2,765 research outputs found
The organic component of interstellar grains
The 3.4 micron absorption feature observed in the spectrum of a number of Galactic Center (GC) sources indicates the presence of organic molecules in the interstellar medium. It is ascribed to the C-H stretch vibration of tetrahedrally bonded carbon. From the observed features due to the interstellar organic material, an estimate was made of its composition and abundance. The ratio of the number of C-H groups of tetrahedrally to those of trigonally bonded carbon was 1.5, the cosmic abundance of carbon was .00037, and the depth of the silicate absorption toward the GC was taken equal to 3.6
Laboratory and observational study of the interrelation of the carbonaceous component of interstellar dust and solar system materials
By studying the chemical and isotopic composition of interstellar ice and dust, one gains insight into the composition and chemical evolution of the solid bodies in the solar nebula and the nature of the material subsequently brought into the inner part of the solar system by comets and meteorites. It is now possible to spectroscopically probe the composition of interstellar ice and dust in the mid-infrared, the spectral range which is most diagnostic of fundamental molecular vibrations. We can compare these spectra of various astronomical objects (including the diffuse and dense interstellar medium, comets, and the icy outer planets and their satellites) with the spectra of analogs we produce in the laboratory under conditions which mimic those in these different objects. In this way one can determine the composition and abundances of the major constituents of the various ices and place general constraints on the types of organics coating the grains in the diffuse interstellar medium. In particular we have shown the ices in the dense clouds contain H2O, CH3OH, CO, perhaps some NH3 and H2CO, we well as nitriles and ketones or esters. Furthermore, by studying the photochemistry of these ice analogs in the laboratory, one gains insight into the chemistry which takes place in interstellar/precometary ices. Chemical and spectroscopic studies of photolyzed analogs (including deuterated species) are now underway. The results of some of these studies will be presented and implications for the evolution of the biogenic elements in interstellar dust and comets will be discussed
Molecular and mass spectroscopic analysis of isotopically labeled organic residues
Experimental studies aimed at understanding the evolution of complex organic molecules on interstellar grains were performed. The photolysis of frozen gas mixtures of various compositions containing H2O, CO, NH3, and CH4 was studied. These species were chosen because of their astrophysical importance as deducted from observational as well as theoretical studies of ice mantles on interstellar grains. These ultraviolet photolyzed ices were warmed up in order to produce refractory organic molecules like the ones formed in molecular clouds when the icy mantles are being irradiated and warmed up either by a nearby stellar source or impulsive heating. The laboratory studies give estimates of the efficiency of production of such organic material under interstellar conditions. It is shown that the gradual carbonization of organic mantles in the diffuse cloud phase leads to higher and higher visual absorptivity - yellow residues become brown in the laboratory. The obtained results can be applied to explaining the organic components of comets and their relevance to the origin of life
Methanol masers : Reliable tracers of the early stages of high-mass star formation
The GLIMPSE and MSX surveys have been used to examine the mid-infrared
properties of a statistically complete sample of 6.7 GHz methanol masers. The
GLIMPSE point sources associated with methanol masers are clearly distinguished
from the majority, typically having extremely red mid-infrared colors, similar
to those expected of low-mass class 0 young stellar objects. The intensity of
the GLIMPSE sources associated with methanol masers is typically 4 magnitudes
brighter at 8.0 micron than at 3.6 micron. Targeted searches towards GLIMPSE
point sources with [3.6]-[4.5] > 1.3 and an 8.0 micron magnitude less than 10
will detect more than 80% of class II methanol masers. Many of the methanol
masers are associated with sources within infrared dark clouds (IRDC) which are
believed to mark regions where high-mass star formation is in its very early
stages. The presence of class II methanol masers in a significant fraction of
IRDC suggests that high-mass star formation is common in these regions.
Different maser species are thought to trace different evolutionary phases of
the high-mass star formation process. Comparison of the properties of the
GLIMPSE sources associated with class II methanol masers and other maser
species shows interesting trends, consistent with class I methanol masers
tracing a generally earlier evolutionary phase and OH masers tracing a later
evolutionary phase.Comment: 45 pages, 19 figures, accepted for publication in Ap
Maternal mortality due to cardiovascular disease in the Netherlands:a 21-year experience
Objective Cardiovascular disorders are the leading cause of indirect maternal mortality in Europe. The aim of this study is to present an extensive overview concerning the specific cardiovascular causes of maternal death and to identify avoidable contributing care factors related to these deaths. Methods We assessed all cases of maternal death due to cardiovascular disorders collected by a systematic national confidential enquiry of maternal deaths published by the Dutch Maternal Mortality and Morbidity Committee on behalf of the Netherlands Society of Obstetrics and Gynaecology over a 21-year period (1993-2013) in the Netherlands. Results There were 96 maternal cardiovascular deaths (maternal mortality rate due to cardiovascular diseases 2.4/100,000 liveborn children). Causes were aortic dissection (n & x202f;= 20, 21%), ischaemic heart disease (n & x202f;= 17, 18%), cardiomyopathies (including peripartum cardiomyopathy and myocarditis, n & x202f;= 20, 21%) and (unexplained) sudden death (n & x202f;= 27, 28%). Fifty-five percent of the deaths occurred postpartum (n & x202f;= 55, 55%). Care factors that may have contributed to the adverse outcome were identified in 27 cases (28%). These factors were patient-related in 40% (pregnancy against medical advice, underestimation of symptoms) and healthcare-provider-related in 60% (symptoms not recognised, delay in diagnosis, delay in referral). Conclusion The maternal cardiovascular mortality ratio is low in the Netherlands and the main causes of maternal cardiovascular mortality are in line with other European reports. In a minority of cases, care factors that were possibly preventable were identified. Women with cardiovascular disease should be properly counselled about the risks of pregnancy and the symptoms of complications. Education of care providers regarding the incidence, presentation and diagnosis of cardiovascular disease during pregnancy is recommended
The peculiar new state of the blazar PKS 1510-089
Contemporaneous multiwavelength observations with H.E.S.S., SALT, Fermi-LAT,
Swift, and ATOM show that the blazar PKS 1510-089 suffered a significant
decrease in its optical flux, degree of optical polarization and high-energy
gamma-ray (E > 100 MeV) flux since July 2021. Meanwhile, the X-ray and
very-high-energy gamma-ray (E > 100 GeV) fluxes remained steady throughout 2021
and 2022. The degree of optical polarization decreased to about zero in 2022,
indicating an unpolarized dominating accretion disk component in the optical-UV
domain that is completely diluting the polarized electron synchrotron
component. In this proceeding we will discuss, via theoretical SED modeling,
possible reasons for this dramatic change in the appearance of this blazar.Comment: 8 pages, 3 figures, ICRC conferenc
Autoimmune encephalitis: Epidemiology, pathophysiology and clinical spectrum (part 2)
Autoimmune encephalitis (AE) represents a growing number of severe autoimmune-inflammatory diseases affecting both the white and grey matter of the brain. In part 1 of this series we focused on the epidemiology, pathophysiology and clinical presentation of this condition, with two illustrative cases. In this part, we will introduce the clinical criteria for AE, particularly for the diagnosis of anti-N-methyl-D-aspartate (NMDA) receptor encephalitis, which were developed to facilitate immune treatment in suspected cases before antibody results are available. We subsequently discuss the work up, differential diagnosis and treatment options for patients with this disease.
The Infrared Band Strengths of H2o, Co and Co2 in Laboratory Simulations of Astrophysical Ice Mixtures
Infrared spectroscopic observations toward objects obscured by dense cloud
material show that HO, CO and, likely, CO are important constituents of
interstellar ice mantles. In order to accurately calculate the column densities
of these molecules, it is important to have good measurements of their infrared
band strengths in astrophysical ice analogs. We present the results of
laboratory experiments to determine these band strengths. Improved experimental
methods, relying on simultaneous independent depositions of the molecule to be
studied and of the dominating ice component, have led to accuracies better than
a few percent. Furthermore, the temperature behavior of the infrared band
strengths of CO and HO are studied. In contrast with previous work, the
strengths of the CO, CO, and HO infrared features are found to depend
only weakly on the composition of the ice matrix, and the reversible
temperature dependence of the CO band is found to be weaker than previously
measured for a mixture of CO in HO.Comment: 17 pages uuencoded compressed Postscript file-- includes all 6
figures (replaces most recent posting with only figs 2-5
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