Mass spectrometry in structural and stereochemical problems. Part 178 - The electron-impact promoted fragmentation of 1,2-cyclohexene oxide

Mass spectra of 1,2-cyclohexane oxide and three deuterium labeled analog

Parameterization of the Angular Distribution of Gamma Rays Produced by p-p Interaction in Astronomical Environment

We present the angular distribution of gamma rays produced by proton-proton interactions in parameterized formulae to facilitate calculations in astrophysical environments. The parameterization is derived from Monte Carlo simulations of the up-to-date proton-proton interaction model by Kamae et al. (2005) and its extension by Kamae et al. (2006). This model includes the logarithmically rising inelastic cross section, the diffraction dissociation process and Feynman scaling violation. The extension adds two baryon resonance contributions: one representing the Delta(1232) and the other representing multiple resonances around 1600 MeV/c^2. We demonstrate the use of the formulae by calculating the predicted gamma-ray spectrum for two different cases: the first is a pencil beam of protons following a power law and the second is a fanned proton jet with a Gaussian intensity profile impinging on the surrounding material. In both cases we find that the predicted gamma-ray spectrum to be dependent on the viewing angle.Comment: 8 pages, 7 figures, figure 7 updated, accepted for publication in ApJ, text updated to match changes by the editor, two refs updated from preprints to full journal

Propagation of Light Elements in the Galaxy

The origin and evolution of isotopes of the lightest elements H2, He3, Li, Be, B in the universe is a key problem in such fields as astrophysics of CR, Galactic evolution, non-thermal nucleosynthesis, and cosmological studies. One of the major sources of these species is spallation by CR nuclei in the interstellar medium. On the other hand, it is the B/C ratio in CR and Be10 abundance which are used to fix the propagation parameters and thus the spallation rate. We study the production and Galactic propagation of isotopes of elements Z<6 using the numerical propagation code GALPROP and updated production cross sections.Comment: 4 pages, 6 ps-figures, tsukuba.sty, to appear in the Proc. 28th International Cosmic Ray Conference (Tsukuba, Japan 2003). More details can be found at http://www.gamma.mpe-garching.mpg.de/~aws/aws.htm

Experimental study of the stability and flow characteristics of floating liquid columns confined between rotating disks

A low Bond number simulation technique was used to establish the stability limits of cylindrical and conical floating liquid columns under conditions of isorotation, equal counter rotation, rotation of one end only, and parallel axis offset. The conditions for resonance in cylindrical liquid columns perturbed by axial, sinusoidal vibration of one end face are also reported. All tests were carried out under isothermal conditions with water and silicone fluids of various viscosities. A technique for the quantitative measurement of stream velocity within a floating, isothermal, liquid column confined between rotatable disks was developed. In the measurement, small, light scattering particles were used as streamline markers in common arrangement, but the capability of the measurement was extended by use of stereopair photography system to provide quantitative data. Results of velocity measurements made under a few selected conditions, which established the precision and accuracy of the technique, are given. The general qualitative features of the isothermal flow patterns under various conditions of end face rotation resulting from both still photography and motion pictures are presented

A new Determination of the Extragalactic Background of Diffuse Gamma Rays taking into account Dark Matter Annihilation

The extragalactic background (EGB) of diffuse gamma rays can be determined by subtracting the Galactic contribution from the data. This requires a Galactic model (GM) and we include for the first time the contribution of dark matter annihilation (DMA), which was previously proposed as an explanation for the EGRET excess of diffuse Galactic gamma rays above 1 GeV. In this paper it is shown that the newly determined EGB shows a characteristic high energy bump on top of a steeply falling soft contribution. The bump is shown to be compatible with a contribution from an extragalactic DMA signal from weakly interacting massive particles (WIMPs) with a mass between 50 and 100 GeV in agreement with the EGRET excess of the Galactic diffuse gamma rays and in disagreement with earlier analysis. The remaining soft contribution of the EGB is shown to resemble the spectra of the observed point sources in our Galaxy.Comment: 7 pages, 4 figures. Accepted by A&A, made Fig. 4 and table 1 consisten

The 1979 Southeastern Virginia Urban Plume Study (SEV-UPS): Surface and airborne studies

The operation of two surface monitoring stations (one in downtown Norfolk, Virginia, one south of the city near the Great Dismal Swamp) and the collection of 40 hours of airborne measurements is described. Surface site measurements of ozone, oxides of nitrogen, sulfur dioxide, temperature, dew point, b sub seat, and condensation nuclei were made. Instrument calibrations, quality assurance audits, and preliminary data analysis in support of the Urban Plume Study were also made. The air pollution problems that were addressed are discussed. Data handling procedures followed for the surface stations are presented. The operation of the aircraft sampling platform is described. Aircraft sampling procedures are discussed. A preliminary descriptive analysis of the aircraft data is given along with data or plots for surface sites, airborne studies, hydrocarbon species, and instrument performance audits. Several of the aircraft flights clearly show the presence of an urban ozone plume downwind of Norfolk in the direction of the mean wind flow