Utilização da fração protéica verde de folhas de mandioca na fortificação de alimentos.

bitstream/item/76342/1/ct50-2002.pd

Two Avenues to Self-Interaction Correction within Kohn-Sham Theory: Unitary Invariance is the Shortcut

The most widely-used density functionals for the exchange-correlation energy are inexact for one-electron systems. Their self-interaction errors can be severe in some applications. The problem is not only to correct the self-interaction error, but to do so in a way that will not violate size-consistency and will not go outside the standard Kohn-Sham density functional theory. The solution via the optimized effective potential (OEP) method will be discussed, first for the Perdew-Zunger self-interaction correction (whose performance for molecules is briefly summarized) and then for the more modern self-interaction corrections based upon unitarily-invariant indicators of iso-orbital regions. For the latter approaches, the OEP construction is greatly simplified. The kinetic-energy-based iso-orbital indicator \tau^W_\sigma(\re)/\tau_\sigma(\re) will be discussed and plotted, along with an alternative exchange-based indicator

Microwave cavity-enhanced transduction for plug and play nanomechanics at room temperature

Nanomechanical resonators with increasingly high quality factors are enabled following recent insights into energy storage and loss mechanisms in nanoelectromechanical systems (NEMS). Consequently, efficient, non-dissipative transduction schemes are required to avoid the dominating influence of coupling losses. We present an integrated NEMS transducer based on a microwave cavity dielectrically coupled to an array of doubly-clamped pre-stressed silicon nitride beam resonators. This cavity-enhanced detection scheme allows resolving the resonators' Brownian motion at room temperature while preserving their high mechanical quality factor of 290,000 at 6.6 MHz. Furthermore, our approach constitutes an "opto"mechanical system in which backaction effects of the microwave field are employed to alter the effective damping of the resonators. In particular, cavity-pumped self-oscillation yields a linewidth of only 5 Hz. Thereby, an adjustement-free, all-integrated and self-driven nanoelectromechanical resonator array interfaced by just two microwave connectors is realised, potentially useful for applications in sensing and signal processing

Neel order, ring exchange and charge fluctuations in the half-filled Hubbard model

We investigate the ground state properties of the two dimensional half-filled one band Hubbard model in the strong (large-U) to intermediate coupling limit ({\it i.e.} away from the strict Heisenberg limit) using an effective spin-only low-energy theory that includes nearest-neighbor exchange, ring exchange, and all other spin interactions to order t(t/U)^3. We show that the operator for the staggered magnetization, transformed for use in the effective theory, differs from that for the order parameter of the spin model by a renormalization factor accounting for the increased charge fluctuations as t/U is increased from the t/U -> 0 Heisenberg limit. These charge fluctuations lead to an increase of the quantum fluctuations over and above those for an S=1/2 antiferromagnet. The renormalization factor ensures that the zero temperature staggered moment for the Hubbard model is a monotonously decreasing function of t/U, despite the fact that the moment of the spin Hamiltonien, which depends on transverse spin fluctuations only, in an increasing function of t/U. We also comment on quantitative aspects of the t/U and 1/S expansions.Comment: 9 pages - 3 figures - References and details to help the reader adde

Otimização da detecção de isotiocianatos na análise por CG-DNP.

bitstream/CTAA-2009-09/9978/1/ct100-2006.pd

Arithmetic complexity via effective names for random sequences

We investigate enumerability properties for classes of sets which permit recursive, lexicographically increasing approximations, or left-r.e. sets. In addition to pinpointing the complexity of left-r.e. Martin-L\"{o}f, computably, Schnorr, and Kurtz random sets, weakly 1-generics and their complementary classes, we find that there exist characterizations of the third and fourth levels of the arithmetic hierarchy purely in terms of these notions. More generally, there exists an equivalence between arithmetic complexity and existence of numberings for classes of left-r.e. sets with shift-persistent elements. While some classes (such as Martin-L\"{o}f randoms and Kurtz non-randoms) have left-r.e. numberings, there is no canonical, or acceptable, left-r.e. numbering for any class of left-r.e. randoms. Finally, we note some fundamental differences between left-r.e. numberings for sets and reals