Active Brownian Particles. From Individual to Collective Stochastic Dynamics

We review theoretical models of individual motility as well as collective dynamics and pattern formation of active particles. We focus on simple models of active dynamics with a particular emphasis on nonlinear and stochastic dynamics of such self-propelled entities in the framework of statistical mechanics. Examples of such active units in complex physico-chemical and biological systems are chemically powered nano-rods, localized patterns in reaction-diffusion system, motile cells or macroscopic animals. Based on the description of individual motion of point-like active particles by stochastic differential equations, we discuss different velocity-dependent friction functions, the impact of various types of fluctuations and calculate characteristic observables such as stationary velocity distributions or diffusion coefficients. Finally, we consider not only the free and confined individual active dynamics but also different types of interaction between active particles. The resulting collective dynamical behavior of large assemblies and aggregates of active units is discussed and an overview over some recent results on spatiotemporal pattern formation in such systems is given.Comment: 161 pages, Review, Eur Phys J Special-Topics, accepte

Host Decoy Trap (HDT) with cattle odour is highly effective for collection of exophagic malaria vectors

Background: As currently implemented, malaria vector surveillance in sub-Saharan Africa targets endophagic and endophilic mosquitoes, leaving exophagic (outdoor blood feeding) mosquitoes underrepresented. We evaluated the recently developed host decoy trap (HDT) and compared it to the gold standard, human landing catch (HLC), in a 3x3 Latin square study design outdoors in western Kenya. HLCs are considered to represent the natural range of Anopheles biting-behaviour compared to other sampling tools, and therefore, in principle, provide the most reliable profile of the biting population transmitting malaria. The HDT incorporates the main host stimuli that attract blood meal seeking mosquitoes and can be baited with the odours of live hosts. Results: Numbers and species diversity of trapped mosquitoes varied significantly between HLCs and HDTs baited with human (HDT-H) or cattle (HDT-C) odour, revealing important differences in behaviour of Anopheles species. In the main study in Kisian, the HDT-C collected a nightly mean of 43.2 (95% CI; 26.7-69.8) Anopheles, compared to 5.8 (95% CI; 4.1-8.2) in HLC, while HDT-H collected 0.97 (95% CI; 0.4-2.1), significantly fewer than the HLC. Significantly higher proportions of An. arabiensis were caught in HDT-Cs (0.94 ± 0.01; SE) and HDT-Hs (0.76 ± 0.09; SE) than in HLCs (0.45 ± 0.05; SE) per trapping night. The proportion of An. gambiae s.s. was highest in HLC (0.55 ±0.05; SE) followed by HDT-H (0.20 ± 0.09; SE) and least in HDT-C (0.06 ± 0.01; SE). An unbaited HDT placed beside locales where cattle are usually corralled overnight caught mostly An. arabiensis with proportions of 0.97 ± 0.02 and 0.80 ± 0.2 relative to the total anopheline catch in the presence and absence of cattle, respectively. A mean of 10.4 (95% CI; 2.0-55.0) Anopheles/night were trapped near cattle, compared to 0.4 (95% CI; 0.1-1.7) in unbaited HDT away from hosts. Conclusions: The capability of HDTs to combine host odours, heat and visual stimuli to simulate a host provides the basis of a system to sample human- and cattle-biting mosquitoes. HDT-C is particularly effective for collecting An. arabiensis outdoors. The HDT offers the prospect of a system to monitor and potentially control An. arabiensis and other outdoor-biting mosquitoes more effectively

Discovery of the Closest Hot Subdwarf Binary with White Dwarf Companion

Contains fulltext : 117396.pdf (preprint version ) (Open Access

Hydrocarbon separations in metal-organic frameworks

Owing to their high surface areas, tunable pore dimensions, and adjustable surface functionality, metal-org. frameworks (MOFs) can offer advantages for a variety of gas storage and gas sepn. applications. In an effort to reduce the major energy requirements for the sepn. of mixts. of light hydrocarbons via cryogenic distn., we are developing new MOFs with a high capacity for the selective adsorption of unsatd. hydrocarbons at higher temps. In particular, the compds. M2(dobdc) (M = Mg, Mn, Fe, Co, Ni; dobdc4- = 2,5-dioxido-1,4-benzenedicarboxylate), featuring open M2+ cation sites, have been evaluated for their performance in the fractionation of mixts. of C1-C3 hydrocarbons at 45 °C. The results indicate that these materials have significant potential for applications in adsorption-based processes for natural gas purifn. and olefin/paraffin spearations. In addn., it will be shown that certain structural features possible within MOFs, but not in zeolites, can enable the fractionation of hexane isomers according to the degree of branching or octane no.

The phosphinoboration of 2-diphenylphosphino benzaldehyde and related aldimines

We have investigated the addition of a simple phosphinoboronate ester, Ph2PBpin (pin = 1,2-O2C2Me4), to 2-diphenylphosphinobenzaldehyde (2-Ph2PC6H4C(O)H) and related aldimine derivatives (2-Ph2PC6H4C(NR)H) as a simple and effective strategy for generating unique diphosphine ligands bearing a pendant Lewis-acid Bpin group. These reactions proceed selectively to give one new product where the phosphide fragment has added to the aldehyde (or imine) carbon atom and the electron-deficient boron group has added to the electron-rich heteroatom. Preliminary studies show these new compounds can ligate to Pd(II) and Pt(II) metal centres. These novel metal complexes, as well as the organic soluble [MCl2(coe)]2 (M = Pd, Pt, coe = cis-cyclooctene) compounds, have been shown to be effective precatalysts in the cyclisation of alkynoic acids to give the corresponding exo-dig cyclic lactones. Reactions employing these metal complexes also generated unusual endo-dig cyclic lactones not traditionally observed in these cyclisation reactions. For instance, reactions of 4-pentynoic acid also afforded significant amounts of α-angelica lactone, a biologically-important compound traditionally prepared via th

Hot subdwarfs in binary systems and the nature of their unseen companions

A large fraction of the sdB stars reside in short period binaries. It is therefore clear that binary evolution plays an important role in the still unsolved problem of hot subdwarf formation. Here we present new results from different projects devoted to the analysis of sdBs in close binaries. The nature and masses of the unseen companions of 31 sdBs have been constrained by an analysis of high resolution spectra. In the course of this study candidate systems with massive compact companions have been discovered. The HYPERMUCHFUSS project aims at finding such systems making use of the huge spectral database of SDSS. A multi-site follow-up campaign of promising radial velocity variable sdBs started in 2009 and preliminary results are shown here. The most recent discovery of a substellar companion to the bright sdB HD 149382 may provide new evidence for the decisive role of low mass companions for sdB formation in general. A mysterious IR-excess has been detected, which may be caused by this otherwise invisible companion. Another low mass companion has been found to orbit the sdB star EGB 5 within 16.5 days. The space mission CoRoT is performing wide field and high precision photometry. First preliminary results from a spectroscopic survey of the COROT fields are also reported