Ultrahigh oxygen permeation flux through supported Ba0.5Sr0.5Co0.8Fe0.2O3-delta membranes

[EN] Oxygen transport membranes made of Ba0.5Sr0.5Co0.8Fe0.2O3-delta (BSCF) were manufactured by tape casting and co-firing. The disk-shaped membranes consisted of a top gastight layer (70 mu m thick) and a porous substrate (830 mu m thick) with 34% open porosity. The variation of the permeation operation conditions allowed (i) the identification of the different limitations steps in the permeation process, i.e., bulk oxygen ion diffusion, catalytic surface exchange and gas phase diffusion in the membrane compartments and porous substrate, and (ii) the ultimate optimization of the oxygen flux. The variables considered in the systematic permeation study included the inlet gas flow rate of the sweep and air feed, the temperature and the nature of the oxygen feed gas (air or pure oxygen). Moreover, the influence of the deposition of a catalytic activation layer (17 mu m thick) made of BSCF on top of the thin gastight layer was investigated. As a result of this parametric study, unpreceded oxygen flux values were achieved, i.e., a maximum flux of 67.7 ml(STP) min(-1) cm(-2) was obtained at 1000 degrees C using pure oxygen as the feed and argon as the sweep, while a flux of 12.2 ml(STP) min(-1) cm(-2) at 1000 degrees C was obtained when air was used as the feed. (C) 2011 Elsevier BM. All rights reserved.Financial support from the Spanish Ministry for Science and Innovation (Project ENE2008-06302 and FPI Grant JAE-Pre 08-0058), EU through FP7 NASA-OTM Project (NMP3-SL-2009-228701), and the Helmholtz Association of German Research Centres through the Helmholtz Alliance MEM-BRAIN (Initiative and Networking Fund) is kindly acknowledged. Mrs H. Burlet has contributed to this work with the careful revision of the English language.Baumann, S.; Serra Alfaro, JM.; Lobera González, MP.; Escolástico Rozalén, S.; Schulze-Kueppers, F.; Meulenberg, WA. (2011). Ultrahigh oxygen permeation flux through supported Ba0.5Sr0.5Co0.8Fe0.2O3-delta membranes. Journal of Membrane Science. 377(1-2):198-205. https://doi.org/10.1016/j.memsci.2011.04.050S1982053771-

MEM-BRAIN gas separation membranes for energy-efficient processes

[EN] The objective of the Helmholtz Portfolio "MEM-BRAIN" is the development and integration of cermaic and polymeric gas separation membranes for advanced fossil power plants and other applications like biogas processing or processes in the chemical industry. This will be achieved using membranes with a high permeability and selectivity for either CO2 O2 or H2, for the three CO" capture process routes in power plants, thus enabling CO2 to be captures with high-purity in a reaadly condensable form.Czyperek, M.; Baumann, S.; Bouwmeester, H.; Meulenberg, WA.; Modigell, M.; Serra Alfaro, JM.; Shishatskiy, S.... (2012). MEM-BRAIN gas separation membranes for energy-efficient processes. Procedia Engineering. 44:1554-1556. doi:10.1016/j.proeng.2012.08.863S155415564