Double excitations of helium in weak static electric fields

A dramatic electric field dependence has been observed in the fluorescence yield spectrum of the doubly excited states in helium, where a rich phenomenology is encountered below the N 2 threshold. Fluorescence yields of certain states can be tuned to zero, while other dipole-forbidden states are significantly enhanced, for fields much weaker than 1 kV=cm. Using an R-matrix multichannel quantum defect theory, spherical-to-parabolic frame transformation method, we are able to reproduce the main features of the observed spectrum, and we discuss the qualitative behavior in terms of weak electric field mixing

Magnetic-field induced enhancement in the fluorescence yield spectrum of doubly excited states in helium

An influence of static magnetic fields on the fluorescence yield spectrum of He in the vicinity of the N 2 thresholds has been observed. The experimental results are in excellent agreement with predictions based on multichannel quantum defect theory, and it is demonstrated that the Rydberg electron ‘ mixing due to the diamagnetic interaction is essential for the description of the observed fluorescence yield intensity enhancement

Hydrogen bond effects in multimode nuclear dynamics of acetic acid observed via resonant x-ray scattering

A theoretical and experimental study of the gas phase and liquid acetic acid based on resonant inelastic x-ray scattering (RIXS) spectroscopy is presented. We combine and compare different levels of theory for an isolated molecule for a comprehensive analysis, including electronic and vibrational degrees of freedom. The excitation energy scan over the oxygen K-edge absorption reveals nuclear dynamic effects in the core-excited and final electronic states. The theoretical simulations for the monomer and two different forms of the dimer are compared against high-resolution experimental data for pure liquid acetic acid. We show that the theoretical model based on a dimer describes the hydrogen bond formation in the liquid phase well and that this bond formation sufficiently alters the RIXS spectra, allowing us to trace these effects directly from the experiment. Multimode vibrational dynamics is accounted for in our simulations by using a hybrid time-dependent stationary approach for the quantum nuclear wave packet simulations, showing the important role it plays in RIXS

The SPECIES beamline at the MAX IV Laboratory : a facility for soft X-ray RIXS and APXPS

SPECIES is an undulator-based soft X-ray beamline that replaced the old I511 beamline at the MAX II storage ring. SPECIES is aimed at high-resolution ambient-pressure X-ray photoelectron spectroscopy (APXPS), near-edge X-ray absorption fine-structure (NEXAFS), X-ray emission spectroscopy (XES) and resonant inelastic X-ray scattering (RIXS) experiments. The beamline has two branches that use a common elliptically polarizing undulator and monochromator. The beam is switched between the two branches by changing the focusing optics after the monochromator. Both branches have separate exit slits, refocusing optics and dedicated permanent endstations. This allows very fast switching between two types of experiments and offers a unique combination of the surface-sensitive XPS and bulk-sensitive RIXS techniques both in UHV- and at elevated ambient-pressure conditions on a single beamline. Another unique property of the beamline is that it reaches energies down to approximately 27 eV, which is not obtainable on other current APXPS beamlines. This allows, for instance, valence band studies under ambient-pressure conditions. In this article the main properties and performance of the beamline are presented, together with selected showcase experiments performed on the new setup