Gas-Phase Photodegradation of Decane and Methanol on TiO_2: Dynamic Surface Chemistry Characterized by Diffuse Reflectance FTIR

Diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) was used to study illuminated TiO2 surfaces under both vacuum conditions, and in the presence of organic molecules (decane and methanol). In the presence of hole scavengers, electrons are trapped at Ti(III)–OH sites, and free electrons are generated. These free electrons are seen to decay by exposure either to oxygen or to heat; in the case of heating, reinjection of holes into the lattice by loss of sorbed hole scavenger leads to a decrease in Ti(III)–OH centers. Decane adsorption experiments lend support to the theory that removal of surficial hydrocarbon contaminants is responsible for superhydrophilic TiO2 surfaces. Oxidation of decane led to a mixture of surface-bound organics, while oxidation of methanol leads to the formation of surface-bound formic acid

Mixed-Metal Semiconductor Anodes for Electrochemical Water Splitting and Reactive Chlorine Species Generation: Implications for Electrochemical Wastewater Treatment

A procedure for the preparation of semiconductor anodes using mixed-metal oxides bound together and protected with a TiO_2 nanoglue has been developed and tested in terms of the relative efficiencies of the oxygen evolution (OER), the reactive chlorine species evolution (RCS), and the hydrogen evolution (HER) reactions. The composition of the first anode is a Ti metal substrate coated with IrTaO_x and overcoated with TiO_2 (P_(25)) that was mixed with TiO_2 nanogel, while the second anode consists of a Ti metal substrate coated with IrTaO_x and an over-coating layer of La-doped sodium tantalate, NaTaO_3:La. The experimental efficiencies for water splitting ranged from 62.4% to 67.5% for H_2 evolution and 40.6% to 60.0% for O_2 evolution. The corresponding over-potentials for the Ti/IrTa-TiO_2 and Ti/IrTa-NaTaO_3:La anodes coupled with stainless steel cathodes of the same dimensions were determined to be 437 mV and 367 mV for the OER, respectively, and 239 mV and 205 mV for RCS, respectively. The preparation procedure described herein should allow for easier production of large-surface area anodes at lower costs than standard methods

Two-Dimensional Dirac Fermions Protected by Space-Time Inversion Symmetry in Black Phosphorus

We report the realization of novel symmetry-protected Dirac fermions in a surface-doped two-dimensional (2D) semiconductor, black phosphorus. The widely tunable band gap of black phosphorus by the surface Stark effect is employed to achieve a surprisingly large band inversion up to ~0.6 eV. High-resolution angle-resolved photoemission spectra directly reveal the pair creation of Dirac points and their moving along the axis of the glide-mirror symmetry. Unlike graphene, the Dirac point of black phosphorus is stable, as protected by spacetime inversion symmetry, even in the presence of spin-orbit coupling. Our results establish black phosphorus in the inverted regime as a simple model system of 2D symmetry-protected (topological) Dirac semimetals, offering an unprecedented opportunity for the discovery of 2D Weyl semimetals

CongNaMul: A Dataset for Advanced Image Processing of Soybean Sprouts

We present 'CongNaMul', a comprehensive dataset designed for various tasks in soybean sprouts image analysis. The CongNaMul dataset is curated to facilitate tasks such as image classification, semantic segmentation, decomposition, and measurement of length and weight. The classification task provides four classes to determine the quality of soybean sprouts: normal, broken, spotted, and broken and spotted, for the development of AI-aided automatic quality inspection technology. For semantic segmentation, images with varying complexity, from single sprout images to images with multiple sprouts, along with human-labelled mask images, are included. The label has 4 different classes: background, head, body, tail. The dataset also provides images and masks for the image decomposition task, including two separate sprout images and their combined form. Lastly, 5 physical features of sprouts (head length, body length, body thickness, tail length, weight) are provided for image-based measurement tasks. This dataset is expected to be a valuable resource for a wide range of research and applications in the advanced analysis of images of soybean sprouts. Also, we hope that this dataset can assist researchers studying classification, semantic segmentation, decomposition, and physical feature measurement in other industrial fields, in evaluating their models. The dataset is available at the authors' repository. (https://bhban.kr/data)Comment: Accepted to International Conference on ICT Convergence 202

Research on Assembling Steel Tower on The Top of Skyscraper by Gradual Erection

The top surface of the hise rise buildings are very small for working space. The findings of this research is to clarify the scientific and technological problems to assemble big steel tower in different shapes on the top of the skyscrapers to the height of dozens of meters safely by using simple mechanical equipment including hoist, hydraulic jack by gradual erection method

Gas-Phase Photodegradation of Decane and Methanol on TiO

Diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) was used to study illuminated TiO2 surfaces under both vacuum conditions, and in the presence of organic molecules (decane and methanol). In the presence of hole scavengers, electrons are trapped at Ti(III)–OH sites, and free electrons are generated. These free electrons are seen to decay by exposure either to oxygen or to heat; in the case of heating, reinjection of holes into the lattice by loss of sorbed hole scavenger leads to a decrease in Ti(III)–OH centers. Decane adsorption experiments lend support to the theory that removal of surficial hydrocarbon contaminants is responsible for superhydrophilic TiO2 surfaces. Oxidation of decane led to a mixture of surface-bound organics, while oxidation of methanol leads to the formation of surface-bound formic acid

Development of sensitizer peptide-fused endolysin Lys1S-L9P acting against multidrug-resistant gram-negative bacteria

The advent of multidrug-resistant (MDR) bacteria poses a major threat to public health, garnering attention to novel antibiotic replacements. Endolysin, a bacteriophage-derived cell wall-degrading enzyme, is a promising alternative to conventional antibiotics. However, it is challenging to control Gram-negative bacteria due to the presence of the outer membrane that shields the peptidoglycan layer from enzymatic degradation. To overcome this threshold, we constructed the fusion endolysin Lys1S-L9P by combining endolysin LysSPN1S with KL-L9P, a sensitizer peptide known to extend efficacy of antibiotics by perturbing the outer membrane of Gram-negative bacteria. In addition, we established a new endolysin purification procedure that increases solubility allowing a 4-fold increase in production yield of Lys1S-L9P. The sensitizer peptide-fused endolysin Lys1S-L9P exhibited high bactericidal effects against many MDR Gram-negative pathogens and was more effective in eradicating biofilms compared to LysSPN1S. Moreover, Lys1S-L9P showed potential for clinical use, maintaining stability at various storage temperatures without cytotoxicity against human cells. In the in vivo Galleria mellonella model, Lys1S-L9P demonstrated potent antibacterial activity against MDR Gram-negative bacteria without inducing any toxic activity. This study suggest that Lys1S-L9P could be a potential biocontrol agent to combat MDR Gram-negative bacteria

Long-term results comparison after anterior cervical discectomy with BGS-7 spacer (NOVOMAX®-C) and allograft spacer: A prospective observational study

Introduction: In an anterior cervical discectomy and fusion (ACDF), various types of graft materials including autograft, allograft, and synthetic graft have been used to achieve adequate spinal fusion. Allograft spacer is mainly used in cervical fusion, especially in the anterior approach. The synthetic bone graft material BGS-7(CaO-SiO2-P2O5-B2O3, bioactive Glass-Ceramics) can bind with surrounding bone tissue by forming a hydroxyapatite layer bone bridge, leading to faster graft osseointegration. This study was conducted to compare long-term clinical outcome of BGS-7 spacer and allograft spacer for anterior cervical discectomy and fusion surgery.Materials and Methods: From September 2014 to December 2016, Consecutive anterior cervical discectomy and fusion surgeries using a BGS-7 spacer (N = 18) and Allograft spacer (N = 26) were compared for postoperative clinical outcomes. Radiologic assessments were performed, and Instrumental failure, including breakage, cage migration, subsidence were observed and Fusion status were analyzed. Finite element analysis was performed for simulating mechanical stress between the vertebral body and implant. Clinical outcomes were evaluated using neck VAS, NDI, and JOA on the patient’s final follow-up visits.Results: Among the 44 patients who underwent an anterior cervical discectomy and fusion surgery using the BGS-7 spacer and Allograft spacer, there were 30 men and 14 women. The average age at the operation was 47.69 ± 10.49 in allograft spacer and 51.67 ± 11.03 in BGS-7 spacer. The mean follow-up period was 89.18 ± 5.44 months. Twenty three (88.46%) patients in allograft spacer and 20(100%) patients in BGS-7 spacer were demonstrated radiologic evidence of interbody fusion in last OPD, which accounts for fusion grade 4 or 5. Peak stresses were 343.85 MPa in allograft spacer, and 132.55 MPa in BGS-7 spacer. Long-term clinical outcomes including neck VAS, NDI, and JOA didn’t show statistical differences between the two groups. There were no adverse events related to the BGS-7 spacer.10.3389/fbioe.2023.110046.Conclusion: The BGS-7 spacer demonstrated reliability as a spacer in anterior cervical discectomy and fusionF surgery without instrumental failure. Early stabilization with a bony bridge formation was observed at the intermediate follow-up period, and the long-term clinical outcome was favorable at more than 60 months after surgery without any adverse events. Thus, the BGS-7 spacer is a safe and effective alternative to the allograft spacer in anterior cervical discectomy and fusion surgery