Microplastic fibres from synthetic textiles: Environmental degradation and additive chemical content

Microplastic fibres (MPFs) often make up the largest fraction of microplastic pollution in aquatic environments, yet little is known about their degradative fate and persistence. This study investigates the environmentally relevant photodegradation of common MPFs: polyester (PET), polyamide (PA) and polyacrylonitrile (PAN), their respective additive chemical profile, together with their potential for additive leaching. MPFs were subject to ultraviolet (UV) exposure in seawater and freshwater media over 10 months. PET and PA MPFs showed significant fragmentation and surface changes following UV exposure, additionally PA showed evidence of chemical changes. PAN did not undergo significant photodegradation in the same exposure period. Chemicals tentatively identified in MPFs and aqueous leachates via non-target gas chromatography-mass spectrometry include monomers, UV stabilisers and degradation products. Characterisation of several bisphenols (BPs) and benzophenones (BzPs) was performed via ultraperformance liquid chromatography tandem mass spectrometry. Bisphenol A, bisphenol S and benzophenone-3 were quantified in all MPFs and wool at concentrations between 4.3 - 501 ng/g, with wool displaying the highest sum concentration of BPs and BzPs at 863 and 27 ng/g, respectively.publishedVersio

Eldre jernalders tjæreproduksjon ut av tåken. Om tidlig norsk tjæreproduksjon med utgangspunkt i et funn på Averøy i Møre og Romsdal

For many years it has been well known that tar was an available commodity in the Norwegian Iron Age, but until recently no production site or installation for such production was known. In this paper two recently discovered tar production sites, in south-eastern and mid-Norway respectively, are presented and discussed. Both are clay-lined funnel-shaped pits that are dug into the ground with an upper part where the wood was stacked and lit, and a lower part where the tar was collected in a container. The Norwegian tar production pits are similar to contemporary Swedish ones found in large numbers in mid-Sweden. The type is also known from the eastern part of Central Europe where they came into use a few centuries later than in Scandinavia.&nbsp

Accelerated hydrolysis method for producing partially degraded polyester microplastic fiber reference materials

Microplastic fibers (MPFs) from textiles significantly contribute to the microplastic (MP) load in many environmental matrices and have been shown to negatively impact the organisms therein. Most fate and effect studies to date rely on pristine reference MP materials that have limited relevance compared with the partially degraded MP particles and fibers typically present in the natural environment. The current study aimed to develop and validate a rapid method to generate environmentally relevant polyester (PET) MPF reference material with controllable levels of degradation. Importantly, the method produced the same degradation products (terephthalic acid (TA) and ethylene glycol (EG)) as those generated during natural UV (sunlight) exposure of PET. Alkaline hydrolysis provided linearly increasing degrees of degraded PET MPFs over just a few hours, with full decomposition into molecular fragments occurring after 3 h. The extent of physical degradation was determined by scanning electron microscopy, whereas chemical degradation was quantified by measuring the production of TA and EG degradation products. The proposed accelerated hydrolysis degradation method is relevant for producing partially degraded PET MPF reference materials for use in fate and effect studies

Microplastic fibres from synthetic textiles: Environmental degradation and additive chemical content

Microplastic fibres (MPFs) often make up the largest fraction of microplastic pollution in aquatic environments, yet little is known about their degradative fate and persistence. This study investigates the environmentally relevant photodegradation of common MPFs: polyester (PET), polyamide (PA) and polyacrylonitrile (PAN), their respective additive chemical profile, together with their potential for additive leaching. MPFs were subject to ultraviolet (UV) exposure in seawater and freshwater media over 10 months. PET and PA MPFs showed significant fragmentation and surface changes following UV exposure, additionally PA showed evidence of chemical changes. PAN did not undergo significant photodegradation in the same exposure period. Chemicals tentatively identified in MPFs and aqueous leachates via non-target gas chromatography-mass spectrometry include monomers, UV stabilisers and degradation products. Characterisation of several bisphenols (BPs) and benzophenones (BzPs) was performed via ultraperformance liquid chromatography tandem mass spectrometry. Bisphenol A, bisphenol S and benzophenone-3 were quantified in all MPFs and wool at concentrations between 4.3 - 501 ng/g, with wool displaying the highest sum concentration of BPs and BzPs at 863 and 27 ng/g, respectively

Microplastic fibres from synthetic textiles: Environmental degradation and additive chemical content

Microplastic fibres (MPFs) often make up the largest fraction of microplastic pollution in aquatic environments, yet little is known about their degradative fate and persistence. This study investigates the environmentally relevant photodegradation of common MPFs: polyester (PET), polyamide (PA) and polyacrylonitrile (PAN), their respective additive chemical profile, together with their potential for additive leaching. MPFs were subject to ultraviolet (UV) exposure in seawater and freshwater media over 10 months. PET and PA MPFs showed significant fragmentation and surface changes following UV exposure, additionally PA showed evidence of chemical changes. PAN did not undergo significant photodegradation in the same exposure period. Chemicals tentatively identified in MPFs and aqueous leachates via non-target gas chromatography-mass spectrometry include monomers, UV stabilisers and degradation products. Characterisation of several bisphenols (BPs) and benzophenones (BzPs) was performed via ultraperformance liquid chromatography tandem mass spectrometry. Bisphenol A, bisphenol S and benzophenone-3 were quantified in all MPFs and wool at concentrations between 4.3 - 501 ng/g, with wool displaying the highest sum concentration of BPs and BzPs at 863 and 27 ng/g, respectively

Determination of steroid hormones in grey seal (Halichoerus grypus) blood plasma using convergence chromatography tandem mass spectrometry

A hybrid solid phase extraction (HybridSPE) protocol tailored to ultra-performance convergence chromatography tandem mass spectrometry (UPC2-MS/MS) was developed for the determination of 19 steroid hormones in grey seal (Halichoerus grypus) blood plasma. In this study, the protocol demonstrated acceptable absolute recoveries ranging from 33 to 90%. The chromatographic separation was carried out using a gradient elution program with a total run time of 5 min. The method repeatability ranged from 1.9% to 24% for most target analytes and the method limits of quantification (mLOQs) ranged from 0.03 to 1.67 ng/mL. A total of 9 plasma samples were analysed to demonstrate the applicability of the developed method in blood plasma from a wildlife species. A total of 13 steroid hormones were quantified in grey seal pup plasma. The most prevalent steroids: cortisol, cortisone, corticosterone, 11-deoxycortisol, progesterone and 17α-hydroxyprogesterone were detected at concentrations in the range of 9.09–40.1, 7.10–24.2, 0.742–10.7, 1.06–5.72, 0.38–4.38 and <mLOQ - 1.05 ng/mL, respectively. To our knowledge, this is the first study to determine steroid hormones in the plasma of pinnipeds using convergence chromatography