The 4.8 GHz LHC Schottky Pick-up System

The LHC Schottky observation system is based on traveling wave type high sensitivity pickup structures operating at 4.8 GHz. The choice of the structure and operating frequency is driven by the demanding LHC impedance requirements, where very low impedance is required below 2 GHz, and good sensitivity at the selected band at 4.8 GHz. A sophisticated filtering and triple down-mixing signal processing chain has been designed and implemented in order to achieve the specified 100 dB instantaneous dynamic range without range switching. Detailed design aspects for the complete systems and test results without beam are presented and discussed

Direct Observation of the Relationship between Molecular Topology and Bulk Morphology for a π-Conjugated Material

International audienceHigh-performance organic semiconducting materials are reliant upon subtle changes in structure across different length scales. These morphological features control relevant physical properties and ultimately device performance. By combining in situ NMR spectroscopy and theoretical calculations, the conjugated small molecule TT is shown to exhibit distinct temperature-dependent local structural features that are related to macroscopic properties. Specifically, lamellar and melt states are shown to exhibit different molecular topologies associated with planar and twisted conformations of TT, respectively. This topological transformation offers a novel avenue for molecular design and control of solid-state organization

Nanoscale insight into intermolecular interactions in organic photovoltaic blends using solid state NMR spectroscopy

International audienc

Side-Chain Engineering of Nonfullerene Acceptors for Near-Infrared Organic Photodetectors and Photovoltaics

Narrow bandgap n-type molecular semiconductors are relevant as key materials components for the fabrication nearinfrared organic solar cells (OSCs) and organic photodetectors (OPDs). We thus designed nearly isostructural nonfullerene electron acceptors, except for the choice of solubilizing units, which absorb from 600 to 1100 nm. Specific molecules include CTIC-4F, CO1-4F, and COTIC-4F, whose optical bandgaps are 1.3, 1.2, and 1.1 eV, respectively. Modulation of intramolecular charge transfer characteristics was achieved by replacing alkoxy groups with alkyl groups on thiophene spacers that connect an electron-rich cyclopentadithiophene core to peripheral electronpoor fragments. OSCs incorporating CTIC-4F and CO1-4F with PTB7-Th achieve power conversion efficiencies of over 10% with short-circuit current densities as high as similar to 25 mA.cm(-2). The same blends achieve OPD responsivities of 0.52 A.W-1 at similar to 920 nm. These findings highlight outstanding opportunities to tune further molecular design so that OPDs may ultimately compete with their silicon counterparts.11Nsciescopu

Sizes of pure and doped helium droplets from single shot x-ray imaging

Advancements in x-ray free-electron lasers on producing ultrashort, ultrabright, and coherent x-ray pulses enable single-shot imaging of fragile nanostructures, such as superfluid helium droplets. This imaging technique gives unique access to the sizes and shapes of individual droplets. In the past, such droplet characteristics have only been indirectly inferred by ensemble averaging techniques. Here, we report on the size distributions of both pure and doped droplets collected from single-shot x-ray imaging and produced from the free-jet expansion of helium through a 5 μm diameter nozzle at 20 bars and nozzle temperatures ranging from 4.2 to 9 K. This work extends the measurement of large helium nanodroplets containing 109–1011 atoms, which are shown to follow an exponential size distribution. Additionally, we demonstrate that the size distributions of the doped droplets follow those of the pure droplets at the same stagnation condition but with smaller average sizes