11 research outputs found
Inhibited Al diffusion and growth roughening on Ga-coated Al (100)
Ab initio calculations indicate that the ground state for Ga adsorption on Al
(100) is on-surface with local unit coverage. On Ga-coated Al (100), the bridge
diffusion barrier for Al is large, but the AlGa {\it exchange
barrier is zero}: the ensuing incorporation of randomly deposited Al's into the
Ga overlayer realizes a percolation network, efficiently recoated by Ga atoms.
Based on calculated energetics, we predict rough surface growth at all
temperatures; modeling the growth by a random deposition model with partial
relaxation, we find a power-law divergent roughness .Comment: 4 pages RevTeX-twocolumn, no figures. to appear in Phys. Rev. Lett.,
July 199
Theory of Adsorption and Surfactant Effect of Sb on Ag (111)
We present first-principles studies of the adsorption of Sb and Ag on clean
and Sb-covered Ag (111). For Sb, the {\it substitutional} adsorption site is
found to be greatly favored with respect to on-surface fcc sites and to
subsurface sites, so that a segregating surface alloy layer is formed. Adsorbed
silver adatoms are more strongly bound on clean Ag(111) than on Sb-covered Ag.
We propose that the experimentally reported surfactant effect of Sb is due to
Sb adsorbates reducing the Ag adatom mobility. This gives rise to a high
density of Ag islands which coalesce into regular layers.Comment: RevTeX 3.0, 11 pages, 0 figures] 13 July 199