15,685 research outputs found
A wave-mechanical treatment of the Mills-Nixon effect
The Mills-Nixon effect has been examined by a very simple wave-mechanical treatment. This has led to the conclusion that the effect of saturated side rings upon the ratio of the coefficients of the wave-functions of the two Kekulé structures is relatively small, being not more than about 6 per cent., and that the benzene ring retains the greater part of its stabilising resonance energy. Nevertheless, making the reasonable assumption that the ratio of the activation energies, for reaction as either one of the two Kekulé structures, depends upon the square of the ratio of coefficients, it is possible to account for the experimental facts. The effect which bending two valencies has upon the angles between the other valencies projecting from the benzene ring is found to be very small
The brightness distribution of IRC +10216 at 11 microns
The brightness distribution of IRC +10216 at a wavelength of 11 microns was measured in detail using a spatial interferometer. This brightness distribution appears to have azimuthal symmetry; an upper limit of 1.1 may be set to the ellipticity at 11 microns if the object has a major axis oriented either along or perpendicular to the major axis of the optical image. The radial distribution shows both compact and extended emission. The extended component, which is due to thermal emission from circumstellar dust, contributes 91% of the total flux and has a 1/e diameter of 0.90 minutes. The tapered shape of this component is consistent with a l/r squared dust density dependence. The compact component is unresolved (less than 0.2 minutes in diameter) and represents emission from the central star seen through the circumstellar envelope
Heterodyne detection of CO2 emission lines and wind velocities in the atmosphere of Venus
Strong 10 micrometer line emission from (c-12)(o-16)2 in the upper atmosphere of Venus was detected by heterodyne techniques. Observations of the absolute Doppler shift of the emission features indicate mean zonal wind velocities less than 10 m/sec in the upper atmosphere near the equator. No evidence was found of the 100 m/sec wind velocity implied by the apparent 4-day rotation period of ultraviolet cloud features
Heterodyne detection of CO2 emission lines and wind velocities in the atmosphere of Venus
Strong 10 micrometer line emission from (C-12)(O-16)2 in the upper atmosphere of Venus was detected by heterodyne techniques. Observations of the absolute Doppler shift of the emission features indicate mean zonal wind velocities less than 10 m/sec in the upper atmosphere near the equator. No evidence was found of the 100 m/sec wind velocity implied by the apparent 4-day rotation period of ultraviolet cloud features
Variations in the spatial distribution of 11 Micron radiation from omicron Ceti
The spatial distribution of 11 micron radiation from omicron Ceti was observed at various phases of its light cycle using a stellar interferometer. Changes were seen which can be attributed to variation in the strength of thermal emission from circumstellar dust relative to the stellar continuum at 11 microns. These changes are shown to be correlated with the changes in luminosity of micron Ceti in such a way that dust grain emission at 11 microns was increased more than the continuum during the period of maximum luminosity. The degree of the change in dust grain emission implies that the maximum dust temperature is in the range of 500 K to 700 K during minimum stellar luminosity
Spatial heterodyne interferometry of VY Canis Major's, alpha Orionis, alpha Scorpii, and R leonis at 11 microns
Using the technique of heterodyne interferometry, measurements were made of the spatial distribution of 11 micron radiation from four late type stars. The circumstellar shells surrounding VY Canis Majoris, alpha Orionis, and alpha Scorpii were resolved, whereas that of R Leonis was only partially resolved at a fringe spacing of 0.4 sec
Preliminary catalog of pictures taken on the lunar surface during the Apollo 15 mission
Catalog of all pictures taken from lunar module or lunar surface during Apollo 15 missio
Synthesizing Program Input Grammars
We present an algorithm for synthesizing a context-free grammar encoding the
language of valid program inputs from a set of input examples and blackbox
access to the program. Our algorithm addresses shortcomings of existing grammar
inference algorithms, which both severely overgeneralize and are prohibitively
slow. Our implementation, GLADE, leverages the grammar synthesized by our
algorithm to fuzz test programs with structured inputs. We show that GLADE
substantially increases the incremental coverage on valid inputs compared to
two baseline fuzzers
Large-Scale Image Processing with the ROTSE Pipeline for Follow-Up of Gravitational Wave Events
Electromagnetic (EM) observations of gravitational-wave (GW) sources would
bring unique insights into a source which are not available from either channel
alone. However EM follow-up of GW events presents new challenges. GW events
will have large sky error regions, on the order of 10-100 square degrees, which
can be made up of many disjoint patches. When searching such large areas there
is potential contamination by EM transients unrelated to the GW event.
Furthermore, the characteristics of possible EM counterparts to GW events are
also uncertain. It is therefore desirable to be able to assess the statistical
significance of a candidate EM counterpart, which can only be done by
performing background studies of large data sets. Current image processing
pipelines such as that used by ROTSE are not usually optimised for large-scale
processing. We have automated the ROTSE image analysis, and supplemented it
with a post-processing unit for candidate validation and classification. We
also propose a simple ad hoc statistic for ranking candidates as more likely to
be associated with the GW trigger. We demonstrate the performance of the
automated pipeline and ranking statistic using archival ROTSE data. EM
candidates from a randomly selected set of images are compared to a background
estimated from the analysis of 102 additional sets of archival images. The
pipeline's detection efficiency is computed empirically by re-analysis of the
images after adding simulated optical transients that follow typical light
curves for gamma-ray burst afterglows and kilonovae. We show that the automated
pipeline rejects most background events and is sensitive to simulated
transients to limiting magnitudes consistent with the limiting magnitude of the
images
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