The Cosmological Kibble Mechanism in the Laboratory: String Formation in Liquid Crystals

We have observed the production of strings (disclination lines and loops) via the Kibble mechanism of domain (bubble) formation in the isotropic to nematic phase transition of a sample of uniaxial nematic liquid crystal. The probablity of string formation per bubble is measured to be $0.33 \pm 0.01$. This is in good agreement with the theoretical value $1/ \pi$ expected in two dimensions for the order parameter space $S^2/{\bf Z}_2$ of a simple uniaxial nematic liquid crystal.Comment: 17 pages, in TEX, 2 figures (not included, available on request

Consequences of Zeeman Degeneracy for van der Waals Blockade between Rydberg Atoms

We analyze the effects of Zeeman degeneracies on the long-range interactions between like Rydberg atoms, with particular emphasis on applications to quantum information processing using van der Waals blockade. We present a general analysis of how degeneracies affect the primary error sources in blockade experiments, emphasizing that blockade errors are sensitive primarily to the weakest possible atom-atom interactions between the degenerate states, not the mean interaction strength. We present explicit calculations of the van der Waals potentials in the limit where the fine-structure interaction is large compared to the atom-atom interactions. The results are presented for all potential angular momentum channels invoving s, p, and d states. For most channels there are one or more combinations of Zeeman levels that have extremely small dipole-dipole interactions and are therefore poor candidates for effective blockade experiments. Channels with promising properties are identified and discussed. We also present numerical calculations of Rb and Cs dipole matrix elements and relevant energy levels using quantum defect theory, allowing for convenient quantitative estimates of the van der Waals interactions to be made for principal quantum numbers up to 100. Finally, we combine the blockade and van der Waals results to quantitatively analyze the angular distribution of the blockade shift and its consequence for angular momentum channels and geometries of particular interest for blockade experiments with Rb.Comment: 16 figure

Loop Groups and Discrete KdV Equations

A study is presented of fully discretized lattice equations associated with the KdV hierarchy. Loop group methods give a systematic way of constructing discretizations of the equations in the hierarchy. The lattice KdV system of Nijhoff et al. arises from the lowest order discretization of the trivial, lowest order equation in the hierarchy, b_t=b_x. Two new discretizations are also given, the lowest order discretization of the first nontrivial equation in the hierarchy, and a "second order" discretization of b_t=b_x. The former, which is given the name "full lattice KdV" has the (potential) KdV equation as a standard continuum limit. For each discretization a Backlund transformation is given and soliton content analyzed. The full lattice KdV system has, like KdV itself, solitons of all speeds, whereas both other discretizations studied have a limited range of speeds, being discretizations of an equation with solutions only of a fixed speed.Comment: LaTeX, 23 pages, 1 figur

The quantitative condition is necessary in guaranteeing the validity of the adiabatic approximation

The usual quantitative condition has been widely used in the practical applications of the adiabatic theorem. However, it had never been proved to be sufficient or necessary before. It was only recently found that the quantitative condition is insufficient, but whether it is necessary remains unresolved. In this letter, we prove that the quantitative condition is necessary in guaranteeing the validity of the adiabatic approximation.Comment: 4 pages,1 figue

Hydrogen production by photoelectrolytic decomposition of H2O using solar energy

Photoelectrochemical systems for the efficient decomposition of water are discussed. Semiconducting d band oxides which would yield the combination of stability, low electron affinity, and moderate band gap essential for an efficient photoanode are sought. The materials PdO and Fe-xRhxO3 appear most likely. Oxygen evolution yields may also be improved by mediation of high energy oxidizing agents, such as CO3(-). Examination of several p type semiconductors as photocathodes revealed remarkable stability for p-GaAs, and also indicated p-CdTe as a stable H2 photoelectrode. Several potentially economical schemes for photoelectrochemical decomposition of water were examined, including photoelectrochemical diodes and two stage, four photon processes

Evolution of a localized electron spin in a nuclear spin environment

Motivated by recent interest in the role of the hyperfine interaction in quantum dots we study the dynamics of a localized electron spin coupled to many nuclei. An important feature of the model is that the coupling to an individual nuclear spin depends on its position in the quantum dot. We introduce a semi-classical description of the system valid in the limit of a large number of nuclei and analyze the resulting classical dynamics. Contrary to a natural assumption, the correlation functions of electron spin with an arbitrary initial condition show no decay in time. Rather, they exhibit complicated undamped oscillations. This may be attributed to the fact that the system has many integrals of motion and is close to an integrable one. The ensemble averaged correlation functions do exhibit a slow decay (1/ln(t)) for t -> \infty.Comment: 11 pages, 11 figures, revtex4 styl

Atom cooling by non-adiabatic expansion

Motivated by the recent discovery that a reflecting wall moving with a square-root in time trajectory behaves as a universal stopper of classical particles regardless of their initial velocities, we compare linear in time and square-root in time expansions of a box to achieve efficient atom cooling. For the quantum single-atom wavefunctions studied the square-root in time expansion presents important advantages: asymptotically it leads to zero average energy whereas any linear in time (constant box-wall velocity) expansion leaves a non-zero residual energy, except in the limit of an infinitely slow expansion. For finite final times and box lengths we set a number of bounds and cooling principles which again confirm the superior performance of the square-root in time expansion, even more clearly for increasing excitation of the initial state. Breakdown of adiabaticity is generally fatal for cooling with the linear expansion but not so with the square-root expansion.Comment: 4 pages, 4 figure

The Universal Gaussian in Soliton Tails

We show that in a large class of equations, solitons formed from generic initial conditions do not have infinitely long exponential tails, but are truncated by a region of Gaussian decay. This phenomenon makes it possible to treat solitons as localized, individual objects. For the case of the KdV equation, we show how the Gaussian decay emerges in the inverse scattering formalism.Comment: 4 pages, 2 figures, revtex with eps

Theoretical analysis of the transmission phase shift of a quantum dot in the presence of Kondo correlations

We study the effects of Kondo correlations on the transmission phase shift of a quantum dot coupled to two leads in comparison with the experimental determinations made by Aharonov-Bohm (AB) quantum interferometry. We propose here a theoretical interpretation of these results based on scattering theory combined with Bethe ansatz calculations. We show that there is a factor of 2 difference between the phase of the S-matrix responsible for the shift in the AB oscillations, and the one controlling the conductance. Quantitative agreement is obtained with experimental results for two different values of the coupling to the leads.Comment: 4 pages, 4 figures, accepted for publication in Physical Review Letter

Locality and topology in the molecular Aharonov-Bohm effect

It is shown that the molecular Aharonov-Bohm effect is neither nonlocal nor topological in the sense of the standard magnetic Aharonov-Bohm effect. It is further argued that there is a close relationship between the molecular Aharonov-Bohm effect and the Aharonov-Casher effect for an electrically neutral spin$-{1/2}$ particle encircling a line of charge.Comment: 3 pages, no figure