In-situ X-ray spectroscopy of the electric double layer around TiO2 nanoparticles dispersed in aqueous solution: Implications for H2 generation

We report an experimental observation of a significant amount of hydroxide (OH–) created upon water dissociation and subsequently trapped around TiO2 nanoparticles dispersed in NH4OH aqueous solution. The hydroxide species is identified and quantified by a combination of photoemission and photon emission X-ray spectroscopies conducted on liquid samples using a liquid microjet. Unlike previous X-ray studies that observed only a few monolayers of water coverage on TiO2 surfaces and found maximally submonolayer of OH–, the true aqueous environment adopted in this study enables ion mobility and the separation of the water dissociation products H+/OH–. This facilitates the formation of OH– diffused multilayer in which the trapped OH– ions are discovered to coordinate with three water molecules to form a tetrahedral hydration configuration. The negatively charged diffuse layers, together with the positive NH4+ Stern layers, constitute >0.8 nm thick electric double layers around the TiO2 nanoparticles. The large observed amount of hydroxide indicates a high efficiency of water dissociation for the TiO2 catalyst, a promising result for H2 generation in true aqueous environments

A minimal model of quantized conductance in interacting ballistic quantum wires

We review what we consider to be the minimal model of quantized conductance in a finite interacting quantum wire. Our approach utilizes the simplicity of the equation of motion description to both deal with general spatially dependent interactions and finite wire geometry. We emphasize the role of two different kinds of boundary conditions, one associated with local "chemical" equilibrium in the sense of Landauer, the other associated with screening in the proximity of the Fermi liquid metallic leads. The relation of our analysis to other approaches to this problem is clarified. We then use our formalism to derive a Drude type expression for the low frequency AC-conductance of the finite wire with general interaction profile.Comment: 6 pages, 2 figures; extended discussion, references adde

Reviewing and analyzing shrinkage of peat and other organic soils in relation to selected soil properties

Peat and other organic soils (e.g., organo-mineral soils) show distinctive volume changes through desiccation and wetting. Important processes behind volume changes are shrinkage and swelling. There is a long history of studies on shrinkage which were conducted under different schemes for soil descriptions, nomenclatures and parameters, measurement approaches, and terminologies. To date, these studies have not been harmonized in order to compare or predict shrinkage from different soil properties, for example, bulk density or substrate composition. This, however, is necessary to prevent biases in the determination of volume-based soil properties or for the interpretation of elevation measurements in peatlands, in order to predict carbon dioxide emissions or uptake caused by microbial decomposition or peat formation. This study gives a comprehensive overview of shrinkage studies carried out in the last 100 years. Terminology and approaches are systematically classified. In part I, the concepts for shrinkage characteristics, measurement methods, and model approaches are summarized. Part II is a meta-analysis of shrinkage studies on peat and other organic soils amended by own measurement data obtained by a three-dimensional structured light scanner. The results show that maximum shrinkage has a wide range from 11% to 93% and is strongly affected by common soil properties (botanical composition, degree of decomposition, soil organic carbon, and bulk density). Showing a stronger correlation, bulk density was a better predictor than soil organic carbon, but maximum shrinkage showed a large spread over all types of peat and other organic soils and ranges of bulk density and soil organic carbon

Mechanical losses in low loss materials studied by Cryogenic Resonant Acoustic spectroscopy of bulk materials (CRA spectroscopy)

Mechanical losses of crystalline silicon and calcium fluoride have been analyzed in the temperature range from 5 to 300 K by our novel mechanical spectroscopy method, cryogenic resonant acoustic spectroscopy of bulk materials (CRA spectrocopy). The focus lies on the interpretation of the measured data according to phonon-phonon interactions and defect induced losses in consideration of the excited mode shape.Comment: 4 pages, 4 figures, proceedings of the PHONONS 2007, submitted to Journal of Physics: Conference Serie

Gaffnian holonomy through the coherent state method

We analyze the effect of exchanging quasiholes described by Gaffnian quantum Hall trial state wave functions. This exchange is carried out via adiabatic transport using the recently developed coherent state Ansatz. We argue that our Ansatz is justified if the Gaffnian parent Hamiltonian has a charge gap, even though it is gapless to neutral excitations, and may therefore properly describe the adiabatic transport of Gaffnian quasiholes. For nonunitary states such as the Gaffnian, the result of adiabatic transport cannot agree with the monodromies of the conformal block wave functions, and may or may not lead to well-defined anyon statistics. Using the coherent state Ansatz, we find two unitary solutions for the statistics, one of which agrees with the statistics of the non-Abelian spin-singlet state by Ardonne and Schoutens.Comment: 11 pages, 4 figure

On the mechanical quality factors of cryogenic test masses from fused silica and crystalline quartz

Current interferometric gravitational wave detectors (IGWDs) are operated at room temperature with test masses made from fused silica. Fused silica shows very low absorption at the laser wavelength of 1064 nm. It is also well suited to realize low thermal noise floors in the detector signal band since it offers low mechanical loss, i. e. high quality factors (Q factors) at room temperature. However, for a further reduction of thermal noise, cooling the test masses to cryogenic temperatures may prove an interesting technique. Here we compare the results of Q factor measurements at cryogenic temperatures of acoustic eigenmodes of test masses from fused silica and its crystalline counterpart. Our results show that the mechanical loss of fused silica increases with lower temperature and reaches a maximum at 30 K for frequencies of slightly above 10 kHz. The losses of crystalline quartz generally show lower values and even fall below the room temperature values of fused silica below 10 K. Our results show that in comparison to fused silica, crystalline quartz has a considerably narrower and lower dissipation peak on cooling and thus has more promise as a test mass material for IGDWs operated at cryogenic temperatures. The origin of the different Q factor versus temperature behavior of the two materials is discussed.Comment: 11 pages, 2 figures, submitted to Class. Quantum Gra

Mechanical Q-factor measurements on a test mass with a structured surface

We present mechanical Q-factors (quality factors) of a crystalline quartz test mass with a nano-structured surface, measured in the temperature regime from 5 to 300 K. The nano-structure was a grating with a period of 2 mu m and a depth of about 0.1 mu m. Comparative measurements were performed on the plain substrate and on the structured test mass with different numbers of SiO2/Ta2O5 coating layers. The measurements at different stages of the test mass fabrication process show that the surface distortion induced by the nanostructure does not severely lower the mechanical Q-factor of the substrate. Damping due to a multi-layer coating stack was found to be orders of magnitude higher. The results provide vital information concerning the potential usage of low-thermal noise nano-structured test masses in future generations of high-precision laser interferometers and in current attempts to measure quantum effects of macroscopic mirror oscillators.DFG/SFB/Transregio

Reviewing and analyzing shrinkage of peat and other organic soils in relation to selected soil properties

Abstract Peat and other organic soils (e.g., organo‐mineral soils) show distinctive volume changes through desiccation and wetting. Important processes behind volume changes are shrinkage and swelling. There is a long history of studies on shrinkage which were conducted under different schemes for soil descriptions, nomenclatures and parameters, measurement approaches, and terminologies. To date, these studies have not been harmonized in order to compare or predict shrinkage from different soil properties, for example, bulk density or substrate composition. This, however, is necessary to prevent biases in the determination of volume‐based soil properties or for the interpretation of elevation measurements in peatlands, in order to predict carbon dioxide emissions or uptake caused by microbial decomposition or peat formation. This study gives a comprehensive overview of shrinkage studies carried out in the last 100 years. Terminology and approaches are systematically classified. In part I, the concepts for shrinkage characteristics, measurement methods, and model approaches are summarized. Part II is a meta‐analysis of shrinkage studies on peat and other organic soils amended by own measurement data obtained by a three‐dimensional structured light scanner. The results show that maximum shrinkage has a wide range from 11% to 93% and is strongly affected by common soil properties (botanical composition, degree of decomposition, soil organic carbon, and bulk density). Showing a stronger correlation, bulk density was a better predictor than soil organic carbon, but maximum shrinkage showed a large spread over all types of peat and other organic soils and ranges of bulk density and soil organic carbon

Pelvic orthosis effects on posterior pelvis kinematics: An in-vitro biomechanical study

The sacroiliac joint (SIJ) is a well-known source of low back pain, with increasing interest for both conservative and surgical treatment. Alterations in pelvis kinematics are hypothesized as a contributor to SIJ pain and pelvic orthoses one treatment option, but their effects on the pelvis are poorly understood. Alterations in movement patterns induced by the application of pelvic orthoses were determined in five human cadaveric pelvises. Deformations were obtained from the lumbosacral transition and the bilateral SIJ, using digital image correlation and a customized routine to compute the movements within the pelvis. Significant alterations were found for the movements at the SIJ, in particular a vast increase in axial (x-axis) rotation, accompanied by increased inferior (y-) translation of the sacrum relative to the ilium. Movement patterns at the lumbosacral transition changed, causing increases in axial rotation and decreased inferior translation of L5 relative to S1. Using a physiologic mode of load application gives novel insights into the potential effects of pelvic orthoses. The results of these in-vitro experiments vary markedly from previous experiments with loading limited to two or less axes. Furthermore, the influence of pelvic orthoses on the lumbosacral transition warrants further investigation