Core hole-electron correlation in coherently coupled molecules

We study the core hole-electron correlation in coherently coupled molecules by energy dispersive near edge X-ray absorption fine-structure spectroscopy. In a transient phase, which exists during the transition between two bulk arrangements, 1,4,5,8-naphthalene-tetracarboxylicacid-dianhydride multilayer films exhibit peculiar changes of the line shape and energy position of the X-ray absorption signal at the C K-edge with respect to the bulk and gas phase spectra. By a comparison to a theoretical model based on a coupling of transition dipoles, which is established for optical absorption, we demonstrate that the observed spectroscopic differences can be explained by an intermolecular delocalized core hole-electron pair. By applying this model we can furthermore quantify the coherence length of the delocalized core-exciton.Comment: 5 pages, 3 figures, Accepted Version, PRL, minor wording change

Single-nucleotide polymorphisms: analysis by mass spectrometry

Matrix-assisted laser desorption-ionization (MALDI) mass spectrometry has evolved as a powerful method for analyzing nucleic acids. Here we provide protocols for genotyping single-nucleotide polymorphisms (SNPs) by MALDI based on PCR and primer extension to generate allele-specific products. Furthermore, we present three different approaches for sample preparation of primer-extension products before MALDI analysis and discuss their potential areas of application. The first approach, the 'GOOD' assay, is a purification-free procedure that uses DNA-modification chemistry, including alkylation of phosphorothioate linkages in the extension primers. The other two approaches use either solid-phase extraction or microarray purification for the purification of primer-extension products. Depending on the reaction steps of the various approaches, the protocols take about 6–8 hours

New calculation schemes for proton-deuteron scattering including the Coulomb interaction

The Coulomb interaction between the protons is included in the description of proton-deuteron scattering using the screening and renormalization approach in the framework of momentum-space integral equations. Two new calculational schemes are presented that confirm the reliability of the perturbative approach for treating the screened Coulomb interaction in high partial waves, used by us in earlier works.Comment: To be published in Phys. Rev.

Amenable covers and integral foliated simplicial volume

In analogy with ordinary simplicial volume, we show that integral foliated simplicial volume of oriented closed connected aspherical n-manifolds that admit an open amenable cover of multiplicity at most n is zero. This implies that the fundamental groups of such manifolds have fixed price and are cheap as well as reproves some statements about homology growth

Germinability Factors of Field-Grown Sorghum Seed

Germination of sorghum seed did not appear to be affected by spraying the plants with Maneb or with a chemical defoliant before harvest. Mechanical threshing greatly reduced germination of most but not all lots; this injury is thought to be related to the maturity and/ or moisture content of the seed when threshed, although other varietal differences may be important. At any given time there were large differences in moisture content between seeds of different hybrids, different plants of any one hybrid, and between different parts of the same panicle

Franck-Condon Factors and Radiative Lifetime of the A^{2}\Pi_{1/2} - X^{2}\Sigma^{+} Transition of Ytterbium Monoflouride, YbF

The fluorescence spectrum resulting from laser excitation of the A^{2}\Pi_{1/2} - X^{2}\Sigma^{+} (0,0) band of ytterbium monofluoride, YbF, has been recorded and analyzed to determine the Franck-Condon factors. The measured values are compared with those predicted from Rydberg-Klein-Rees (RKR) potential energy curves. From the fluorescence decay curve the radiative lifetime of the A^{2}\Pi_{1/2} state is measured to be 28\pm2 ns, and the corresponding transition dipole moment is 4.39\pm0.16 D. The implications for laser cooling YbF are discussed.Comment: 5 pages, 5 figure