9,205 research outputs found
Core hole-electron correlation in coherently coupled molecules
We study the core hole-electron correlation in coherently coupled molecules
by energy dispersive near edge X-ray absorption fine-structure spectroscopy. In
a transient phase, which exists during the transition between two bulk
arrangements, 1,4,5,8-naphthalene-tetracarboxylicacid-dianhydride multilayer
films exhibit peculiar changes of the line shape and energy position of the
X-ray absorption signal at the C K-edge with respect to the bulk and gas phase
spectra. By a comparison to a theoretical model based on a coupling of
transition dipoles, which is established for optical absorption, we demonstrate
that the observed spectroscopic differences can be explained by an
intermolecular delocalized core hole-electron pair. By applying this model we
can furthermore quantify the coherence length of the delocalized core-exciton.Comment: 5 pages, 3 figures, Accepted Version, PRL, minor wording change
Single-nucleotide polymorphisms: analysis by mass spectrometry
Matrix-assisted laser desorption-ionization (MALDI) mass spectrometry has evolved as a powerful method for analyzing nucleic acids. Here we provide protocols for genotyping single-nucleotide polymorphisms (SNPs) by MALDI based on PCR and primer extension to generate allele-specific products. Furthermore, we present three different approaches for sample preparation of primer-extension products before MALDI analysis and discuss their potential areas of application. The first approach, the 'GOOD' assay, is a purification-free procedure that uses DNA-modification chemistry, including alkylation of phosphorothioate linkages in the extension primers. The other two approaches use either solid-phase extraction or microarray purification for the purification of primer-extension products. Depending on the reaction steps of the various approaches, the protocols take about 6–8 hours
New calculation schemes for proton-deuteron scattering including the Coulomb interaction
The Coulomb interaction between the protons is included in the description of
proton-deuteron scattering using the screening and renormalization approach in
the framework of momentum-space integral equations. Two new calculational
schemes are presented that confirm the reliability of the perturbative approach
for treating the screened Coulomb interaction in high partial waves, used by us
in earlier works.Comment: To be published in Phys. Rev.
Amenable covers and integral foliated simplicial volume
In analogy with ordinary simplicial volume, we show that integral foliated simplicial volume of oriented closed connected aspherical n-manifolds that admit an open amenable cover of multiplicity at most n is zero. This implies that the fundamental groups of such manifolds have fixed price and are cheap as well as reproves some statements about homology growth
Germinability Factors of Field-Grown Sorghum Seed
Germination of sorghum seed did not appear to be affected by spraying the plants with Maneb or with a chemical defoliant before harvest. Mechanical threshing greatly reduced germination of most but not all lots; this injury is thought to be related to the maturity and/ or moisture content of the seed when threshed, although other varietal differences may be important. At any given time there were large differences in moisture content between seeds of different hybrids, different plants of any one hybrid, and between different parts of the same panicle
Franck-Condon Factors and Radiative Lifetime of the A^{2}\Pi_{1/2} - X^{2}\Sigma^{+} Transition of Ytterbium Monoflouride, YbF
The fluorescence spectrum resulting from laser excitation of the
A^{2}\Pi_{1/2} - X^{2}\Sigma^{+} (0,0) band of ytterbium monofluoride, YbF, has
been recorded and analyzed to determine the Franck-Condon factors. The measured
values are compared with those predicted from Rydberg-Klein-Rees (RKR)
potential energy curves. From the fluorescence decay curve the radiative
lifetime of the A^{2}\Pi_{1/2} state is measured to be 28\pm2 ns, and the
corresponding transition dipole moment is 4.39\pm0.16 D. The implications for
laser cooling YbF are discussed.Comment: 5 pages, 5 figure
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