Communication: Inferring the equation of state of a metastable hard-sphere fluid from the equation of state of a hard-sphere mixture at high densities

A possible approximate route to obtain the equation of state of the monodisperse hard-sphere system in the metastable fluid region from the knowledge of the equation of state of a hard-sphere mixture at high densities is discussed. The proposal is illustrated by using recent Monte Carlo simulation data for the pressure of a binary mixture. It is further shown to exhibit high internal consistency.Comment: 4 pages, 2 figures; v2: Simulation data for one-component hard spheres included in Fig.

Contact values of the particle-particle and wall-particle correlation functions in a hard-sphere polydisperse fluid

The contact values $g(\sigma,\sigma')$ of the radial distribution functions of a fluid of (additive) hard spheres with a given size distribution $f(\sigma)$ are considered. A ``universality'' assumption is introduced, according to which, at a given packing fraction $\eta$, $g(\sigma,\sigma')=G(z(\sigma,\sigma'))$, where $G$ is a common function independent of the number of components (either finite or infinite) and $z(\sigma,\sigma')=[2 \sigma \sigma'/(\sigma+\sigma')]\mu_2/\mu_3$ is a dimensionless parameter, $\mu_n$ being the $n$-th moment of the diameter distribution. A cubic form proposal for the $z$-dependence of $G$ is made and known exact consistency conditions for the point particle and equal size limits, as well as between two different routes to compute the pressure of the system in the presence of a hard wall, are used to express $G(z)$ in terms of the radial distribution at contact of the one-component system. For polydisperse systems we compare the contact values of the wall-particle correlation function and the compressibility factor with those obtained from recent Monte Carlo simulations.Comment: 9 pages, 7 figure

Depletion potential in the infinite dilution limit

The depletion force and depletion potential between two in principle unequal "big" hard spheres embedded in a multicomponent mixture of "small" hard spheres are computed using the Rational Function Approximation method for the structural properties of hard-sphere mixtures [S. B. Yuste, A. Santos, and M. L\'opez de Haro, J. Chem. Phys. {\bf 108}, 3683 (1998)]. The cases of equal solute particles and of one big particle and a hard planar wall in a background monodisperse hard-sphere fluid are explicitly analyzed. An improvement over the performance of the Percus-Yevick theory and good agreement with available simulation results are foundComment: 10 pages, 5 figures; v2: few minor additions and reduction in the number of figures; v3: Fig. 2 corrected (see http://dx.doi.org/10.1063/1.4874639

Contact values of the radial distribution functions of additive hard-sphere mixtures in d dimensions: A new proposal

The contact values $g_{ij}(\sigma_{ij})$ of the radial distribution functions of a $d$-dimensional mixture of (additive) hard spheres are considered. A `universality' assumption is put forward, according to which $g_{ij}(\sigma_{ij})=G(\eta, z_{ij})$, where $G$ is a common function for all the mixtures of the same dimensionality, regardless of the number of components, $\eta$ is the packing fraction of the mixture, and $z_{ij}$ is a dimensionless parameter that depends on the size distribution and the diameters of spheres $i$ and $j$. For $d=3$, this universality assumption holds for the contact values of the Percus--Yevick approximation, the Scaled Particle Theory, and, consequently, the Boublik--Grundke--Henderson--Lee--Levesque approximation. Known exact consistency conditions are used to express $G(\eta,0)$, $G(\eta,1)$, and $G(\eta,2)$ in terms of the radial distribution at contact of the one-component system. Two specific proposals consistent with the above conditions (a quadratic form and a rational form) are made for the $z$-dependence of $G(\eta,z)$. For one-dimensional systems, the proposals for the contact values reduce to the exact result. Good agreement between the predictions of the proposals and available numerical results is found for $d=2$, 3, 4, and 5.Comment: 10 pages, 11 figures; Figure 1 changed; Figure 5 is new; New references added; accepted for publication in J. Chem. Phy

A simple effective rule to estimate the jamming packing fraction of polydisperse hard spheres

A recent proposal in which the equation of state of a polydisperse hard-sphere mixture is mapped onto that of the one-component fluid is extrapolated beyond the freezing point to estimate the jamming packing fraction $\phi_\text{J}$ of the polydisperse system as a simple function of $M_1M_3/M_2^2$, where $M_k$ is the $k$th moment of the size distribution. An analysis of experimental and simulation data of $\phi_\text{J}$ for a large number of different mixtures shows a remarkable general agreement with the theoretical estimate. To give extra support to the procedure, simulation data for seventeen mixtures in the high-density region are used to infer the equation of state of the pure hard-sphere system in the metastable region. An excellent collapse of the inferred curves up to the glass transition and a significant narrowing of the different out-of-equilibrium glass branches all the way to jamming are observed. Thus, the present approach provides an extremely simple criterion to unify in a common framework and to give coherence to data coming from very different polydisperse hard-sphere mixtures.Comment: 5 pages, 3 figures; v2: slight changes plus new reference

Photoinduced pseudospin effects in silicene beyond the off resonant condition

We study the photoinduced manipulation of charge carriers in monolayer silicene subject to intense electromagnetic terahertz radiation. Considering the Dirac cone approximation and going beyond the off resonant condition for large frequencies of the radiation field, where only virtual photon processes are allowed, we present the exact zero-momentum pseudospin polarization and numerical results for the quasienergy band structure and time-averaged density of states. We find that resonant processes, due to real photon emission and absorbtion processes, induce a band inversion that qualitatively modifies the quasienergy spectrum. These band structure changes manifest themselves as an inversion of the averaged pseudospin polarization. Through the analysis of the time-averaged density of states we find that effective photoinduced gap manipulation can only be achieved in the intermediate and strong matter-radiation coupling regime where the off resonant approximation breaks down.Comment: 8 pages, 3 figures, Accepted in PRB (in press

State of the art of pricing policy in air transportation: network carriers vs. low-cost airlines

The modern air transport industry is highly competitive. To survive in the market, the implementation of a successful marketing strategy is fundamental. In particular, an effective pricing policy has become crucial for airlines to remain profitable. Correspondingly, the different types of airline in the market have also established very distinct pricing policies. The present study is based on a literature review and presents the state of the art of pricing policy in air transportation. The aim is to compare and discuss the pricing strategies of network carriers and low-cost airlines. Special attention is paid to Revenue Management, which is a very important management tool used by airlines to take advantage of the differences in willingness to pay of passengers. The pricing policy, however, depends on the overall business strategy of the airline. Results show many differences, resulting from the fact that these two types of airline are characterized by very different fundamental business models and, correspondingly, also target groups. Since network carriers and also low-cost airlines have adjusted their pricing strategies lately, these recent developments will be discussed as well. This paper adds to the knowledge of this topic because it presents the most up-to-date and complete study on pricing regarding network carriers vs. low-cost airlines.A moderna indústria do transporte aéreo é altamente competitiva. Para sobreviver no mercado, a implementação de uma estratégia de marketing bem-sucedida é fundamental. Em particular, uma política de preços eficaz tornou-se crucial para as companhias aéreas continuarem lucrativas. Os diferentes tipos de companhias aéreas no mercado também estabeleceram políticas de preços muito distintas. O presente estudo baseia-se numa revisão da literatura e apresenta o estado da arte da política de preços no transporte aéreo. O objetivo é comparar e discutir as estratégias de preços de companhias aéreas de linha e companhias aéreas de baixo custo. Atenção especial é dada à Gestão de Receitas (Revenue Management), que é uma ferramenta de gestão usada pelas companhias aéreas para aproveitar as diferenças na disposição de pagar dos passageiros. A política de preços, no entanto, depende da estratégia geral de negócios da companhia aérea. Os resultados mostram muitas diferenças, resultantes do facto de que esses dois tipos de companhias aéreas são caracterizados por modelos de negócios fundamentais muito diferentes e, correspondentemente, também grupos-alvo. Como as operadoras de rede e também as companhias aéreas de baixo custo ajustaram as suas estratégias de preços ultimamente, esses desenvolvimentos recentes também serão discutidos. Este documento contribui para o conhecimento deste tópico, pois apresenta o estudo mais atualizado e completo sobre preços de companhias aéreas de linha versus companhias aéreas de baixo custo.info:eu-repo/semantics/publishedVersio