17 research outputs found

    Temperature and Concentration Effects of Aqueous Solution of Sodium Octanoate on Micelle Formation Measured by Small angle X-ray Scattering

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    Characteristic sizes of sodium octanoate micelles have been determined (by nucleus radius) with the use of small angle X-ray scattering technique at various molar concentrations, which are for a spherical shape 1 and nonspherical 1.2 nm, respectively. The value of the critical concentration for micelle formation (CMC2) has been also found equal to 0.7 M. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/3628

    Mechanisms of Ions Adsorption by Nanodiamonds in Aqueous Suspensions

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    This work is devoted to the study of adsorption properties and adsorption mechanisms of the original (I6), modified (I6COOH) nanodiamonds and charcoal dispersed in water, with respect to dissolved ions (Cu2 +, Pb2 +, NO3 –, CH3COO –) using optical spectroscopy methods: Raman and IR spectroscopies, absorption, dynamic light scattering. Mechanisms of anions and cations adsorption were studied. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/3365

    Improving the resilience of neural network solution of inverse problems in Raman spectroscopy to the distortions caused by frequency shift of the spectral channels

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    Π’ Π΄Π°Π½Π½ΠΎΠΉ Ρ€Π°Π±ΠΎΡ‚Π΅ Ρ€Π°ΡΡΠΌΠ°Ρ‚Ρ€ΠΈΠ²Π°Π»Π°ΡΡŒ Π·Π°Π΄Π°Ρ‡Π° опрСдСлСния ΠΊΠΎΠ½Ρ†Π΅Π½Ρ‚Ρ€Π°Ρ†ΠΈΠΉ растворСнных Π² Π²ΠΎΠ΄Π΅ ΠΈΠΎΠ½ΠΎΠ² посрСдством спСктроскопии ΠΊΠΎΠΌΠ±ΠΈΠ½Π°Ρ†ΠΈΠΎΠ½Π½ΠΎΠ³ΠΎ рассСяния свСта. Π’ настоящСС врСмя Π½Π΅ сущСствуСт Π°Π΄Π΅ΠΊΠ²Π°Ρ‚Π½Ρ‹Ρ… матСматичСских ΠΌΠΎΠ΄Π΅Π»Π΅ΠΉ, ΠΎΠΏΠΈΡΡ‹Π²Π°ΡŽΡ‰ΠΈΡ… исслСдуСмый ΠΎΠ±ΡŠΠ΅ΠΊΡ‚, поэтому практичСски СдинствСнным способом Ρ€Π΅ΡˆΠ΅Π½ΠΈΡ рассматриваСмой Π·Π°Π΄Π°Ρ‡ΠΈ являСтся ΠΏΡ€ΠΈΠΌΠ΅Π½Π΅Π½ΠΈΠ΅ ΠΌΠ΅Ρ‚ΠΎΠ΄ΠΎΠ² машинного обучСния с использованиСм ΡΠΊΡΠΏΠ΅Ρ€ΠΈΠΌΠ΅Π½Ρ‚Π°Π»ΡŒΠ½Ρ‹Ρ… Π΄Π°Π½Π½Ρ‹Ρ…. ВслСдствиС Ρ‚ΠΎΠ³ΠΎ, Ρ‡Ρ‚ΠΎ Π»ΡŽΠ±Ρ‹Π΅ Π΄Π°Π½Π½Ρ‹Π΅, ΠΏΠΎΠ»ΡƒΡ‡Π΅Π½Π½Ρ‹Π΅ ΡΠΊΡΠΏΠ΅Ρ€ΠΈΠΌΠ΅Π½Ρ‚Π°Π»ΡŒΠ½Ρ‹ΠΌ ΠΏΡƒΡ‚Π΅ΠΌ, содСрТат ΡˆΡƒΠΌ, Π²ΠΎΠ·Π½ΠΈΠΊΠ°Π΅Ρ‚ Π½Π΅ΠΎΠ±Ρ…ΠΎΠ΄ΠΈΠΌΠΎΡΡ‚ΡŒ Π² Ρ€Π°Π·Ρ€Π°Π±ΠΎΡ‚ΠΊΠ΅ ΡΠΏΠ΅Ρ†ΠΈΠ°Π»ΡŒΠ½Ρ‹Ρ… ΠΏΠΎΠ΄Ρ…ΠΎΠ΄ΠΎΠ² ΠΊ ΠΏΠΎΠ²Ρ‹ΡˆΠ΅Π½ΠΈΡŽ устойчивости Ρ€Π΅ΡˆΠ΅Π½ΠΈΡ ΠΊ ΡˆΡƒΠΌΠ°ΠΌ Π² Π΄Π°Π½Π½Ρ‹Ρ…. ΠŸΡ€ΠΈΠΌΠ΅Π½ΠΈΡ‚Π΅Π»ΡŒΠ½ΠΎ ΠΊ рассматриваСмой Π·Π°Π΄Π°Ρ‡Π΅, Π΄Π°Π½Π½Ρ‹Π΅ ΠΌΠΎΠ³ΡƒΡ‚ ΡΠΎΠ΄Π΅Ρ€ΠΆΠ°Ρ‚ΡŒ искаТСния ΡΠ»Π΅Π΄ΡƒΡŽΡ‰ΠΈΡ… Ρ‚ΠΈΠΏΠΎΠ²: нСточности Π² Π·Π°Π΄Π°Π½Π½Ρ‹Ρ… концСнтрациях ΠΈΠΎΠ½ΠΎΠ², Π²ΠΎΠ·Π½ΠΈΠΊΠ°ΡŽΡ‰ΠΈΠ΅ ΠΏΡ€ΠΈ ΠΏΡ€ΠΈΠ³ΠΎΡ‚ΠΎΠ²Π»Π΅Π½ΠΈΠΈ растворов, ΠΏΠΎΠ³Ρ€Π΅ΡˆΠ½ΠΎΡΡ‚ΠΈ измСрСния интСнсивности ΠΊΠ°Π½Π°Π»ΠΎΠ² спСктра ΠΈ смСщСниС частоты ΠΊΠ°Π½Π°Π»ΠΎΠ² спСктра, Π²Ρ‹Π·Π²Π°Π½Π½ΠΎΠ΅ ΠΈΠ·ΠΌΠ΅Π½Π΅Π½ΠΈΠ΅ΠΌ ΡŽΡΡ‚ΠΈΡ€ΠΎΠ²ΠΊΠΈ ΡΠΊΡΠΏΠ΅Ρ€ΠΈΠΌΠ΅Π½Ρ‚Π°Π»ΡŒΠ½ΠΎΠΉ установки. Настоящая Ρ€Π°Π±ΠΎΡ‚Π° посвящСна Ρ€Π°Π·Ρ€Π°Π±ΠΎΡ‚ΠΊΠ΅ ΠΏΠΎΠ΄Ρ…ΠΎΠ΄ΠΎΠ² ΠΊ ΠΏΠΎΠ²Ρ‹ΡˆΠ΅Π½ΠΈΡŽ устойчивости нСйросСтСвого Ρ€Π΅ΡˆΠ΅Π½ΠΈΡ ΠΊ искаТСниям, обусловлСнным смСщСниСм частоты ΠΊΠ°Π½Π°Π»ΠΎΠ² спСктра. In this study, we considered the problem of determining the concentrations of ions dissolved in water by the spectra of Raman scattering of light. At the moment, there are no adequate mathematical models describing the studied object, so in fact the only way to solve this problem is the use of machine learning methods based on experimental data. As any data resulting from experimental measurements contain noise, there is a need to develop specific approaches to improving the resilience of the solution to noise in the data. Regarding the studied problem, experimental data may contain distortions of three types: variations in the concentrations of ions, error in the determination of the intensity in the channels of the spectra, and frequency shift of the channels of the spectrum. This study is devoted to the development of approaches to improve the resilience of the neural network solution to the distortions caused by the shift of the spectral channels.Π Π°Π±ΠΎΡ‚Π° Π²Ρ‹ΠΏΠΎΠ»Π½Π΅Π½Π° Π·Π° счСт Π³Ρ€Π°Π½Ρ‚Π° Российского Π½Π°ΡƒΡ‡Π½ΠΎΠ³ΠΎ Ρ„ΠΎΠ½Π΄Π° (ΠΏΡ€ΠΎΠ΅ΠΊΡ‚ β„– 14-11-00579)

    Survey: Application of Neural Networks in Physical Research in Scobeltsyn Nuclear Physics Institute, Moscow

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    This paper is the survey of research projects being conducted by our group in the Nuclear Physics Institute of Moscow State University in the area of development of neural network methods for registration, analysis, processing and classification of patterns. The results of investigations have found application in a wide range of practical problems, in particular, in the fields of medicine and neurophysiology, ecological monitoring of natural waters, non-linear laser spectroscopy, temperature measurements in plasma, and in investigations of solar wind - geomagnetosphere interaction. Medicine [1

    The impact of temperature on the degree of structurization of water of different isotope composition

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    Using vacuum ultrafiltration radiation and the method of dynamic light scattering employing samples of light (D/H = 6 ppm), distilled (D/H = 150 ppm) water and the water with an increased content of deuterium (D/H = 7700 ppm, 99.96%) as an example within the interval 4–80Β°C the impact of temperature on the degree of water structurization of the different isotope composition was studied. Experimentally has been established the sizes of optical inhomogeneties of studied waters at various temperatures. It has been shown that temperature relationships of these types of water obtained by these methods have a graded nature with clear-cut critical points at 4; 36; 45 and 60–70Β°C. Β© 2017, Allerton Press, Inc

    The impact of temperature on the degree of structurization of water of different isotope composition

    No full text
    Using vacuum ultrafiltration radiation and the method of dynamic light scattering employing samples of light (D/H = 6 ppm), distilled (D/H = 150 ppm) water and the water with an increased content of deuterium (D/H = 7700 ppm, 99.96%) as an example within the interval 4–80Β°C the impact of temperature on the degree of water structurization of the different isotope composition was studied. Experimentally has been established the sizes of optical inhomogeneties of studied waters at various temperatures. It has been shown that temperature relationships of these types of water obtained by these methods have a graded nature with clear-cut critical points at 4; 36; 45 and 60–70Β°C. Β© 2017, Allerton Press, Inc
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