2,090 research outputs found
Modeling Micro-Porous Surfaces for Secondary Electron Emission Control to Suppress Multipactor
This work seeks to understand how the topography of a surface can be engineered to control secondary electron emission (SEE) for multipactor suppression. Two unique, semi-empirical models for the secondary electron yield (SEY) of a micro-porous surface are derived and compared. The first model is based on a two-dimensional (2D) pore geometry. The second model is based on a three-dimensional (3D) pore geometry. The SEY of both models is shown to depend on two categories of surface parameters: chemistry and topography. An important parameter in these models is the probability of electron emissions to escape the surface pores. This probability is shown by both models to depend exclusively on the aspect ratio of the pore (the ratio of the pore height to the pore diameter). The increased accuracy of the 3D model (compared to the 2D model) results in lower electron escape probabilities with the greatest reductions occurring for aspect ratios less than two. In order to validate these models, a variety of micro-porous gold surfaces were designed and fabricated using photolithography and electroplating processes. The use of an additive metal-deposition process (instead of the more commonly used subtractive metal-etch process) provided geometrically ideal pores which were necessary to accurately assess the 2D and 3D models. Comparison of the experimentally measured SEY data with model predictions from both the 2D and 3D models illustrates the improved accuracy of the 3D model. For a micro-porous gold surface consisting of pores with aspect ratios of two and a 50% pore density, the 3D model predicts that the maximum total SEY will be one. This provides optimal engineered surface design objectives to pursue for multipactor suppression using gold surfaces
Semantically Informed Multiview Surface Refinement
We present a method to jointly refine the geometry and semantic segmentation
of 3D surface meshes. Our method alternates between updating the shape and the
semantic labels. In the geometry refinement step, the mesh is deformed with
variational energy minimization, such that it simultaneously maximizes
photo-consistency and the compatibility of the semantic segmentations across a
set of calibrated images. Label-specific shape priors account for interactions
between the geometry and the semantic labels in 3D. In the semantic
segmentation step, the labels on the mesh are updated with MRF inference, such
that they are compatible with the semantic segmentations in the input images.
Also, this step includes prior assumptions about the surface shape of different
semantic classes. The priors induce a tight coupling, where semantic
information influences the shape update and vice versa. Specifically, we
introduce priors that favor (i) adaptive smoothing, depending on the class
label; (ii) straightness of class boundaries; and (iii) semantic labels that
are consistent with the surface orientation. The novel mesh-based
reconstruction is evaluated in a series of experiments with real and synthetic
data. We compare both to state-of-the-art, voxel-based semantic 3D
reconstruction, and to purely geometric mesh refinement, and demonstrate that
the proposed scheme yields improved 3D geometry as well as an improved semantic
segmentation
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Editors' Choice - Precipitation of Suboxides in Silicon, their Role in Gettering of Copper Impurities and Carrier Recombination
This paper describes a theoretical investigation of the phase composition of oxide precipitates and the corresponding emission of self-interstitials at the minimum of the free energy and their evolution with increasing number of oxygen atoms in the precipitates. The results can explain the compositional evolution of oxide precipitates and the role of self-interstitials therein. The formation of suboxides at the edges of SiO2 precipitates after reaching a critical size can explain several phenomena like gettering of Cu by segregation to the suboxide region and lifetime reduction by recombination of minority carriers in the suboxide. It provides an alternative explanation, based on minimized free energy, to the theory of strained and unstrained plates. A second emphasis was payed to the evolution of the morphology of oxide precipitates. Based on the comparison with results from scanning transmission electron microscopy the sequence of morphology evolution of oxide precipitates was deduced. It turned out that it is opposite to the sequence assumed until now. © 2020 The Author(s). Published on behalf of The Electrochemical Society by IOP Publishing Limited
Hybridization-related correction to the jellium model for fullerenes
We introduce a new type of correction for a more accurate description of
fullerenes within the spherically symmetric jellium model. This correction
represents a pseudopotential which originates from the comparison between an
accurate ab initio calculation and the jellium model calculation. It is shown
that such a correction to the jellium model allows one to account, at least
partly, for the sp2-hybridization of carbon atomic orbitals. Therefore, it may
be considered as a more physically meaningful correction as compared with a
structureless square-well pseudopotential which has been widely used earlier.Comment: 16 pages, 10 figure
Two European Cornus L. feeding leafmining moths, Antispila petryi Martini, 1899, sp. rev. and A. treitschkiella (Fischer von Röslerstamm, 1843) (Lepidoptera, Heliozelidae): an unjustified synonymy and overlooked range expansion
Antispila treitschkiella (Fischer von Röslerstamm, 1843) and A. petryi Martini, 1899, sp. rev. were regarded as synonymous since 1978, but are shown to be two clearly separated species with different hostplants, life histories, DNA barcodes and morphology. Antispila treitschkiella feeds on Cornus mas L., is bivoltine, and has, by following its ornamentally planted host, greatly expanded its range in north-western Europe. In contrast A. petryi feeds on the widespread native C. sanguinea L., is univoltine, and is one of only two Antispila species previously resident in the British Isles, the Netherlands and northern Europe. Consequently, the increase in abundance of A. treitschkiella in the Netherlands since the early 1990s and in Great Britain in recent years must be regarded as part of a recent expansion into north-western Europe, whereas the native A. petryi is hardly expanding and less abundant. In Britain, detailed surveys of parks and living collections confirmed the monophagy of these two species. A search of British herbarium samples provided no evidence for an earlier date of establishment. Information on recognition of all stages, including DNA barcodes, and distribution is provided, and these two species are compared with the third European Cornus L. leafminer, A. metallella (Denis & Schiffermüller, 1775)
A strongly Lewis-acidic and fluorescent borenium cation supported by a tridentate formazanate ligand
Lewis acids are highly sought after for their applications in sensing, small-molecule activation, and catalysis. When combined with π-conjugated molecular frameworks, Lewis acids with unique optoelectronic properties can be realized. Here, we use a tridentate formazanate ligand to create a planar, redox-active, fluorescent, and strongly Lewis-acidic borenium cation. We also demonstrate that this compound can act as a colourimetric probe for reactivity
Anion vacancy driven magnetism in incipient ferroelectric SrTiO3 and KTaO3 nanoparticles
Based on our analytical results [http://arxiv.org/abs/1006.3670], we predict
that undoped nanoparticles (size <10-100nm) of incipient ferroelectrics without
any magnetic ions can become ferromagnetic even at room temperatures due to the
inherent presence of a new type of magnetic defects with spin S=1, namely
oxygen vacancies, where the magnetic triplet state is the ground state in the
vicinity of the surface (magnetic shell), while the nonmagnetic singlet is the
ground state in the bulk material (nonmagnetic core). Consideration of randomly
distributed magnetic spins (S=1) had shown that magnetic properties of
incipient ferroelectric nanoparticles are strongly size and temperature
dependent due to the size and temperature dependence of their dielectric
permittivity and the effective Bohr radius proportional to permittivity. The
phase diagrams in coordinates temperature - particle radius are considered. In
particular, for particle radii less that the critical radius ferromagnetic
long-range order appears in a shell region of thickness 5 - 50 nm once the
concentration of magnetic defects exceeds the magnetic percolation threshold.
The critical radius is calculated in the mean field theory from the condition
of the magnetic defects exchange energy equality to thermal energy. For
particle radii higher than critical value only the paramagnetic phase is
possible. The conditions of the super-paramagnetic state appearance in the
assembly of nanoparticles with narrow distribution function of their sizes are
discussed also.Comment: 33 pages, 7 figures, 2 appendice
Time Optimal Control in Spin Systems
In this paper, we study the design of pulse sequences for NMR spectroscopy as
a problem of time optimal control of the unitary propagator. Radio frequency
pulses are used in coherent spectroscopy to implement a unitary transfer of
state. Pulse sequences that accomplish a desired transfer should be as short as
possible in order to minimize the effects of relaxation and to optimize the
sensitivity of the experiments. Here, we give an analytical characterization of
such time optimal pulse sequences applicable to coherence transfer experiments
in multiple-spin systems. We have adopted a general mathematical formulation,
and present many of our results in this setting, mindful of the fact that new
structures in optimal pulse design are constantly arising. Moreover, the
general proofs are no more difficult than the specific problems of current
interest. From a general control theory perspective, the problems we want to
study have the following character. Suppose we are given a controllable right
invariant system on a compact Lie group, what is the minimum time required to
steer the system from some initial point to a specified final point? In NMR
spectroscopy and quantum computing, this translates to, what is the minimum
time required to produce a unitary propagator? We also give an analytical
characterization of maximum achievable transfer in a given time for the two
spin system.Comment: 20 Pages, 3 figure
Predicting Visual Overlap of Images Through Interpretable Non-Metric Box Embeddings
To what extent are two images picturing the same 3D surfaces? Even when this
is a known scene, the answer typically requires an expensive search across
scale space, with matching and geometric verification of large sets of local
features. This expense is further multiplied when a query image is evaluated
against a gallery, e.g. in visual relocalization. While we don't obviate the
need for geometric verification, we propose an interpretable image-embedding
that cuts the search in scale space to essentially a lookup.
Our approach measures the asymmetric relation between two images. The model
then learns a scene-specific measure of similarity, from training examples with
known 3D visible-surface overlaps. The result is that we can quickly identify,
for example, which test image is a close-up version of another, and by what
scale factor. Subsequently, local features need only be detected at that scale.
We validate our scene-specific model by showing how this embedding yields
competitive image-matching results, while being simpler, faster, and also
interpretable by humans.Comment: ECCV 202
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