MALEO: Modular Assembly in Low Earth Orbit. A strategy for an IOC lunar base

Modular Assembly in Low Earth Orbit (MALEO) is a new strategy for building an initial operational capability lunar habitation base. In this strategy, the modular lunar base components are brought up to Low Earth Orbit by the Space Transportation System/Heavy Lift Launch Vehicle fleet, and assembled there to form a complete lunar base. Modular propulsion systems are then used to transport the MALEO lunar base, complete and intact, all the way to the moon. Upon touchdown on the lunar surface, the MALEO lunar habitation base is operational. An exo-skeletal truss superstructure is employed in order to uniformly absorb and distribute the rocket engine thrusting forces incurred by the MALEO lunar base during translunar injection, lunar orbit insertion, and lunar surface touchdown. The components, configuration, and structural aspects of the MALEO lunar base are discussed. Advantages of the MALEO strategy over conventional strategies are pointed out. It is concluded that MALEO holds promise for lunar base deployment

Digital modulation of the nickel valence state in a cuprate-nickelate heterostructure

Layer-by-layer oxide molecular beam epitaxy has been used to synthesize cuprate-nickelate multilayer structures of composition (La$_2$CuO$_4$)$_m$/LaO/(LaNiO$_3$)$_n$. In a combined experimental and theoretical study, we show that these structures allow a clean separation of dopant and doped layers. Specifically, the LaO layer separating cuprate and nickelate blocks provides an additional charge that, according to density functional theory calculations, is predominantly accommodated in the interfacial nickelate layers. This is reflected in an elongation of bond distances and changes in valence state, as observed by scanning transmission electron microscopy and x-ray absorption spectroscopy. Moreover, the predicted charge disproportionation in the nickelate interface layers leads to a thickness-dependent metal-to-insulator transition for $n=2$, as observed in electrical transport measurements. The results exemplify the perspectives of charge transfer in metal-oxide multilayers to induce doping without introducing chemical and structural disorder

Tunable Charge and Spin Order in PrNiO3_3 Thin Films and Superlattices

We have used polarized Raman scattering to probe lattice vibrations and charge ordering in 12 nm thick, epitaxially strained PrNiO$_3$ films, and in superlattices of PrNiO$_3$ with the band-insulator PrAlO$_3$. A carefully adjusted confocal geometry was used to eliminate the substrate contribution to the Raman spectra. In films and superlattices under tensile strain, which undergo a metal-insulator transition upon cooling, the Raman spectra reveal phonon modes characteristic of charge ordering. These anomalous phonons do not appear in compressively strained films, which remain metallic at all temperatures. For superlattices under compressive strain, the Raman spectra show no evidence of anomalous phonons indicative of charge ordering, while complementary resonant x-ray scattering experiments reveal antiferromagnetic order associated with a modest increase in resistivity upon cooling. This confirms theoretical predictions of a spin density wave phase driven by spatial confinement of the conduction electrons.Comment: PRL, in pres

Momentum-dependent charge correlations in YBa2_2Cu3_3O6+δ_{6+\delta} superconductors probed by resonant x-ray scattering: Evidence for three competing phases

We have used resonant x-ray scattering to determine the momentum dependent charge correlations in YBa$_2$Cu$_3$O$_{6.55}$ samples with highly ordered chain arrays of oxygen acceptors (ortho-II structure). The results reveal nearly critical, biaxial charge density wave (CDW) correlations at in-plane wave vectors (0.315, 0) and (0, 0.325). The corresponding scattering intensity exhibits a strong uniaxial anisotropy. The CDW amplitude and correlation length are enhanced as superconductivity is weakened by an external magnetic field. Analogous experiments were carried out on a YBa$_2$Cu$_3$O$_{6.6}$ crystal with a dilute concentration of spinless (Zn) impurities, which had earlier been shown to nucleate incommensurate magnetic order. Compared to pristine crystals with the same doping level, the CDW amplitude and correlation length were found to be strongly reduced. These results indicate a three-phase competition between spin-modulated, charge-modulated, and superconducting states in underdoped YBa$_2$Cu$_3$O$_{6+\delta}$.Comment: 6 pages, 3 figures revised version, to appear in Phys. Rev. Let

Long-range charge density wave proximity effect at cuprate-manganate interfaces

The interplay between charge density waves (CDWs) and high-temperature superconductivity is currently under intense investigation. Experimental research on this issue is difficult because CDW formation in bulk copper-oxides is strongly influenced by random disorder, and a long-range-ordered CDW state in high magnetic fields is difficult to access with spectroscopic and diffraction probes. Here we use resonant x-ray scattering in zero magnetic field to show that interfaces with the metallic ferromagnet La$_{2/3}$Ca$_{1/3}$MnO$_3$ greatly enhance CDW formation in the optimally doped high-temperature superconductor YBa$_2$Cu$_3$O$_{6+\delta}$ ($\bf \delta \sim 1$), and that this effect persists over several tens of nm. The wavevector of the incommensurate CDW serves as an internal calibration standard of the charge carrier concentration, which allows us to rule out any significant influence of oxygen non-stoichiometry, and to attribute the observed phenomenon to a genuine electronic proximity effect. Long-range proximity effects induced by heterointerfaces thus offer a powerful method to stabilize the charge density wave state in the cuprates, and more generally, to manipulate the interplay between different collective phenomena in metal oxides.Comment: modified version published in Nature Material

A Comparison of Stripe Modulations in La1.875_{1.875}Ba0.125_{0.125}CuO4_4 and La1.48_{1.48}Nd0.4_{0.4}Sr0.12_{0.12}CuO4_4

We report combined soft and hard x-ray scattering studies of the electronic and lattice modulations associated with stripe order in La$_{1.875}$Ba$_{0.125}$CuO$_4$ and La$_{1.48}$Nd$_{0.4}$Sr$_{0.12}$CuO$_4$. We find that the amplitude of both the electronic modulation of the hole density and the strain modulation of the lattice is significantly larger in La$_{1.875}$Ba$_{0.125}$CuO$_4$ than in La$_{1.48}$Nd$_{0.4}$Sr$_{0.12}$CuO$_4$ and is also better correlated. The in-plane correlation lengths are isotropic in each case; for La$_{1.875}$Ba$_{0.125}$CuO$_4$, $\xi^{hole}=255\pm 5$ \AA\ whereas for La$_{1.48}$Nd$_{0.4}$Sr$_{0.12}$CuO$_4$F, $\xi^{hole}=111\pm 7$ \AA. We find that the modulations are temperature independent in La$_{1.875}$Ba$_{0.125}$CuO$_4$ in the low temperature tetragonal phase. In contrast, in La$_{1.48}$Nd$_{0.4}$Sr$_{0.12}$CuO$_4$, the amplitude grows smoothly from zero, beginning 13 K below the LTT phase transition. We speculate that the reduced average tilt angle in La$_{1.875}$Ba$_{0.125}$CuO$_4$ results in reduced charge localization and incoherent pinning, leading to the longer correlation length and enhanced periodic modulation amplitude.Comment: 6 pages, 4 figure

Transfer of Magnetic Order and Anisotropy through Epitaxial Integration of 3d and 4f Spin Systems

Resonant x ray scattering at the Dy M 5 and Ni L 3 absorption edges was used to probe the temperature and magnetic field dependence of magnetic order in epitaxial LaNiO3 DyScO3 superlattices. For superlattices with 2 unit cell thick LaNiO3 layers, a commensurate spiral state develops in the Ni spin system below 100 K. Upon cooling below T ind 18 K, Dy Ni exchange interactions across the LaNiO3 DyScO3 interfaces induce collinear magnetic order of interfacial Dy moments as well as a reorientation of the Ni spins to a direction dictated by the strong magnetocrystalline anisotropy of Dy. This transition is reversible by an external magnetic field of 3 T. Tailored exchange interactions between rare earth and transition metal ions thus open up new perspectives for the manipulation of spin structures in metal oxide heterostructures and device