Magnetism of Substitutional Co Impurities in Graphene: Realization of Single π\pi-Vacancies

We report {\it ab initio} calculations of the structural, electronic and magnetic properties of a graphene monolayer substitutionally doped with Co (Co$_{sub}$) atoms. We focus in Co because among traditional ferromagnetic elements (Fe, Co and Ni), only Co$_{sub}$ atoms induce spin-polarization in graphene. Our results show the complex magnetism of Co substitutional impurites in graphene, which is mapped into simple models such as the $\pi$-vacancy and Heisenberg model. The links established in our work can be used to bring into contact the engineering of nanostructures with the results of $\pi$-models in defective graphene. In principle, the structures considered here can be fabricated using electron irradiation or Ar$^+$ ion bombardment to create defects and depositing Co at the same time

Magnetism of Covalently Functionalized Carbon Nanotubes

We investigate the electronic structure of carbon nanotubes functionalized by adsorbates anchored with single C-C covalent bonds. We find that, despite the particular adsorbate, a spin moment with a universal value of 1.0 $\mu_B$ per molecule is induced at low coverage. Therefore, we propose a mechanism of bonding-induced magnetism at the carbon surface. The adsorption of a single molecule creates a dispersionless defect state at the Fermi energy, which is mainly localized in the carbon wall and presents a small contribution from the adsorbate. This universal spin moment is fairly independent of the coverage as long as all the molecules occupy the same graphenic sublattice. The magnetic coupling between adsorbates is also studied and reveals a key dependence on the graphenic sublattice adsorption site.Comment: final version, improved discussion about calculations and defect concentratio

First-Principles Study of Substitutional Metal Impurities in Graphene: Structural, Electronic and Magnetic Properties

We present a theoretical study using density functional calculations of the structural, electronic and magnetic properties of 3d transition metal, noble metal and Zn atoms interacting with carbon monovacancies in graphene. We pay special attention to the electronic and magnetic properties of these substitutional impurities and found that they can be fully understood using a simple model based on the hybridization between the states of the metal atom, particularly the d shell, and the defect levels associated with an unreconstructed D3h carbon vacancy. We identify three different regimes associated with the occupation of different carbon-metal hybridized electronic levels: (i) bonding states are completely filled for Sc and Ti, and these impurities are non-magnetic; (ii) the non-bonding d shell is partially occupied for V, Cr and Mn and, correspondingly, these impurties present large and localized spin moments; (iii) antibonding states with increasing carbon character are progressively filled for Co, Ni, the noble metals and Zn. The spin moments of these impurities oscillate between 0 and 1 Bohr magnetons and are increasingly delocalized. The substitutional Zn suffers a Jahn-Teller-like distortion from the C3v symmetry and, as a consequence, has a zero spin moment. Fe occupies a distinct position at the border between regimes (ii) and (iii) and shows a more complex behavior: while is non-magnetic at the level of GGA calculations, its spin moment can be switched on using GGA+U calculations with moderate values of the U parameter.Comment: 13 figures, 4 tables. Submitted to Phys. Rev. B on September 26th, 200

A project of a new detector for direct Dark Matter search: MACHe3

MACHe3 (MAtrix of Cells of superfluid He3) is a project of a new detector for direct Dark Matter (DM) search. A cell of superfluid He3 has been developed and the idea of using a large number of such cells in a high granularity detector is proposed.This contribution presents, after a brief description of the superfluid He3 cell, the simulation of the response of different matrix configurations allowing to define an optimum design as a function of the number of cells and the volume of each cell. The exclusion plot and the predicted interaction cross-section for the neutralino as a photino are presented.Comment: 8 pages, 7 figures, Proceedings of Dark Matter 2000 (Marina Del Rey, Los Angeles, USA, 02/23/2000-02/25/2000

Interlayer superfluidity in bilayer systems of fermionic polar molecules

We consider fermionic polar molecules in a bilayer geometry where they are oriented perpendicularly to the layers, which permits both low inelastic losses and superfluid pairing. The dipole-dipole interaction between molecules of different layers leads to the emergence of interlayer superfluids. The superfluid regimes range from BCS-like fermionic superfluidity with a high $T_c$ to Bose-Einstein (quasi-)condensation of interlayer dimers, thus exhibiting a peculiar BCS-BEC crossover. We show that one can cover the entire crossover regime under current experimental conditions.Comment: 4 pages, 4 figure

Landau levels of cold atoms in non-Abelian gauge fields

The Landau levels of cold atomic gases in non-Abelian gauge fields are analyzed. In particular we identify effects on the energy spectrum and density distribution which are purely due to the non-Abelian character of the fields. We investigate in detail non-Abelian generalizations of both the Landau and the symmetric gauge. Finally, we discuss how these non-Abelian Landau and symmetric gauges may be generated by means of realistically feasible lasers in a tripod scheme.Comment: 13 pages, 9 figure

Equivalence between the Lovelock-Cartan action and a constrained gauge theory

We show that the four-dimensional Lovelock-Cartan action can be derived from a massless gauge theory for the $SO(1,3)$ group with an additional BRST trivial part. The model is originally composed by a topological sector and a BRST exact piece and has no explicit dependence on the metric, the vierbein or a mass parameter. The vierbein is introduced together with a mass parameter through some BRST trivial constraints. The effect of the constraints is to identify the vierbein with some of the additional fields, transforming the original action into the Lovelock-Cartan one. In this scenario, the mass parameter is identified with Newton's constant while the gauge field is identified with the spin-connection. The symmetries of the model are also explored. Moreover, the extension of the model to a quantum version is qualitatively discussed.Comment: 17 pages. No figures. Final version accepted for publication at the EPJ