State of the art of the co-incineration of waste-derived fuels and raw materials in clinker/cement plants

The treatise is about the co-incineration of waste-derived fuels and raw materials in clinker/cement production plants and its impact on emissions to air. Depending on the incineration conditions, emissions to air can exceed existing requirements. This is demonstrated and explained by both conventional parameters such as dust, nitrogen oxides, sulphur dioxide, carbon monoxide, volatile organic carbon, mercury and other heavy metals, ammonia and hydrogen chloride and special organic pollutants such as benzene, polychlorinated dibenzo-p-dioxins and furans (PCCD/F), polychlorinated biphenyls (PCB), hexachlorobenzene (HCB) and polycyclic aromatic hydrocarbons (PAH)

A fundamental study on the extraction of particulate organic carbon from municipal wastewater treatment plants

In line with the strategy of transforming existing municipal wastewater treatment plants (WWTP) from disposal facilities into systems for using domestic wastewater (WW) as a source of energy and raw materials, a concept consisting of chemical, physical, and biological steps has been set up as a pilot project in WWTP Büsnau, Stuttgart, Germany. The key part of the entire process is based on the use of advanced microsieving (MS) to eliminate remaining particulate organic carbon (POC) (mg/L) from the effluent of the primary sedimentation tank (PST). Therefore, in the primary stages of this project, it was necessary to have a broad vision and a true understanding of the particle size distribution (PSD) of municipal WW. As a novel approach, in the present study, the conventional PSD method was optimized by implementing certain modifications, and the tests were conducted in situ. The modified PSD analyses facilitated in-depth investigations of solid–liquid separation at WWTPs and showed that drying samples in the oven can result in a 20% to 30% deviation in the POC (mg/L) removal results. In addition, the idea of the substitution of PSTs with an MS was supported by the results of this study. It was determined that an MS with a pore size of 45 µm to 63 µm can provide the same elimination efficiency as a PST. Another significant outcome of this study was the introduction of suitable mesh sizes for the MS which were coupled with PST in order to extract the maximum amount of POC (mg/L) from the municipal WWTPs without the addition of any chemicals. The results revealed that up to 90% of the TSS (mg/L) and 70% of the COD (mg/L) can be removed if an MS with a mesh size between 4 µm and 20 µm is coupled with a PST.German Research Foundation (DFG

Kutatási jelentés a magyarországi kommunális szennyvíztisztító telepek energiahatékonysági vizsgálatának módszertani megalapozásához

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Spurenstoffe und antibiotikaresistente Bakterien - Schnittstelle Abwasserent- und Wasserversorgung

Thema des Abwasserkolloquiums 2018 ist die Schnittstelle Abwasserentsorgung-Wasserversorgung. Renommierte Expert*innen präsentieren ihre aktuelle Sicht auf Spurenstoffe und antibiotikaresistente Bakterien in der Umwelt: Herkunft, Verbreitungswege, Wirkungen und Gefahren, analytische Nachweisverfahren sowie konzeptionelle und technische Maßnahmen zur Minderung bzw. Elimination. Welche diesbezüglichen gemeinsamen oder auch unterschiedlichen Aufgaben werden Abwasserentsorger und Wasserversorger in Zukunft zu bewältigen haben

Non-Syndromic and Syndromic Defects in Children with Extracranial Germ Cell Tumors: Data of 2610 Children Registered with the German MAKEI 96/MAHO 98 Registry Compared to the General Population

GCTs are developmental tumors and are likely to reflect ontogenetic and teratogenetic determinants. The objective of this study was to identify syndromes with or without congenital anomalies and non-syndromic defects as potential risk factors. Patients with extracranial GCTs (eGCTs) registered in MAKEI 96/MAHO 98 between 1996 and 2017 were included. According to Teilum’s holistic concept, malignant and benign teratomas were registered. We used a case–control study design with Orphanet as a reference group for syndromic defects and the Mainz birth registry (EUROCAT) for congenital anomalies at birth. Co-occurring genetic syndromes and/or congenital anomalies were assessed accordingly. Odds ratios and 95% confidence intervals were calculated and p -values for Fisher’s exact test with Bonferroni correction if needed. A strong association was confirmed for Swyer (OR 338.6, 95% CI 43.7–2623.6) and Currarino syndrome (OR 34.2, 95% CI 13.2–88.6). We additionally found 16 isolated cases of eGCT with a wide range of syndromes. However, these were not found to be significantly associated following Bonferroni correction. Most of these cases pertained to girls. Regarding non-syndromic defects, no association with eGCTs could be identified. In our study, we confirmed a strong association for Swyer and Currarino syndromes with additional congenital anomalies.This research received no external funding

Effect of coupling primary sedimentation tank (PST) and microscreen (MS) to remove particulate organic carbon (POC): a study to mitigate energy demand in municipal wastewater treatment plants

Abstract Particulate Chemical Oxygen Demand (COD) removal is one of the first and foremost steps in a wastewater treatment plant (WWTP). It is a highly essential step that supports subsequent biological steps to achieve discharge limits. However, the energy demand for subsequent biological steps is significant due to the requirement of physical processes such as aeration. As a part of the project: WWTP of the future, it was expected that by coupling primary sedimentation tank (PST) and microscreen (MS) as advanced primary treatment (APT), around 60 to 70% removal of total COD and more than 90% of total suspended solids could be achieved which can replace such energy-intensive steps. To achieve this, a pilot plant set up including two different types of rotatory drum sieves (8 and 20 μm) was coupled with a PST in the WWTP Büsnau, Stuttgart, Germany, and the efficiency of APT was undergone for deeper investigations. The results showed that applying APT processes is an innovative and robust approach for removing more solids in municipal WWTPs so that retrofitting treatment plants comes true with a marginal footprint. However, the long-term performance of the APT system demonstrated that the system’s ability to remove solids is highly limited by MS capacity and strength of produced flocs/filter-cakes inside the MS against shear forces, which makes it easier for flocs to be detained by MS. Therefore, additional auxiliary steps like flocculation are recommended to be synchronized with APT system to enhance its efficiency. Additionally, applying a middle mesh size sieve, for instance, a 15 μm, along with changing the backwashing regime, could be considered the next alternative

Batch studies of phosphonate and phosphate adsorption on granular ferric hydroxide (GFH) with membrane concentrate and its synthetic replicas

Phosphonates are widely used as antiscalants for softening processes in drinking water treatment. To prevent eutrophication and accumulation in the sediment, it is desirable to remove them from the membrane concentrate before they are discharged into receiving water bodies. This study describes batch experiments with synthetic solutions and real membrane concentrate, both in the presence of and absence of granular ferric hydroxide (GFH), to better understand the influence of ions on phosphonate and phosphate adsorption. To this end, experiments were conducted with six different phosphonates, using different molar Ca:phosphonate ratios. The calcium already contained in the GFH plays an essential role in the elimination process, as it can be re-dissolved, and, therefore, increase the molar Ca:phosphonate ratio. (Hydrogen-)carbonate ions had a competitive effect on the adsorption of phosphonates and phosphate, whereas the influence of sulfate and nitrate ions was negligible. Up to pH 8, the presence of CaII had a positive effect on adsorption, probably due to the formation of ternary complexes. At pH > 8, increased removal was observed, with either direct precipitation of Ca:phosphonate complexes or the presence of inorganic precipitates of calcium, magnesium, and phosphate serving as adsorbents for the phosphorus compounds. In addition, the presence of (hydrogen-)carbonate ions resulted in precipitation of CaCO3 and/or dolomite, which also acted as adsorbents for the phosphorus compounds