2,780 research outputs found

    Unconventional superconducting pairing symmetry induced by phonons

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    The possibility of non-s-wave superconductivity induced by phonons is investigated using a simple model that is inspired by Sr2_2RuO4_4. The model assumes a two-dimensional electronic structure, a two-dimensional spin-fluctuation spectrum, and three-dimensional electron-phonon coupling. Taken separately, each interaction favors formation of spin-singlet pairs (of s symmetry for the phonon interaction and dx2−y2_{x^2-y^2} symmetry for the spin interaction), but in combination, a variety of more unusual singlet and triplet states are found, depending on the interaction parameters. This may have important implications for Sr2_2RuO4_4, providing a plausible explanation of how the observed spin fluctuations, which clearly favor dx2−y2_{x^2-y^2} pairing, may still be instrumental in creating a superconducting state with a different (e.g., p-wave) symmetry. It also suggests an interpretation of the large isotope effect observed in Sr2_2RuO4_4. These results indicate that phonons could play a key role in establishing the order-parameter symmetry in Sr2_2RuO4_4, and possibly in other unconventional superconductors.Comment: 6 pages, 5 figures, submitted to Phys. Rev.

    First-principle Wannier functions and effective lattice fermion models for narrow-band compounds

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    We propose a systematic procedure for constructing effective lattice fermion models for narrow-band compounds on the basis of first-principles electronic structure calculations. The method is illustrated for the series of transition-metal (TM) oxides: SrVO3_3, YTiO3_3, V2_2O3_3, and Y2_2Mo2_2O7_7. It consists of three parts, starting from LDA. (i) construction of the kinetic energy Hamiltonian using downfolding method. (ii) solution of an inverse problem and construction of the Wannier functions (WFs) for the given kinetic energy Hamiltonian. (iii) calculation of screened Coulomb interactions in the basis of \textit{auxiliary} WFs, for which the kinetic-energy term is set to be zero. The last step is necessary in order to avoid the double counting of the kinetic-energy term, which is included explicitly into the model. The screened Coulomb interactions are calculated in a hybrid scheme. First, we evaluate the screening caused by the change of occupation numbers and the relaxation of the LMTO basis functions, using the conventional constraint-LDA approach, where all matrix elements of hybridization involving the TM dd orbitals are set to be zero. Then, we switch on the hybridization and evaluate the screening associated with the change of this hybridization in RPA. The second channel of screening is very important, and results in a relatively small value of the effective Coulomb interaction for isolated t2gt_{2g} bands. We discuss details of this screening and consider its band-filling dependence, frequency dependence, influence of the lattice distortion, proximity of other bands, and the dimensionality of the model Hamiltonian.Comment: 35 pages, 25 figure

    Limit cycles in the presence of convection, a travelling wave analysis

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    We consider a diffusion model with limit cycle reaction functions, in the presence of convection. We select a set of functions derived from a realistic reaction model: the Schnakenberg equations. This resultant form is unsymmetrical. We find a transformation which maps the irregular equations into model form. Next we transform the dependent variables into polar form. From here, a travelling wave analysis is performed on the radial variable. Results are complex, but we make some simple estimates. We carry out numerical experiments to test our analysis. An initial `knock' starts the propagation of pattern. The speed of the travelling wave is not quite as expected. We investigate further. The system demonstrates distinctly different behaviour to the left and the right. We explain how this phenomenon occurs by examining the underlying behaviour.Comment: 20 pages, 5 figure

    Tissue engineering of small caliber vascular grafts

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    Objective: Previous tissue engineering approaches to create small caliber vascular grafts have been limited by the structural and mechanical immaturity of the constructs. This study uses a novel in vitro pulse duplicator system providing a ‘biomimetic' environment during tissue formation to yield more mature, implantable vascular grafts. Methods: Vascular grafts (I.D. 0.5 cm) were fabricated from novel bioabsorbable polymers (polyglycolic-acid/poly-4-hydroxybutyrate) and sequentially seeded with ovine vascular myofibroblasts and endothelial cells. After 4 days static culture, the grafts (n=24) were grown in vitro in a pulse duplicator system (bioreactor) for 4, 7, 14, 21, and 28 days. Controls (n=24) were grown in static culture conditions. Analysis of the neo-tissue included histology, scanning electron microscopy (SEM), and biochemical assays (DNA for cell content, 5-hydroxyproline for collagen). Mechanical testing was performed measuring the burst pressure and the suture retention strength. Results: Histology showed viable, dense tissue in all samples. SEM demonstrated confluent smooth inner surfaces of the grafts exposed to pulsatile flow after 14 days. Biochemical analysis revealed a continuous increase of cell mass and collagen to 21 days compared to significantly lower values in the static controls. The mechanical properties of the pulsed vascular grafts comprised supra-physiological burst strength and suture retention strength appropriate for surgical implantation. Conclusions: This study demonstrates the feasibility of tissue engineering of viable, surgically implantable small caliber vascular grafts and the important effect of a ‘biomimetic' in vitro environment on tissue maturation and extracellular matrix formatio
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