Highly Reliable Quadruple-Node Upset-Tolerant D-Latch

This work was supported in part by the Spanish MCIN/AEI /10.13039/501100011033/ FEDER under Grant PID2020-117344RB-I00, and in part by the Regional Government under Grant P20_00265 and Grant P20_00633.As CMOS technology scaling pushes towards the reduction of the length of transistors, electronic circuits face numerous reliability issues, and in particular nodes of D-latches at nano-scale confront multiple-node upset errors due to their operation in harsh radiative environments. In this manuscript, a new high reliable D-latch which can tolerate quadruple-node upsets is presented. The design is based on a low-cost single event double-upset tolerant (LSEDUT) cell and a clock-gating triple-level soft-error interceptive module (CG-SIM). Due to its LSEDUT base, it can tolerate two upsets, but the combination of two LSEDUTs and the triple-level CG-SIM provides the proposed D-latch with remarkable quadruple-node upsets (QNU) tolerance. Applying LSEDUTs for designing a QNU-tolerant D-latch improves considerably its features; in particular, this approach enhances its reliability against process variations, such as threshold voltage and (W/L) transistor variability, compared to previous QNU-tolerant D-latches and double-node-upset tolerant latches. Furthermore, the proposed D-latch not only tolerates QNUs, but it also features a clear advantage in comparison with the previous clock gating-based quadruple-node-upset-tolerant (QNUTL-CG) D-latch: it can mask single event transients. Speci c gures of merit endorse the gains introduced by the new design: compared with the QNUTL-CG D-latch, the improvements of the maximum standard deviations of the gate delay, induced by threshold voltage and (W/L) transistors variability of the proposed D-latch, are 13.8% and 5.7%, respectively. Also, the proposed D-latch has 23% lesser maximum standard deviation in power consumption, resulting from threshold voltage variability, when compared to the QNUTL-CG D-latch.Spanish MCIN/AEI /10.13039/501100011033/ FEDER under Grant PID2020-117344RB-I00Regional Government under Grant P20_00265 and Grant P20_0063

Molecularly imprinted silica films prepared by electroassisted deposition for the selective detection of dopamine

Dopamine (DA) can be detected by electrochemical oxidation in conventional electrodes. However, the presence of other oxidizable species (interferents) usually present in physiological fluids at high concentrations (like ascorbic acid) makes very difficult its electrochemical detection. In the present work, glassy carbon electrodes have been modified with molecularly imprinted silica (MIS) films prepared by electroassisted deposition of sol–gel precursors. The production of MIS films was performed by adding the template molecule (DA) to the precursor sol. The molecular impression of silica was assessed showing a high coherency allowing a filtering capacity in the molecular scale. The MIS-modified electrodes present a high selectivity for the detection of DA in neutral or acidic solutions. The MIS-modified electrodes allow the amperometric determination of dopamine in solutions containing ascorbic acid with molar ratios lower than 1:50,000.We acknowledge the financial support from the Fundación Ramón Areces (CIVP16A1821), Spanish Ministerio de Economía y Competitividad (MAT2013-42007-P) and Generalitat Valenciana (PROMETEO2013/038)

Synthesis of a thermoresponsive crosslinked MEO2MA polymer coating on microclusters of iron oxide nanoparticles

Encapsulation of magnetic nanoparticles (MNPs) of iron (II, III) oxide ( Fe3O4) with a thermopolymeric shell of a crosslinked poly(2-(2-methoxyethoxy)ethyl methacrylate) P(MEO2MA) is successfully developed. Magnetic aggregates of large size, around 150–200 nm are obtained during the functionalization of the iron oxide NPs with vinyl groups by using 3-butenoic acid in the presence of a water soluble azo-initiator and a surfactant, at 70 °C. These polymerizable groups provide a covalent attachment of the P(MEO2MA) shell on the surface of the MNPs while a crosslinked network is achieved by including tetraethylene glycol dimethacrylate in the precipitation polymerization synthesis. Temperature control is used to modulate the swelling-to-collapse transition volume until a maximum of around 21:1 ratio between the expanded: shrunk states (from 364 to 144 nm in diameter) between 9 and 49 °C. The hybrid Fe3O4@ P(MEO2MA) microgel exhibits a lower critical solution temperature of 21.9 °C below the corresponding value for P(MEO2MA) (bulk, 26 °C). The MEO2MA coating performance in the hybrid microgel is characterized by dynamic light scattering and transmission electron microscopy. The content of preformed MNPs [up to 30.2 (wt%) vs. microgel] was established by thermogravimetric analysis while magnetic properties by vibrating sample magnetometry.Andalusian Knowledge AgencyEuropean Commission 291780Ministry of Economy, Innovation, Science and Employment of the Junta de AndalucíaSpanish "Ministerio de Economía y Competitividad" PID2019-103938RB-I00 CTQ2017-86125-PJunta de Andalucía B-FQM-243-UGR18 P18-RT-2961CEI-Biotic CEI2013-MP-1

Comparison of Laser-Synthetized Nanographene-Based Electrodes for Flexible Supercapacitors

In this paper, we present a comparative study of a cost-effective method for the mass fabrication of electrodes to be used in thin-film flexible supercapacitors. This technique is based on the laser-synthesis of graphene-based nanomaterials, specifically, laser-induced graphene and reduced graphene oxide. The synthesis of these materials was performed using two different lasers: a CO2 laser with an infrared wavelength of λ = 10.6 µm and a UV laser (λ = 405 nm). After the optimization of the parameters of both lasers for this purpose, the performance of these materials as bare electrodes for flexible supercapacitors was studied in a comparative way. The experiments showed that the electrodes synthetized with the low-cost UV laser compete well in terms of specific capacitance with those obtained with the CO2 laser, while the best performance is provided by the rGO electrodes fabricated with the CO2 laser. It has also been demonstrated that the degree of reduction achieved with the UV laser for the rGO patterns was not enough to provide a good interaction electrode-electrolyte. Finally, we proved that the specific capacitance achieved with the presented supercapacitors can be improved by modifying the in-planar structure, without compromising their performance, which, together with their compatibility with doping-techniques and surface treatments processes, shows the potential of this technology for the fabrication of future high-performance and inexpensive flexible supercapacitors.Spanish Ministry of Universities FPU16/01451University of Granada PPJIB2019-05Spanish Ministry of Science/FEDER-EU TEC2017-89955-PMexican Government through Conacyt A1-S-3553

Lanthanide(III) Ions and 5-Methylisophthalate Ligand Based Coordination Polymers: An Insight into Their Photoluminescence Emission and Chemosensing for Nitroaromatic Molecules

Acknowledgments: O.P.C. is grateful to the UPV/EHU for his predoctoral grant. S.R. acknowledges the Juan de la Cierva Incorporación Fellowship (grant agreement no. IJC2019-038894-I). The authors thank the technical and human support provided by SGIker (UPV/EHU/ERDF, EU).Funding: This work has been funded by University of the Basque Country (GIU20/028), Gobierno Vasco/Eusko Jaurlaritza (IT1755-22 and IT1500-22), Junta de Andalucía (FQM-394 and B-FQM- 734-UGR20, B-FQM-478-UGR20 and ProyExcel_00386) and the Spanish Ministry of Economy and Competitiveness (MCIU/AEI/FEDER, UE) (PGC2018-102052-A-C22, PGC2018-102052-B-C21 and PID2020-117344RB-I00).The work presented herein reports on the synthesis, structural and physico-chemical characterization, luminescence properties and luminescent sensing activity of a family of isostructural coordination polymers (CPs) with the general formula [Ln2(μ4-5Meip)3(DMF)]n (where Ln(III) = Sm (1Sm), Eu (2Eu), Gd (3Gd), Tb (4Tb) and Yb (5Yb) and 5Meip = 5-methylisophthalate, DMF = N,N-dimethylmethanamide). Crystal structures consist of 3D frameworks tailored by the linkage between infinite lanthanide(III)-carboxylate rods by means of the tetradentate 5Meip ligands. Photoluminescence measurements in solid state at variable temperatures reveal the best-in-class properties based on the capacity of the 5Meip ligand to provide efficient energy transfers to the lanthanide(III) ions, which brings intense emissions in both the visible and near-infrared (NIR) regions. On the one hand, compound 5Yb displays characteristic lanthanide-centered bands in the NIR with sizeable intensity even at room temperature. Among the compounds emitting in the visible region, 4Tb presents a high QY of 63%, which may be explained according to computational calculations. At last, taking advantage of the good performance as well as high chemical and optical stability of 4Tb in water and methanol, its sensing capacity to detect 2,4,6-trinitrophenol (TNP) among other nitroaromatic-like explosives has been explored, obtaining high detection capacity (with Ksv around 105 M−1), low limit of detection (in the 10−6–10−7 M) and selectivity among other molecules (especially in methanol).University of the Basque Country (GIU20/028)Gobierno Vasco/Eusko Jaurlaritza (IT1755-22 and IT1500-22)Junta de Andalucía (FQM-394 and B-FQM- 734-UGR20, B-FQM-478-UGR20 and ProyExcel_00386)Spanish Ministry of Economy and Competitiveness (MCIU/AEI/FEDER, UE) (PGC2018-102052-A-C22, PGC2018-102052-B-C21 and PID2020-117344RB-I00

Monitoring of degradation of porous silicon photonic crystals using digital photography

We report the monitoring of porous silicon (pSi) degradation in aqueous solutions using a consumer-grade digital camera. To facilitate optical monitoring, the pSi samples were prepared as one-dimensional photonic crystals (rugate filters) by electrochemical etching of highly doped p-type Si wafers using a periodic etch waveform. Two pSi formulations, representing chemistries relevant for self-reporting drug delivery applications, were tested: freshly etched pSi (fpSi) and fpSi coated with the biodegradable polymer chitosan (pSi-ch). Accelerated degradation of the samples in an ethanol-containing pH 10 aqueous basic buffer was monitored in situ by digital imaging with a consumer-grade digital camera with simultaneous optical reflectance spectrophotometric point measurements. As the nanostructured porous silicon matrix dissolved, a hypsochromic shift in the wavelength of the rugate reflectance peak resulted in visible color changes from red to green. While the H coordinate in the hue, saturation, and value (HSV) color space calculated using the as-acquired photographs was a good monitor of degradation at short times (t  pSi-ch.We acknowledge the financial support from Ministerio de Educación y Ciencia (Spain), Dirección General de Enseñanza Superior (Spain) (CTQ2009-14428-C02-01), and Junta de Andalucía (Spain) (P10-FQM-5974). A.N. wants to acknowledge Fundación Alfonso Martín Escudero for a postdoctoral fellowship. This material is based upon the work supported by the U.S. National Science Foundation under Grant No. DMR-1210417

A versatile wearable based on reconfigurable hardware for biomedical measurements

In this work a versatile hardware platform based on reconfigurable devices is presented. This platform it intended for the acquisition of multiple biosignals, only requiring a reconfiguration to switch applications. This prototype has been combined with graphene-based, flexible electrodes to cover the application to different biosignals presented in this paper, which are electrocardiogram, electrooculogram and electromyogram. The features of this system provide to the user and to medical personnel a complete set of diagnosis tools, available both at home and hospitals, to be used as a triage tool and for remote patient monitoring. Additionally, an Android application has been developed for signal processing and data presentation to the user. The results obtained demonstrate the wide range of possibilities in portable/wearable applications of the combination of reconfigurable devices and flexible electronics, especially for the remote monitoring of patients using multiple biosignals of interest. The versatility of this device makes it a complete set of monitoring tools integrated in a reduced size device

Laser-synthesis of conductive carbon-based materials from two flexible commercial substrates: A comparison

One of the key challenges in the field of flexible electronics relies on finding conductive materials that can withstand bending and stretching stresses while maintaining their performance. In this context, this work presents a comparative study of laser-induced conductive materials from the direct laser-scribing of two commercial flexible films: the benchmark Kapton® HN polyimide (PI) precursor and the UltemTM 1000 polyetherimide (PEI) alternative contender. The synthesis process on both materials is optimized in terms of electrical conductivity using a high-performance galvanometric laser with a wavelength of 532 nm for the fabrication of multiple samples at different laser powers and speeds. The samples are structurally characterized using Scanning Electron Microscopy (SEM), Raman spectroscopy, X-ray Photoelectron Spectroscopy (XPS), and Fourier-Transform Infrared Spectroscopy (FTIR) aiming at understanding the chemical and physical changes of the ablated material. The results demonstrate that the proposed setup is feasible for the synthesis of uniform and reliable conductive patterns on the surface of both substrates with high reproducibility. In particular, it is proved that PEI is more suitable precursor for flexible electronics applications which demand high electrical conductivity, leading to a sheet resistance of 3.62 ± 0.35 Ω/sq at 0.8 W and 5 mm/s once the laser-synthesis process is optimized (against the 6.04 ± 0.63 Ω/sq at 0.6 W and 5 mm/s offered by the LIG on PI). The performance of both laser-induced patterns as electrodes for the fabrication of electrochemical capacitors is also studied and compared in terms of areal specific capacitance.FEDER/Junta de Andalucía-Consejería de Transformaci´on Econ´omica, IndustriaConocimiento y Universidades Project P20_00265 and Project BRNM-680-UGR20; Project TED2021-129949A-I00MCIN/AEI/10.13039/ 501100011033European Union NextGenerationEU/PRTRGrant PID2020-117344RB-I00MCIN/AEI 10.13039/ 501100011033Junta de Andalucía – Consejería de Universidad, Investigaci´on e Innovaci´on through the project ProyExcel_00268Spanish Ministry of Sciences and Innovation through the Ram´on y Cajal fellow RYC2019- 027457-I,María Zambrano fellow C21.I4.P1grant PRE2021-096886

In-Depth Study of Laser Diode Ablation of Kapton Polyimide for Flexible Conductive Substrates

This work presents a detailed study of the photothermal ablation of KaptonR polyimide by a laser diode targeting its electrical conductivity enhancement. Laser-treated samples were structurally characterized using Scanning Electron Microscopy (SEM), Raman spectroscopy, X-ray Photoelectron Spectroscopy (XPS), as well as Diffuse Reflectance Infrared Fourier Transform (DRIFT) spectroscopy. The results show that the laser-assisted ablation constitutes a simple one-step and environmental friendly method to induce graphene-derived structures on the surface of polyimide films. The laser-modified surface was also electrically characterized through the Transmission Line Method (TLM) aiming at the improvement of the conductivity of the samples by tuning the laser power and the extraction of the contact resistance of the electrodes. Once the laser-ablation process is optimized, the samples increase their conductivity up to six orders of magnitude, being comparable to that of graphene obtained by chemical vapor deposition or by the reduction of graphene-oxide. Additionally, we show that the contact resistance can be decreased down to promising values of ~2 W when using silver-based electrodes.This work has been partially supported by the Spanish Ministry of Education, Culture and Sport (MECD), the European Union and the University of Granada through the project TEC2017-89955-P, the pre-doctoral grant FPU16/01451, the fellowship H2020-MSCA-IF-2017 794885-SELFSENS and the grant “Initiation to Research”. Additionally, this work was supported by the German Research Foundation (DFG) and the Technical University of Munich within the Open Access Publishing Funding Programme

Flexible and robust laser-induced graphene heaters photothermally scribed on bare polyimide substrates

We demonstrate the feasibility of fabricating cost-effective and robust laser-induced graphene (LIG) flexible heaters with an innovative technique based on the photothermal production of graphene with a foam-like morphology. The produced devices are precisely defined on a bare polyimide substrate without the need of photomasks by employing a computer numerical control (CNC) driven laser diode. The electrical properties of the LIG-based heaters can be tailored by adjusting the laser power. The resulting conductive material exhibits electrical and chemical properties which are similar to the ones for graphene such as a negative temperature coefficient of −0.46 m°C−1 and a maximum operating temperature of around 400 °C. The developed heaters can outperform the existing emerging technologies showing a very rapid and stable response up to 225 °C with the extra features of flexibility, biocompatibility, and environmental friendliness