Precursor-mediated crystallization process in suspensions of hard spheres

We report on a large scale computer simulation study of crystal nucleation in hard spheres. Through a combined analysis of real and reciprocal space data, a picture of a two-step crystallization process is supported: First dense, amorphous clusters form which then act as precursors for the nucleation of well-ordered crystallites. This kind of crystallization process has been previously observed in systems that interact via potentials that have an attractive as well as a repulsive part, most prominently in protein solutions. In this context the effect has been attributed to the presence of metastable fluid-fluid demixing. Our simulations, however, show that a purely repulsive system (that has no metastable fluid-fluid coexistence) crystallizes via the same mechanism.Comment: 4 figure

Constraints on the Equation-of-State of neutron stars from nearby neutron star observations

We try to constrain the Equation-of-State (EoS) of supra-nuclear-density matter in neutron stars (NSs) by observations of nearby NSs. There are seven thermally emitting NSs known from X-ray and optical observations, the so-called Magnificent Seven (M7), which are young (up to few Myrs), nearby (within a few hundred pc), and radio-quiet with blackbody-like X-ray spectra, so that we can observe their surfaces. As bright X-ray sources, we can determine their rotational (pulse) period and their period derivative from X-ray timing. From XMM and/or Chandra X-ray spectra, we can determine their temperature. With precise astrometric observations using the Hubble Space Telescope, we can determine their parallax (i.e. distance) and optical flux. From flux, distance, and temperature, one can derive the emitting area - with assumptions about the atmosphere and/or temperature distribution on the surface. This was recently done by us for the two brightest M7 NSs RXJ1856 and RXJ0720. Then, from identifying absorption lines in X-ray spectra, one can also try to determine gravitational redshift. Also, from rotational phase-resolved spectroscopy, we have for the first time determined the compactness (mass/radius) of the M7 NS RBS1223. If also applied to RXJ1856, radius (from luminosity and temperature) and compactness (from X-ray data) will yield the mass and radius - for the first time for an isolated single neutron star. We will present our observations and recent results.Comment: refereed NPA5 conference proceedings, in pres

Negative parental responses to coming out and family functioning in a sample of lesbian and gay young adults

Parental responses to youths' coming out (CO) are crucial to the subsequent adjustment of children and family. The present study investigated the negative parental reaction to the disclosure of same-sex attraction and the differences between maternal and paternal responses, as reported by their homosexual daughters and sons. Participants' perceptions of their parents' reactions (evaluated through the Perceived Parental Reactions Scale, PPRS), age at coming out, gender, parental political orientation, and religiosity involvement, the family functioning (assessed through the Family Adaptability and Cohesion Evaluation Scales, FACES IV), were assessed in 164 Italian gay and lesbian young adults. Pearson correlation coefficients were calculated to assess the relation between family functioning and parental reaction to CO. The paired sample t-test was used to compare mothers and fathers' scores on the PPRS. Hierarchical multiple regression was conducted to analyze the relevance of each variable. No differences were found between mothers and fathers in their reaction to the disclosure. The analysis showed that a negative reaction to coming out was predicted by parents' right-wing political conservatism, strong religious beliefs, and higher scores in the scales Rigid and Enmeshed. Findings confirm that a negative parental reaction is the result of poor family resources to face a stressful situation and a strong belief in traditional values. These results have important implications in both clinical and social fields

Quantitative imaging of concentrated suspensions under flow

We review recent advances in imaging the flow of concentrated suspensions, focussing on the use of confocal microscopy to obtain time-resolved information on the single-particle level in these systems. After motivating the need for quantitative (confocal) imaging in suspension rheology, we briefly describe the particles, sample environments, microscopy tools and analysis algorithms needed to perform this kind of experiments. The second part of the review focusses on microscopic aspects of the flow of concentrated model hard-sphere-like suspensions, and the relation to non-linear rheological phenomena such as yielding, shear localization, wall slip and shear-induced ordering. Both Brownian and non-Brownian systems will be described. We show how quantitative imaging can improve our understanding of the connection between microscopic dynamics and bulk flow.Comment: Review on imaging hard-sphere suspensions, incl summary of methodology. Submitted for special volume 'High Solid Dispersions' ed. M. Cloitre, Vol. xx of 'Advances and Polymer Science' (Springer, Berlin, 2009); 22 pages, 16 fig

Precursor-mediated crystallization in suspensions of hard spheres

We report on a large scale computer simulation study of crystal nucleation in hard spheres. Through a combined analysis of real- and reciprocal-space data, a picture of a two-step crystallization process is supported: First, dense, amorphous clusters form which then act as precursors for the nucleation of well-ordered crystallites. This kind of crystallization process has been previously observed in systems that interact via potentials that have an attractive as well as a repulsive part, most prominently in protein solutions. In this context the effect has been attributed to the presence of metastable fluid-fluid demixing. Our simulations, however, show that a purely repulsive system (that has no metastable fluid-fluid coexistence) crystallizes via the same mechanism

Electrostatic self-assembly of macroscopic crystals using contact electrification

Self-assembly1,2,3,4 of components larger than molecules into ordered arrays is an efficient way of preparing microstructured materials with interesting mechanical5,6 and optical7,8 properties. Although crystallization of identical particles9,10 or particles of different sizes11 or shapes12 can be readily achieved, the repertoire of methods to assemble binary lattices of particles of the same sizes but with different properties is very limited13,14. This paper describes electrostatic self-assembly15,16,17 of two types of macroscopic components of identical dimensions using interactions that are generated by contact electrification18,19,20. The systems we have examined comprise two kinds of objects (usually spheres) made of different polymeric materials that charge with opposite electrical polarities when agitated on flat, metallic surfaces. The interplay of repulsive interactions between like-charged objects and attractive interactions between unlike-charged ones results in the self-assembly of these objects into highly ordered, closed arrays. Remarkably, some of the assemblies that form are not electroneutral???that is, they possess a net charge. We suggest that the stability of these unusual structures can be explained by accounting for the interactions between electric dipoles that the particles in the aggregates induce in their neighbours