The use of Hf-isotopes and high field strength elements to constrain magmatic processes and magma sources

Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences, 1989.Includes bibliographical references.by Vincentius Johannes Maria Salters.Ph.D

The composition and distribution of the rejuvenated component across the Hawaiian plume: Hf-Nd-Sr-Pb isotope systematics of Kaula lavas and pyroxenite xenoliths

Rejuvenated volcanism refers to the reemergence of volcanism after a hiatus of 0.5-2 Ma following the voluminous shield building stage of Hawaiian volcanoes. The composition of the rejuvenated source and its distribution relative to the center of the plu

Isotope and trace element insights into heterogeneity of subridge mantle

Author Posting. © American Geophysical Union, 2014. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 15 (2014): 2438–2453, doi:10.1002/2014GC005314.Geochemical data for abyssal peridotites are used to determine the relationship to mid-ocean ridge basalts from several locations at ridge segments on the SW Indian Ridge (SWIR), the Mid-Cayman-Rise (MCR), and the Mid-Atlantic Ridge (MAR). Based on chemical and petrological criteria peridotites are categorized as being either dominantly impregnated with melt or being residual after recent melting. Those that are considered impregnated with melt also have isotopic compositions similar to the basalts indicating impregnation by an aggregate MORB melt. A SWIR and MCR residual peridotite Nd-isotopic compositions partly overlap the Nd-isotopic compositions of the basalts but extend to more radiogenic compositions. The differences between peridotite and basalt Nd-isotopic compositions can be explained by incorporating a low-solidus component with enriched isotopic signature in the subridge mantle: a component that is preferentially sampled by the basalts. At the MAR, peridotites and associated basalts have overlapping Nd-isotopic compositions, suggesting a more homogeneous MORB mantle. The combined chemistry and petrography indicates a complex history with several depletion and enrichment events. The MCR data indicate that a low-solidus component can be a ubiquitous component of the asthenosphere. Residual abyssal peridotites from limited geographic areas also show significant chemical variations that could be associated with initial mantle heterogeneities related to events predating the ridge-melting event. Sm-Nd model ages for possible earlier depletion events suggest these could be as old as 2.4 Ga.The research was supported by NSF grants OCE 0241053 and OCE 0930429 to Salters and OCE 0827825 to Dick.2014-12-1

Domains of depleted mantle : new evidence from hafnium and neodymium isotopes

Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 12 (2011): Q08001, doi:10.1029/2011GC003617.Isotope systematics of basalts provide information on the distribution of mantle components and the length scale of mantle heterogeneity. To obtain this information, high data and sampling density are crucial. We present hafnium and neodymium isotope data on more than 400 oceanic volcanics. Over length scales of several hundred to over one thousand kilometers hafnium and neodymium isotopes of mid-ocean ridge basalts are correlated and form an array of parallel trends on a global scale. On a larger scale these domains differ in the amount of highly depleted mantle material with radiogenic hafnium and neodymium isotope ratios. Compared to the Atlantic and Indian Ocean basins the asthenosphere of the Pacific basin seems to have a more uniform and a less radiogenic Hf isotopic composition for a given Nd isotopic composition. The parallel arrays of mid-ocean ridge basalts provide strong constraints on the makeup of the MORB mantle and are evidence for the presence of a highly depleted and highly radiogenic neodymium and hafnium component. This component, because of its highly depleted character, is unrecognized in the strontium-neodymium-lead isotope systems alone. Alternatively, the parallel arrays can have an ancient origin of systematic variations in the degree of depletion. Each array then represents the variations in this fossil melting regime. Individual ocean island basalt suites display different slopes in hafnium-neodymium isotope space, which are also best explained by varying amounts of highly residual mantle rather than isotopic differences in enriched mantle components as previously invoked. The ocean island basalt arrays diverge at the depleted end and project to radiogenic compositions that are similar to those of the asthenosphere through which they travel. This is strong evidence that the plume material interacts with its surrounding mantle as it ascends. The isotopic compositions of the ocean island and ridge basalts suggest that their systematics are influenced by a heretofore unrecognized depleted component.This work was supported by NSF grants EAR 0635864 and OCE0648484 to V.S. and OCE0351437 to S.H

Isotopic constraints on the genesis and evolution of basanitic lavas at Haleakala, Island of Maui, Hawaii

© The Author(s), 2016. This is the author's version of the work and is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Geochimica et Cosmochimica Acta 195 (2016): 201-225, doi:10.1016/j.gca.2016.08.017.To understand the dynamics of solid mantle upwelling and melting in the Hawaiian plume, we present new major and trace element data, Nd, Sr, Hf, and Pb isotopic compositions, and 238U-230Th-226Ra and 235U-231Pa-227Ac activities for 13 Haleakala Crater nepheline normative basanites with ages ranging from ~900 to 4100 yr B.P.. These basanites of the Hana Volcanics exhibit an enrichment in incompatible trace elements and a more depleted isotopic signature than similarly aged Hawaiian shield lavas from Kilauea and Mauna Loa. Here we posit that as the Pacific lithosphere beneath the active shield volcanoes moves away from the center of the Hawaiian plume, increased incorporation of an intrinsic depleted component with relatively low 206Pb/204Pb produces the source of the basanites of the Hana Volcanics. Haleakala Crater basanites have average (230Th/238U) of 1.23 (n=13), average age-corrected (226Ra/230Th) of 1.25 (n=13), and average (231Pa/235U) of 1.67 (n=4), significantly higher than Kilauea and Mauna Loa tholeiites. U-series modeling shows that solid mantle upwelling velocity for Haleakala Crater basanites ranges from ~0.7 to 1.0 cm/yr, compared to ~10 to 20 cm/yr for tholeiites and ~1 to 2 cm/yr for alkali basalts. These modeling results indicate that solid mantle upwelling rates and porosity of the melting zone are lower for Hana Volcanics basanites than for shield-stage tholeiites from Kilauea and Mauna Loa and alkali basalts from Hualalai. The melting rate, which is directly proportional to both the solid mantle upwelling rate and the degree of melting, is therefore greatest in the center of the Hawaiian plume and lower on its periphery. Our results indicate that solid mantle upwelling velocity is at least 10 times higher at the center of the plume than at its periphery under Haleakala.Funding for this project was provided by NSF grants EAR-0001924 and EAR-9909473 to KWWS.2018-08-2

Transition from orogenic-like to anorogenic magmatism in the Southern Alps during the Early Mesozoic: Evidence from elemental and Nd-Sr-Hf-Pb isotope geochemistry of alkali-rich dykes from the Finero Phlogopite Peridotite, Ivrea–Verbano Zone

The Ivrea-Verbano Zone (IVZ) in the westernmost sector of the Southern Alps is an iconic upper mantle to lower continental crust sequence of the Adriatic Plate and provides a geological window into the tectono-magmatic events that occurred at the Gondwana–Laurussia boundary from Late Paleozoic to Early Mesozoic. In this work, we document new geochemical and Nd-Sr-Hf-Pb isotopic data for Early Mesozoic alkali-rich dyke swarms which intruded the Finero Phlogopite Peridotite (northern IVZ) to provide geological constraints on the nature, origin and evolution of Early Mesozoic magmatism in the Southern Alps. The studied dykes are amphibole-phlogopite-bearing and show geochemical features varying between two end-member groups. A dyke group is characterized by HFSE-poor, Al-rich amphibole (Al2O3 up to 16 wt.%) with high LILE and LREE contents, high radiogenic 87Sr/86Sr(i) (0.704732 to 0.704934) and low radiogenic Nd isotopes (εNd(i) from –0.1 to –0.7), which support the occurrence of significant amounts of recycled continental crust components in the parental mantle melts and impart an overall “orogenic-like” affinity. This dyke group was largely derived from metasomatized lithospheric mantle sources. The second group is HFSE-rich with Al-poorer amphibole enriched in LILE and LREE, low radiogenic 87Sr/86Sr(i) (0.703761–0.704103) and higher radiogenic Nd isotopes (εNd(i) from +3.4 to +5.4) pointing to an “anorogenic” alkaline affinity and asthenospheric to deep lithospheric mantle sources. Some dykes show both orogenic and anorogenic affinities, providing evidence that the orogenic-like magmatism in the IVZ predates the alkaline anorogenic magmatism. The Finero dyke swarms therefore record a geochemical change of the Early Mesozoic magmatism of the Southern Alps from orogenic-like magmatism, typical of post-collisional settings, to anorogenic alkaline magmatism, common in intraplate to extensional settings, and places a temporal correlation of Early Mesozoic magmatism in the IVZ to those in the eastern and central sectors of the Southern Alps

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Capillary electrophoresis-high resolution sector field inductively coupled plasma mass spectrometry

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