Spin-Charge Separation and Kinetic Energy in the t-J Model

I show that spin-charge separation in 2-D t-J model leads to an increase of kinetic energy. Using a sum rule, I derive an exact expression for the lowest possible KE (E_{bound}) for any state without doubly occupied sites. KE of relevant slave-boson and Schwinger-boson mean-field states -- which exhibit complete spin-charge separation -- are found to be much larger than E_{bound}. Examination of n(k) shows that the large increse in KE is due to excessive depletion of electrons from the bottom of the band (Schwinger boson) and of holes from the top (slave boson). To see whether the excess KE is simply due to poor treatment of the constraints, I solve the constraint problem analytically for the Schwinger boson case in the J = 0 limit. This restores gauge invariance, incorrectly violated in MF theories. The result is a generalized Hartree-Fock state of the Hubbard model, but one that includes spin waves. Even after constraints are imposed correctly, the KE remains much larger than E_{bound}. These results support the notion, advanced earlier [PRB 61, 8663 (2000)] that spin-charge separation in the MF state costs excessive KE, and makes the state unstable toward recombination processes which lead to superconductivity in d = 2 and a Fermi liquid state in higher dimensions.Comment: 13 pages, LateX plus three figures. To appear in Phys Rev B Typos correcte

Schwinger-Boson Mean-Field Theory of Mixed-Spin Antiferromagnet L2BaNiO5L_2BaNiO_5

The Schwinger-boson mean-field theory is used to study the three-dimensional antiferromagnetic ordering and excitations in compounds $L_2BaNiO_5$, a large family of quasi-one-dimensional mixed-spin antiferromagnet. To investigate magnetic properties of these compounds, we introduce a three-dimensional mixed-spin antiferromagnetic Heisenberg model based on experimental results for the crystal structure of $L_2BaNiO_5$. This model can explain the experimental discovery of coexistence of Haldane gap and antiferromagnetic long-range order below N\'{e}el temperature. Properties such as the low-lying excitations, magnetizations of $Ni$ and rare-earth ions, N\'{e}el temperatures of different compounds, and the behavior of Haldane gap below the N\'{e}el temperature are investigated within this model, and the results are in good agreement with neutron scattering experiments.Comment: 12 pages, 6 figure

Hydrogen absorption properties of amorphous (Ni0.6Nb0.4−yTay)100−xZrx membranes

Ni based amorphous materials have great potential as hydrogen purification membranes. In the present work the melt spun (Ni0.6Nb0.4−yTay)100−xZrx with y=0, 0.1 and x=20, 30 was studied. The result of X-ray diffraction spectra of the ribbons showed an amorphous nature of the alloys. Heating these ribbons below T < 400 °C, even in a hydrogen atmosphere (1−10 bar), the amorphous structure was retained. The crystallization process was characterized by differential thermal analysis and the activation energy of such process was obtained. The hydrogen absorption properties of the samples in their amorphous state were studied by the volumetric method, and the results showed that the addition of Ta did not significantly influence the absorption properties, a clear change of the hydrogen solubility was observed with the variation of the Zr content. The values of the hydrogenation enthalpy changed from ~37 kJ/mol for x=30 to ~9 kJ/mol for x=20. The analysis of the volumetric data provides the indications about the hydrogen occupation sites during hydrogenation, suggesting that at the beginning of the absorption process the deepest energy levels are occupied, while only shallower energy levels are available at higher hydrogen content, with the available interstitial sites forming a continuum of energy levels

PyDDRBG: A Python framework for benchmarking and evaluating static and dynamic multimodal optimization methods

PyDDRBG is a Python framework for generating tunable test problems for static and dynamic multimodal optimization. It allows for quick and simple generation of a set of predefined problems for non-experienced users, as well as highly customized problems for more experienced users. It easily integrates with an arbitrary optimization method. It can calculate the optimization performance when measured according to the robust mean peak ratio. PyDDRBG is expected to advance the fields of static and dynamic multimodal optimization by providing a common platform to facilitate the numerical analysis, evaluation, and comparison in these fields

Static and Dynamic Multimodal Optimization by Improved Covariance Matrix Self-Adaptation Evolution Strategy with Repelling Subpopulations

The covariance matrix self-adaptation evolution strategy with repelling subpopulations (RS-CMSA-ES) is one of the most successful multimodal optimization (MMO) methods currently available. However, some of its components may become inefficient in certain situations. This study introduces the second variant of this method, called RS-CMSA-ESII. It improves the adaptation schemes for the normalized taboo distances of the archived solutions and the covariance matrix of the subpopulation, the termination criteria for the subpopulations, and the way in which the infeasible solutions are treated. It also improves the time complexity of RS-CMSA-ES by updating the initialization procedure of a subpopulation and developing a more accurate metric for determining critical taboo regions. The effects of these modifications are illustrated by designing controlled numerical simulations. RS-CMSA-ESII is then compared with the most successful and recent niching methods for MMO on a widely adopted test suite. The results obtained reveal the superiority of RS-CMSA-ESII over these methods, including the winners of the competition on niching methods for MMO in previous years. Besides, this study extends RS-CMSA-ESII to dynamic MMO and compares it with a few recently proposed methods on the modified moving peak benchmark functions

Temperature dependence of the resistivity in the double-exchange model

The resistivity around the ferromagnetic transition temperature in the double exchange model is studied by the Schwinger boson approach. The spatial spin correlation responsible for scattering of conduction electrons are taken into account by adopting the memory function formalism. Although the correlation shows a peak lower than the transition temperature, the resistivity in the ferromagnetic state monotonically increases with increasing temperature due to a variation of the electronic state of the conduction electron. In the paramagnetic state, the resistivity is dominated by the short range correlation of scattering and is almost independent of the temperature. It is attributed to a cancellation between the nearest-neighbor spin correlation, the fermion bandwidth, and the fermion kinetic energy. This result implies the importance of the temperature dependence of the electronic states of the conduction electron as well as the localized spin states in both ferromagnetic and paramagnetic phases.Comment: RevTex, 4 pages, 4 PostScript figures, To appear in Phys. Rev.

Canted Ferromagnetism in Double Exchange Model with on-site Coulomb Repulsion

The double exchange model with on-site Coulomb repulsion is considered. Schwinger-bosons representation of the localized spins is used and two spin-singlet Fermion operators are introduced. In terms of the new Fermi fields the on-site Hund's interaction is in a diagonal form and the true magnons of the system are identified. The singlet fermions can be understood as electrons dressed by a cloud of repeatedly emitted and reabsorbed magnons. Rewritten in terms of Schwinger-bosons and spin-singlet fermions the theory is U(1) gauge invariant. We show that spontaneous breakdown of the gauge symmetry leads to \emph{\textbf{canted ferromagnetism with on-site spins of localized and delocalized electrons misaligned}}. On-site canted phase emerges in double exchange model when Coulomb repulsion is large enough. The quantum phase transition between ferromagnetism and canted phase is studied varying the Coulomb repulsion for different values of parameters in the theory such as Hund's coupling and chemical potential.Comment: 8 pages, 6 figure

Complexes of stationary domain walls in the resonantly forced Ginsburg-Landau equation

The parametrically driven Ginsburg-Landau equation has well-known stationary solutions -- the so-called Bloch and Neel, or Ising, walls. In this paper, we construct an explicit stationary solution describing a bound state of two walls. We also demonstrate that stationary complexes of more than two walls do not exist.Comment: 10 pages, 2 figures, to appear in Physical Review

Structure Formation and Coupling Reactions of Hexaphenylbenzene and Its Brominated Analog

The on‐surface coupling of the prototypical precursor molecule for graphene nanoribbon synthesis, 6,11‐dibromo‐1,2,3,4‐tetraphenyltriphenylene (C(42)Br(2)H(26), TPTP), and its non‐brominated analog hexaphenylbenzene (C(42)H(30), HPB), was investigated on coinage metal substrates as a function of thermal treatment. For HPB, which forms non‐covalent 2D monolayers at room temperature, a thermally induced transition of the monolayer's structure could be achieved by moderate annealing, which is likely driven by π‐bond formation. It is found that the dibrominated carbon positions of TPTP do not guide the coupling if the growth occurs on a substrate at temperatures that are sufficient to initiate C−H bond activation. Instead, similar one‐dimensional molecular structures are obtained for both types of precursors, HPB and TPTP