A Holistic Approach Based on Biomonitoring Techniques and Satellite Observations for Air Pollution Assessment and Health Risk Impact of Atmospheric Trace Elements in a Semi-Rural Area of Southern Italy (High Sauro Valley)

Air pollution is one of the most important environmental problems for rural, urban and industrial areas. This study assesses the concentrations, the possible interaction with the vegetation conditions and the sources of trace elements in atmospheric aerosol particles. To this aim, a novel holistic approach integrating biomonitoring techniques, satellite observations and multivariate statistical analysis was carried out in a semi-rural area before an on-shore reservoir (crude oil and gas) and an oil/gas pre-treatment plant identified as “Tempa Rossa” (High Sauro Valley—Southern Italy) were fully operative. The atmospheric trace element concentrations (i.e., Al, Ca, Cd, Cr, Cu, Fe, K, Li, Mg, Mn, Na, Ni, P, Pb, S, Ti and Zn) were assessed by “lichen-bag” monitoring. Satellite-derived normalized difference vegetation index (NDVI’) estimates were used to support the identification of environmental imbalances affecting vegetation conditions and linked to possible anthropogenic drivers. Principal component analysis (PCA) allowed identifying both natural and anthropogenic trace element sources, such as crustal resuspension, soil and road dust, traffic, biomass burning and agriculture practices. Empirical evidence highlighted an interaction between NDVI’ and S, Ni, Pb and Zn. The health risk impact of atmospheric trace elements on the exposed population, both adults and children, considering inhalation, ingestion and the dermal contact pathway, highlighted a possible non-carcinogenic risk concerning Ni and a not-negligible carcinogenic risk related to Cr(VI) for the adult population in the study area

A Holistic Approach Based on Biomonitoring Techniques and Satellite Observations for Air Pollution Assessment and Health Risk Impact of Atmospheric Trace Elements in a Semi-Rural Area of Southern Italy (High Sauro Valley)

Air pollution is one of the most important environmental problems for rural, urban and industrial areas. This study assesses the concentrations, the possible interaction with the vegetation conditions and the sources of trace elements in atmospheric aerosol particles. To this aim, a novel holistic approach integrating biomonitoring techniques, satellite observations and multivariate statistical analysis was carried out in a semi-rural area before an on-shore reservoir (crude oil and gas) and an oil/gas pre-treatment plant identified as “Tempa Rossa” (High Sauro Valley—Southern Italy) were fully operative. The atmospheric trace element concentrations (i.e., Al, Ca, Cd, Cr, Cu, Fe, K, Li, Mg, Mn, Na, Ni, P, Pb, S, Ti and Zn) were assessed by “lichen-bag” monitoring. Satellite-derived normalized difference vegetation index (NDVI’) estimates were used to support the identification of environmental imbalances affecting vegetation conditions and linked to possible anthropogenic drivers. Principal component analysis (PCA) allowed identifying both natural and anthropogenic trace element sources, such as crustal resuspension, soil and road dust, traffic, biomass burning and agriculture practices. Empirical evidence highlighted an interaction between NDVI’ and S, Ni, Pb and Zn. The health risk impact of atmospheric trace elements on the exposed population, both adults and children, considering inhalation, ingestion and the dermal contact pathway, highlighted a possible non-carcinogenic risk concerning Ni and a not-negligible carcinogenic risk related to Cr(VI) for the adult population in the study area

Apportioning PM1 in a contrasting receptor site in the Mediterranean region: Aerosol sources with an updated sulfur speciation

A multi-parametric experimental campaign was performed in Agri Valley (Basilicata, southern Italy) from July 2017 to January 2018. The investigated area, though basically rural and devoted to agricultural activities, hosts a huge onshore oil reservoir, i.e. Centro Olio Val d'Agri (COVA), bringing substantial environmental modifications and impacts to the district landscape. Daily concentrations of PM1 aerosol samples, Equivalent Black Carbon and number size distributions were evaluated. Chemical aerosol speciation based on elemental and ion analyses were carried out and source apportionment by Positive Matrix Factorization (PMF) was applied to reconstruct PM1 source profile. The most significant emission sources found are torches from the oil treatment facility (37 % w/w), an unresolved factor constituted by soil resuspension, Saharan dust, and biomass burning (24 % w/w), ammonium sulphate (23 % w/w), emissions from the oil desulfurization (Claus process) (13 % w/w), and traffic +road dust (3 % w/w). SEM analysis on PM1 single particles allowed to confirm the finding from PMF including the occurrence of elemental sulfur associated with the Claus process. The novelty of the present study consists in the identification of this latter fingerprint

L'Orlando Furioso e la sua traduzione in immagini. Collezione digitale dedicata alla fortuna figurativa dell'Orlando furioso

(abstract

L'Orlando Furioso e la sua traduzione in immagini. Collezione digitale dedicata alla fortuna figurativa dell'Orlando furioso

(abstract