Matter diffraction at oblique incidence: Higher resolution and the Helium Trimer Efimov state

We study the diffraction of atoms and weakly-bound three-atomic molecules from a transmission grating at non-normal incidence. Due to the thickness of the grating bars the slits are partially shadowed. Therefore, the projected slit width decreases more strongly with the angle of incidence than the projected period, increasing, in principle, the experimental resolution. The shadowing, however, requires a revision of the theory of atom diffraction. We derive an expression in the style of the Kirchhoff integral of optics and show that the diffraction pattern exhibits a characteristic asymmetry which must be accounted for when comparing with experimental data. We then analyze the diffraction of weakly bound trimers and show that their finite size manifests itself in a further reduction of the slit width by (3/4) where is the average bond length. The improved resolution at non-normal incidence may in particular allow to discern, by means of their bond lengths, between the small ground state of the helium trimer (=1 nm, Barletta and Kievsky, Phys. Rev. A 64, 042514 (2001)) and its predicted Efimov-type excited state (=8 nm, ibid.), and in this way to experimentally prove the existence of this long-sought Efimov state.Comment: 17 pages, 11 figure

Thermo-mechanical analysis of additively manufactured hybrid extrusion dies with conformal cooling channels

Profile overheating and surface defects during hot aluminum extrusion can occur when seeking higher productivity rates at increased ram speed velocities. The incorporation of cooling channels in the die-design allows overcoming this process limitation by keeping the profile temperature below the melting point of the alloy used [1]. Selective laser melting (SLM) of conformal cooling channels provides, in contrast to conventional manufacturing techniques, the opportunity to place the cooling circuit inside the mandrel of a porthole-die in a well-defined position to the critical bearing region [2]. In the framework of this study, a preliminary numerical investigation on the extrusion process under the assumption of liquid nitrogen cooling is analysed. The results show, that by combining conformal cooling channels with liquid nitrogen as a cooling media high cooling rates, which are well beyond the state of the art of conventional dies, can be achieved. In a hybrid extrusion die set-up, a part of the mandrel, that is additively manufactured, is either joined [3] or directly selective leaser melted onto the conventionally manufactured parts [4]. For a proper implementation in the extrusion process, material testing of the welded joint are needed. Thus, in the current study, tensile tests performed at room temperature for hybrid specimens, partially consisting of conventionally processed tool steel 1.2343 and partially additively manufactured 1.2709, will be presented. Moreover, four different heat treatment sequences of the hybrid specimens will be discussed. In addition, for each configuration, micro-structural images are taken to investigate failure at the bonding region. Finally, an optimal manufacturing sequence for a hybrid die with the described material combination is proposed

Ground state properties of heavy alkali halides

We extend previous work on alkali halides by calculations for the heavy-atom species RbF, RbCl, LiBr, NaBr, KBr, RbBr, LiI, NaI, KI, and RbI. Relativistic effects are included by means of energy-consistent pseudopotentials, correlations are treated at the coupled-cluster level. A striking deficiency of the Hartree-Fock approach are lattice constants deviating by up to 7.5 % from experimental values which is reduced to a maximum error of 2.4 % by taking into account electron correlation. Besides, we provide ab-initio data for in-crystal polarizabilities and van der Waals coefficients.Comment: accepted by Phys. Rev.

A TEST OF CONTINGENT MARKET BID ELICITATION PROCEDURES FOR PIECEWISE VALUATION

Economists are frequently faced with the task of valuing commodity package components. The valuation of specific impacts of public policies is a case in point. Two contingent market bid elicitation procedures were tested for valuing changes in single components of multicomponent government program. Results of the test suggested that respondents provided more accurate component to piecewise valuation when a two-step bidding approach, rather than a one-step approach was used. Thus, there is evidence that a two-step approach which helps respondents to isolate valuations for package components is perhaps a preferable bid elicitation procedure for piecewise valuation.Research Methods/ Statistical Methods,

Charge and spin density distributions around Zn impurities in cuprates

The effect of zinc substitution on the local electronic structure of several cuprates is investigated using first-principles cluster calculations. Clusters comprising 5, 9, and 13 copper atoms in the cuprate plane of La$_2$CuO$_4$, YBa$_2$Cu$_3$O$_7$, and YBa$_2$Cu$_4$O$_8$ are used. Spin polarized calculations with different multiplicities in the framework of density functional theory enable a detailed study of the changes in the charge and spin density distribution induced by Zn substitution. Furthermore, doping with charge carriers in the above materials is simulated and the resulting changes in the charge distribution are compared to the changes induced by Zn impurities. These differences are then discussed in terms of a phenomenological model related to properties expected from the generic phase diagram. The effects of zinc substitution are rather local and as expected the absolute values of the Mulliken charges at both nearest and next nearest neighbor oxygens to Zn are larger than in the unsubstituted clusters. The calculated electric field gradient at Cu sites that are nearest neighbor to Zn is found to be somewhat larger than in the unsubstituted cluster whereas that of next nearest neighbors is about 5% smaller. We conclude that the satellite peak in the Cu NQR spectrum occurring upon Zn substitution in YBa$_2$Cu$_3$O$_7$ and YBa$_2$Cu$_4$O$_8$ has its origin at Cu that are next nearest neighbors to Zn.Comment: 8 pages, 7 figure

First principles study of local electronic and magnetic properties in pure and electron-doped Nd2_2CuO4_4

The local electronic structure of Nd2CuO4 is determined from ab-initio cluster calculations in the framework of density functional theory. Spin-polarized calculations with different multiplicities enable a detailed study of the charge and spin density distributions, using clusters that comprise up to 13 copper atoms in the CuO2plane. Electron doping is simulated by two different approaches and the resulting changes in the local charge distribution are studied in detail and compared to the corresponding changes in hole doped La2CuO4. The electric field gradient (EFG) at the copper nucleus is investigated in detail and good agreement is found with experimental values. In particular the drastic reduction of the main component of the EFG in the electron-doped material with respect to LaCuO4 is explained by a reduction of the occupancy of the 3d3z^2-r^2 atomic orbital. Furthermore, the chemical shieldings at the copper nucleus are determined and are compared to results obtained from NMR measurements. The magnetic hyperfine coupling constants are determined from the spin density distribution

The Acceptability of War and Support for Defense Spending: Evidence from Fourteen Democracies, 2004–2013

We study the factors that influence citizen support for defense spending in fourteen democracies over the period 2004–2013. We pose two research questions. First, what factors influence citizen support for war and military force? We refer to this as the acceptability of war. Second, in addition to the acceptability of war, what other factors affect support for defense spending? Our principal finding is that citizen acceptance of war and support for defense spending are most influenced by basic beliefs and values. Gender also has a strong negative influence on attitudes toward war and thus indirectly lowers support for defense spending among women. Attitudes toward war and defense spending are also sometimes influenced by short-term threats and by alliance considerations, but the effects are not as substantively meaningful. We conclude with a summary of the results and a discussion of the implications for theory and policy