Synthesis, structural and physical properties of δ′\delta'-FeSe1−x_{1-x}

We report on synthesis, structural characterization, resistivity, magnetic and thermal expansion measurements on the as yet unexplored $\delta'$-phase of FeSe$_{1-x}$, here synthesized under ambient- (AP) and high-pressure (HP) conditions. We show that in contrast to $\beta$-FeSe$_{1-x}$, monophasic superconducting $\delta'$-FeSe$_{1-x}$ can be obtained in off-stoichiometric samples with excess Fe atoms preferentially residing in the van der Waals gap between the FeSe layers. The AP $\delta'$-FeSe$_{1-x}$ sample studied here ($T_c$ $\simeq$ 8.5\,K) possesses an unprecedented residual resistivity ratio RRR $\simeq$ 16. Thermal expansion data reveal a small feature around $\sim$90\,K, which resembles the anomaly observed at the structural and magnetic transitions for other Fe-based superconductors, suggesting that some kind of "magnetic state" is formed also in FeSe. %indicative of a fluctuating magnetic ordering. For HP samples (RRR $\simeq$ 3), the disorder within the FeSe layers is enhanced through the introduction of vacancies, the saturated magnetic moment of Fe is reduced and only spurious superconductivity is observed.Comment: 7 pages, 8 figures, published versio

Modeling iron abundance anhancements in the slow solar wind.

We have studied the behavior of Fe ions in the slow solar wind, using a fluid model extending from the chromosphere to 1 AU. Emphasis is on elemental "pileup" in the corona, i.e., a region where the Fe density increases and has a local maximum. We study the behavior of individual Fe ions relative to each other in the pileup region, where Fe(+10) and Fe(+12) have been used as examples. We find that elemental pileups can occur for a variety of densities and temperatures in the corona. We also calculate the ion fractions and obtain estimates for the freezing-in distance of Fe in the slow solar wind. We find that the freezing-in distance for iron is high, between 3 and 11 R(circle dot), and that a high outflow velocity, of order 50-100 km s(-1), in the region above the temperature maximum is needed to obtain ion fractions for Fe(+10) and Fe(+12) that are consistent with observations