418 research outputs found
Velocity dependence of friction of confined polymers
We present molecular dynamics friction calculations for confined hydrocarbon
solids with molecular lengths from 20 to 1400 carbon atoms. Two cases are
considered: (a) polymer sliding against a hard substrate, and (b) polymer
sliding on polymer. We discuss the velocity dependence of the frictional shear
stress for both cases. In our simulations, the polymer films are very thin
(approx. 3 nm), and the solid walls are connected to a thermostat at a short
distance from the polymer slab. Under these circumstances we find that
frictional heating effects are not important, and the effective temperature in
the polymer film is always close to the thermostat temperature. In the first
setup (a), for hydrocarbons with molecular lengths from 60 to 1400 carbon
atoms, the shear stresses are nearly independent of molecular length, but for
the shortest hydrocarbon C20H42 the frictional shear stress is lower. In all
cases the frictional shear stress increases monotonically with the sliding
velocity. For polymer sliding on polymer [case (b)] the friction is much
larger, and the velocity dependence is more complex. For hydrocarbons with
molecular lengths from 60 to 140 C-atoms, the number of monolayers of lubricant
increases (abruptly) with increasing sliding velocity (from 6 to 7 layers),
leading to a decrease of the friction. Before and after the layering
transition, the frictional shear stresses are nearly proportional to the
logarithm of sliding velocity. For the longest hydrocarbon (1400 C-atoms) the
friction shows no dependence on the sliding velocity, and for the shortest
hydrocarbon (20 C-atoms) the frictional shear stress increases nearly linearly
with the sliding velocity.Comment: 10 pages, 14 figure
DEVELOPING THE METHODS OF FOOD PRESERVATIVES EXTRACTION FROM COMPLEX MATRICES FOR BIOASSAY PURPOSE
The presence of food additives in food products may be associated with the risk of their toxic effects on human body. Therefore, the study of approaches to testing their safety seems to be a particularly urgent task. The aim of this study was to determine the conditions for extracting food preservatives from the samples of preserved pureed vegetables for further bioassay of the extract obtained in the Allium test. Onion roots were used as a test object in this method. Two extraction methods of benzoic and sorbic acids added to pureed vegetables have been developed. Distilled water and acetone were used as extracting solutions. The extraction efficiency was evaluated on Shimadzu Prominence LC-20 liquid chromatograph (Japan) in the ultraviolet range, wavelength 235 nm (benzoic acid), 285 nm (sorbic acid). According to the results of studies using both water and acetone as extractants, the degree of preservatives extraction was approximately the same and quite high. In the quantitative calculation of the preservatives content in pureed vegetables, the value of the correction factor was 0.8. However, due to certain production characteristics of this product, i. e. the stage of cauliflower homogenization, obtaining an extract with acetone seems to be more acceptable for the Allium test conditions.The presence of food additives in food products may be associated with the risk of their toxic effects on human body. Therefore, the study of approaches to testing their safety seems to be a particularly urgent task. The aim of this study was to determine the conditions for extracting food preservatives from the samples of preserved pureed vegetables for further bioassay of the extract obtained in the Allium test. Onion roots were used as a test object in this method. Two extraction methods of benzoic and sorbic acids added to pureed vegetables have been developed. Distilled water and acetone were used as extracting solutions. The extraction efficiency was evaluated on Shimadzu Prominence LC-20 liquid chromatograph (Japan) in the ultraviolet range, wavelength 235 nm (benzoic acid), 285 nm (sorbic acid). According to the results of studies using both water and acetone as extractants, the degree of preservatives extraction was approximately the same and quite high. In the quantitative calculation of the preservatives content in pureed vegetables, the value of the correction factor was 0.8. However, due to certain production characteristics of this product, i. e. the stage of cauliflower homogenization, obtaining an extract with acetone seems to be more acceptable for the Allium test conditions
Infrared studies of a La_(0.67)Ca_(0.33)MnO_3 single crystal: Optical magnetoconductivity in a half-metallic ferromagnet
The infrared reflectivity of a La_(0.67)Ca_(0.33)MnO_3 single crystal is studied over a broad range of temperatures (78–340 K), magnetic fields (0–16 T), and wave numbers (20–9000cm^(-1)). The optical conductivity gradually changes from a Drude-like behavior to a broad peak feature near 5000cm-1 in the ferromagnetic state below the Curie temperature T_C=307K. Various features of the optical conductivity bear striking resemblance to recent theoretical predictions based on the interplay between the double exchange interaction and the Jahn-Teller electron-phonon coupling. A large optical magnetoconductivity is observed near T_C
Infrared Studies of a La_{0.67}Ca_{0.33}MnO_3 Single Crystal: Optical Magnetoconductivity in a Half-Metallic Ferromagnet
The infrared reflectivity of a single crystal
is studied over a broad range of temperatures (78-340 K), magnetic fields (0-16
T), and wavenumbers (20-9000 cm). The optical conductivity gradually
changes from a Drude-like behavior to a broad peak feature near 5000 cm
in the ferromagnetic state below the Curie temperature . Various
features of the optical conductivity bear striking resemblance to recent
theoretical predictions based on the interplay between the double exchange
interaction and the Jahn-Teller electron-phonon coupling. A large optical
magnetoconductivity is observed near .Comment: 4 pages, 4 figures, Latex, PostScript; The 7th Joint MMM-Intermag
Conference,San Francisco, January 6-9, 1998; The Int. Conf. on Strongly
Correlated Electron Systems, Paris, July 15-18,199
Defect-unbinding and the Bose-glass transition in layered superconductors
The low-field Bose-glass transition temperature in heavy-ion irradiated
Bi_2Sr_2CaCu_2O_8+d increases progressively with increasing density of
irradiation-induced columnar defects, but saturates for densities in excess of
1.5 x10^9 cm^-2. The maximum Bose-glass temperature corresponds to that above
which diffusion of two-dimensional pancake vortices between different vortex
lines becomes possible, and above which the ``line-like'' character of vortices
is lost. We develop a description of the Bose-glass line that is in excellent
quantitative agreement with the experimental line obtained for widely different
values of track density and material parameters.Comment: 4 pages, 4 figures, submitted to Phys. Rev. Let
Observation of the parallel-magnetic-field-induced superconductor-insulator transition in thin amorphous InO films
We study the response of a thin superconducting amorphous InO film with
variable oxygen content to a parallel magnetic field. A field-induced
superconductor-insulator transition (SIT) is observed that is very similar to
the one in normal magnetic fields. As the boson-vortex duality, which is the
key-stone of the theory of the field-induced SIT, is obviously absent in the
parallel configuration, we have to draw conclusion about the theory
insufficiency.Comment: 3 pages, 4 figure
Effective viscosity of confined hydrocarbons
We present molecular dynamics friction calculations for confined hydrocarbon films with molecular lengths from 20 to 1400 carbon atoms. We find that the logarithm of the effective viscosity ηeff for nanometer-thin films depends linearly on the logarithm of the shear rate: logηeff=C−nlogγ˙, where n varies from 1 (solidlike friction) at very low temperatures to 0 (Newtonian liquid) at very high temperatures, following an inverse sigmoidal curve. Only the shortest chain molecules melt, whereas the longer ones only show a softening in the studied temperature interval 0<T<900 K. The results are important for the frictional properties of very thin (nanometer) films and to estimate their thermal durability
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