278 research outputs found
Magneto-elastic coupling and competing entropy changes in substituted CoMnSi metamagnets
We use neutron diffraction, magnetometry and low temperature heat capacity to
probe giant magneto-elastic coupling in CoMnSi-based antiferromagnets and to
establish the origin of the entropy change that occurs at the metamagnetic
transition in such compounds. We find a large difference between the electronic
density of states of the antiferromagnetic and high magnetisation states. The
magnetic field-induced entropy change is composed of this contribution and a
significant counteracting lattice component, deduced from the presence of
negative magnetostriction. In calculating the electronic entropy change, we
note the importance of using an accurate model of the electronic density of
states, which here varies rapidly close to the Fermi energy.Comment: 11 pages, 9 figures. Figures 4 and 6 were updated in v2 of this
preprint. In v3, figures 1 and 2 have been updated, while Table II and the
abstract have been extended. In v4, Table I has updated with relevant neutron
diffraction dat
New dextran coated activated carbons for medical use
Activated carbon (AC) can be used for blood purification (hemoperfusion) to treat a range of conditions by direct perfusion of blood through an adsorbent column. The clinical effects of hemoperfusion relate to the AC adsorptive capacity, and any inflammatory response generated by direct blood contact
Giant Barocaloric Effect at the Spin Crossover Transition of a Molecular Crystal
The first experimental evidence for a giant, conventional barocaloric effect (BCE) associated with a pressure‐driven spin crossover transition near room temperature is provided. Magnetometry, neutron scattering, and calorimetry are used to explore the pressure dependence of the SCO phase transition in polycrystalline samples of protonated and partially deuterated [FeL2][BF4]2 [L = 2,6‐di(pyrazol‐1‐yl)pyridine] at applied pressures of up to 120 MPa (1200 bar). The data indicate that, for a pressure change of only 0–300 bar (0–30 MPa), an adiabatic temperature change of 3 K is observed at 262 K or 257 K in the protonated and deuterated materials, respectively. This BCE is equivalent to the magnetocaloric effect (MCE) observed in gadolinium in a magnetic field change of 0–1 Tesla. The work confirms recent predictions that giant, conventional BCEs will be found in a wide range of SCO compounds
Observational Limit on Gravitational Waves from Binary Neutron Stars in the Galaxy
Using optimal matched filtering, we search 25 hours of data from the LIGO
40-meter prototype laser interferometric gravitational-wave detector for
gravitational-wave chirps emitted by coalescing binary systems within our
Galaxy. This is the first test of this filtering technique on real
interferometric data. An upper limit on the rate R of neutron star binary
inspirals in our Galaxy is obtained: with 90% confidence, R< 0.5/hour. Similar
experiments with LIGO interferometers will provide constraints on the
population of tight binary neutron star systems in the Universe.Comment: RevTeX, minor revisions, exactly as published in PRL 83 (1999) p1498,
4 pages, 2 figures include
Measuring anisotropic scattering in the cuprates
A simple model of anisotropic scattering in a quasi two-dimensional metal is
studied. Its simplicity allows an analytic calculation of transport properties
using the Boltzmann equation and relaxation time approximation. We argue that
the c-axis magnetoresistance provides the key test of this model of transport.
We compare this model with experiments on overdoped Tl-2201 and find reasonable
agreement using only weak scattering anisotropy. We argue that optimally doped
Tl-2201 should show strong angular-dependent magnetoresistance within this
model and would provide a robust way of determining the in-plane scattering
anisotropy in the cuprates.Comment: 12 pages, 8 figures, typset in REVTeX 4. Version 2; added references
and corrected typo
Impurity and strain effects on the magnetotransport of La1.85Sr0.15Cu(1-y)Zn(y)O4 films
The influence of zinc doping and strain related effects on the normal state
transport properties(the resistivity, the Hall angle and the orbital magneto-
resistance(OMR) is studied in a series of La1.85Sr0.15Cu(1-y)Zn(y)O4 films with
values of y between 0 and 0.12 and various degrees of strain induced by the
mismatch between the films and the substrate. The zinc doping affects only the
constant term in the temperature dependence of cotangent theta but the strain
affects both the slope and the constant term, while their ratio remains
constant.OMR is decreased by zinc doping but is unaffected by strain. The ratio
delta rho/(rho*tan^2 theta) is T-independent but decreases with impurity
doping. These results put strong constraints on theories of the normal state of
high- temperature superconductors
Quantum and Topological Criticalities of Lifshitz Transition in Two-Dimensional Correlated Electron Systems
We study electron correlation effects on quantum criticalities of Lifshitz
transitions at zero temperature, using the mean-field theory based on a
preexisting symmetry-broken order, in two-dimensional systems. In the presence
of interactions, Lifshitz transitions may become discontinuous in contrast to
the continuous transition in the original proposal by Lifshitz for
noninteracting systems. We focus on the quantum criticality at the endpoint of
discontinuous Lifshitz transitions, which we call the marginal quantum critical
point. It shows remarkable criticalities arising from its nature as a
topological transition. At the point, for the canonical ensemble, the
susceptibility of the order parameter chi is found to diverge as ln 1/|delta
Delta| when the ``neck'' of the Fermi surface collapses at the van Hove
singularity. More remarkably, it diverges as 1/|delta Delta| when the
electron/hole pocket of the Fermi surface vanishes. Here delta Delta is the
amplitude of the mean field measured from the Lifshitz critical point. On the
other hand, for the grand canonical ensemble, the discontinuous transitions
appear as the electronic phase separation and the endpoint of the phase
separation is the marginal quantum critical point. Especially, when a pocket of
the Fermi surface vanishes, the uniform charge compressibility kappa diverges
as 1/|delta n|, instead of chi, where delta n is the electron density measured
from the critical point. Accordingly, Lifshitz transition induces large
fluctuations represented by diverging chi and/or kappa. Such fluctuations must
be involved in physics of competing orders and influence diversity of strong
correlation effects.Comment: 16 pages, 15 figures, to appear in Jounal of the Physical Society of
Japa
Heat-capacity anomalies at and in the ferromagnetic superconductor UGe
The heat-capacity and magnetization measurements under high pressure have
been carried out in a ferromagnetic superconductor UGe. Both measurements
were done using a same pressure cell in order to obtain both data for one
pressure. Contrary to the heat capacity at ambient pressure, an anomaly is
found in the heat capacity at the characteristic temperature where the
magnetization shows an anomalous enhancement under high pressure where the
superconductivity appears. This suggests that a thermodynamic phase transition
takes place at at least under high pressure slightly below
where becomes zero. The heat-capacity anomaly associated with the
superconducting transition is also investigated, where a clear peak of is
observed in a narrow pressure region ( GPa) around
contrary to the previous results of the resistivity measurement.
Present results suggest the importance of the thermodynamic critical point
for the appearance of the superconductivity.Comment: 4 pages, 4 figures, to appear in Phys. Rev. B, Rapid Communication
Synthesis of the polymerizable room temperature ionic liquid AMPS – TEA and superabsorbency for organic liquids of its copolymeric gels with acrylamide
A polymerizable room temperature ionic liquid (RTIL), 2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS) – triethylamine (TEA), was synthesized by neutralization of AMPS with TEA in acetone followed by evaporation of the solvent under a reduced pressure at room temperature. The RTIL was characterized with fourier transform infrared spectroscopy, differential scanning calorimetry (DSC), and 1H NMR. Co-polymeric gels of the RTIL with acrylamide (AAm) were prepared by aqueous solution polymerization using N,N′-methylenebisacrylamide as a crosslinker, and ammonium persulfate as an initiator. Superabsorbency of the gels in aqueous and a series of organic liquids was investigated gravimetrically. DSC data showed that the glass transition temperature of AMPS – TEA was 59.4 °C. Poly (AMPS – TEA-co-AAm) gels exhibited superabsorbency in both water and a series of organic solvents. The mechanism for swelling in aqueous and organic media of the gels was critically discussed
Split transition in ferromagnetic superconductors
The split superconducting transition of up-spin and down-spin electrons on
the background of ferromagnetism is studied within the framework of a recent
model that describes the coexistence of ferromagnetism and superconductivity
induced by magnetic fluctuations. It is shown that one generically expects the
two transitions to be close to one another. This conclusion is discussed in
relation to experimental results on URhGe. It is also shown that the magnetic
Goldstone modes acquire an interesting structure in the superconducting phase,
which can be used as an experimental tool to probe the origin of the
superconductivity.Comment: REVTeX4, 15 pp, 7 eps fig
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