBI-based fuel cell. The fuel cell had power density ca. 300 mW/cm2. Degradation tests showed that carbon carrier oxidation mainly determined the catalyst stability and stability of CNF was higher in comparison with Vulcan XC-7