Fluorescence Analysis for Multi-Site Aluminum Binding to Natural Organic Matter

Natural organic matter (NOM) samples isolated from different water sources in Norway were compared using their fluorescence properties. Fluorescence surfaces were observed at pH 4.36 and deconvoluted using SIMPLISMA (Windig and Guilment 1991). There were a total of seven different fluorophores observed for these samples and each sampling site had between four and six ofthe fluorescent components. These components were observed to bind Al during titrations at the same pH. Multiresponse titration curves were fit using the method of Smith and Kramer (1998) and most of the binding strengths are similar to values for Suwannee River fulvic acid (1ogK’ between 4.8 and 5.5), but there are strong sites (IogK’ = 7) and weak sites (1ogK’ between 3 and 4) also observed. Results depended on the isolation method used; reverse osmosis and low pressure evaporation yielded different values but with no consistent trends

Coupled aerodynamic and acoustical predictions for turboprops

To predict the noise fields for proposed turboprop airplanes, an existing turboprop noise code by Farassat has been modified to accept blade pressure inputs from a three-dimensional aerodynamic code. A Euler-type code can handle the nonlinear transonic flow of these high-speed, highly swept blades. This turbofan code was modified to allow the calculation mesh to extend to about twice the blade radius and to apply circumferential periodicity rather than solid-wall boundary conditions on the blade in the region between the blade tip and the outer shroud. Outputs were added for input to the noise prediction program and for color contour plots of various flow variables. The Farassat input subroutines were modified to read files of blade coordinates and predicted surface pressures. Aerodynamic and acoustic results are shown for the SR-3 model blade. Comparison of the acoustic predicted results with measured data show good agreement

Radiation resistance studies of amorphous silicon films

Hydrogenated amorphous silicon thin films were irradiated with 2.00 MeV helium ions using fluences ranging from 1E11 to 1E15 cm(-2). The films were characterized using photothermal deflection spectroscopy and photoconductivity measurements. The investigations show that the radiation introduces sub-band-gap states 1.35 eV below the conduction band and the states increase supralinearly with fluence. Photoconductivity measurements suggest the density of states above the Fermi energy is not changing drastically with fluence

Numerical solution of periodic vortical flows about a thin airfoil

A numerical method is developed for computing periodic, three-dimensional, vortical flows around isolated airfoils. The unsteady velocity is split into a vortical component which is a known function of the upstream flow conditions and the Lagrangian coordinates of the mean flow, and an irrotational field whose potential satisfies a nonconstant-coefficient, inhomogeneous, convective wave equation. Solutions for thin airfoils at zero degrees incidence to the mean flow are presented in this paper. Using an elliptic coordinate transformation, the computational domain is transformed into a rectangle. The Sommerfeld radiation condition is applied to the unsteady pressure on the grid line corresponding to the far field boundary. The results are compared with a Possio solver, and it is shown that for maximum accuracy the grid should depend on both the Mach number and reduced frequency. Finally, in order to assess the range of validity of the classical thin airfoil approximation, results for airfoils with zero thickness are compared with results for airfoils with small thickness

Numerical solutions of the linearized Euler equations for unsteady vortical flows around lifting airfoils

A linearized unsteady aerodynamic analysis is presented for unsteady, subsonic vortical flows around lifting airfoils. The analysis fully accounts for the distortion effects of the nonuniform mean flow on the imposed vortical disturbances. A frequency domain numerical scheme which implements this linearized approach is described, and numerical results are presented for a large variety of flow configurations. The results demonstrate the effects of airfoil thickness, angle of attack, camber, and Mach number on the unsteady lift and moment of airfoils subjected to periodic vortical gusts. The results show that mean flow distortion can have a very strong effect on the airfoil unsteady response, and that the effect depends strongly upon the reduced frequency, Mach number, and gust wave numbers

A new flux conserving Newton's method scheme for the two-dimensional, steady Navier-Stokes equations

A new numerical method is developed for the solution of the two-dimensional, steady Navier-Stokes equations. The method that is presented differs in significant ways from the established numerical methods for solving the Navier-Stokes equations. The major differences are described. First, the focus of the present method is on satisfying flux conservation in an integral formulation, rather than on simulating conservation laws in their differential form. Second, the present approach provides a unified treatment of the dependent variables and their unknown derivatives. All are treated as unknowns together to be solved for through simulating local and global flux conservation. Third, fluxes are balanced at cell interfaces without the use of interpolation or flux limiters. Fourth, flux conservation is achieved through the use of discrete regions known as conservation elements and solution elements. These elements are not the same as the standard control volumes used in the finite volume method. Fifth, the discrete approximation obtained on each solution element is a functional solution of both the integral and differential form of the Navier-Stokes equations. Finally, the method that is presented is a highly localized approach in which the coupling to nearby cells is only in one direction for each spatial coordinate, and involves only the immediately adjacent cells. A general third-order formulation for the steady, compressible Navier-Stokes equations is presented, and then a Newton's method scheme is developed for the solution of incompressible, low Reynolds number channel flow. It is shown that the Jacobian matrix is nearly block diagonal if the nonlinear system of discrete equations is arranged approximately and a proper pivoting strategy is used. Numerical results are presented for Reynolds numbers of 100, 1000, and 2000. Finally, it is shown that the present scheme can resolve the developing channel flow boundary layer using as few as six to ten cells per channel width, depending on the Reynolds number

A finite-difference, frequency-domain numerical scheme for the solution of the linearized unsteady Euler equations

A numerical method is developed for solving periodic, three-dimensional, vortical flows around lifting airfoils in subsonic flow. The first-order method, that is presented, fully accounts for the distortion effects of the nonuniform mean flow on the convected upstream vortical disturbances. The unsteady velocity is split into a vortical component which is a known function of the upstream flow conditions and the Lagrangian coordinates of the mean flow, and an irrotational field whose potential satisfies a nonconstant-coefficient, inhomogeneous, convective wave equation. Using an elliptic coordinate transformation, the unsteady boundary value problem is solved in the frequency domain on grids which are determined as a function of the Mach number and reduced frequency. Extensive comparisons are made with known solutions to unsteady vortical flow problems, and it is seen that the agreement is generally very good for reduced frequencies ranging from 0 up to 4

Ecological Goods and Services Survey Summary Prepared for: Lower Souris Watershed Committee

An interview based survey of farm landowners in the south east corner of Saskatchewan was undertaken to evaluate the provision of wildlife habitat by agriculture. Producers were asked to provide management information regarding a piece of their land that was managed as a unit. Within the past ten years there has been a reduction in the conversion of remaining native land to crop land, an increase in conversion of annual crop land to perennial cover crops, an increase in the use of minimum disturbance (no-till) farming, and a decrease in the use of fire on stubble fields and sloughs. Many producers in the area often stated economic reasons for their current land use division. Even ecological reasons (productive capacity of the soil, poor cropping soil, light soil etc.) often had an economic basis. If the land was not productive enough, a management scheme with lower input costs would be adopted. This was commonly demonstrated in this survey by the conversion of marginal land to tame forages. Producers within this region seem willing to adopt farming practices that connect economic sustainability with environmental responsibility. This survey is part of an-on going study of the region.Land Use, Tillage, Crop Production/Industries, Environmental Economics and Policy, Land Economics/Use, Q150, Q240,

An Historical Overview of Crop Acres in Western Canada: A Graphical and Statistical Approach

Crop Production/Industries, Land Economics/Use,