Effects of intraparticle heat and mass transfer during devolatilization of a single coal particle

The objective of the present work is to elucidate the influence of intraparticle mass and heat transfer phenomena on the overall rate and product yields during devolatilization of a single coal particle in an inert atmosphere. To this end a mathematical model has been formulated which covers transient devolatilization kinetics and intraparticle mass and heat transport. Secondary deposition reactions of tarry volatiles also are included. These specific features of the model allow a quantitative assessment to be made of the impact of major process conditions such as the coal particle size, the ambient pressure and the heating rate on the tar, gas and total volatile yield during devolatilization. Model predictions are compared to a limited number of experimental results, both from the present work and from various literature sources

Nonholonomic Hamilton-Jacobi Theory via Chaplygin Hamiltonization

We develop Hamilton-Jacobi theory for Chaplygin systems, a certain class of nonholonomic mechanical systems with symmetries, using a technique called Hamiltonization, which transforms nonholonomic systems into Hamiltonian systems. We give a geometric account of the Hamiltonization, identify necessary and sufficient conditions for Hamiltonization, and apply the conventional Hamilton-Jacobi theory to the Hamiltonized systems. We show, under a certain sufficient condition for Hamiltonization, that the solutions to the Hamilton-Jacobi equation associated with the Hamiltonized system also solve the nonholonomic Hamilton-Jacobi equation associated with the original Chaplygin system. The results are illustrated through several examples.Comment: Accepted for publication in Journal of Geometry and Physic

Preordered forests, packed words and contraction algebras

We introduce the notions of preordered and heap-preordered forests, generalizing the construction of ordered and heap-ordered forests. We prove that the algebras of preordered and heap-preordered forests are Hopf for the cut coproduct, and we construct a Hopf morphism to the Hopf algebra of packed words. Moreover, we define another coproduct on the preordered forests given by the contraction of edges. Finally, we give a combinatorial description of morphims defined on Hopf algebras of forests with values in the Hopf algebras of shuffes or quasi-shuffles.Comment: 42 pages. arXiv admin note: text overlap with arXiv:1007.1547, arXiv:1004.5208 by other author