1,112 research outputs found
Chiral molecule adsorption on helical polymers
We present a lattice model for helicity induction on an optically inactive
polymer due to the adsorption of exogenous chiral amine molecules. The system
is mapped onto a one-dimensional Ising model characterized by an on-site
polymer helicity variable and an amine occupancy one. The equilibrium
properties are analyzed at the limit of strong coupling between helicity
induction and amine adsorption and that of non-interacting adsorbant molecules.
We discuss our results in view of recent experimental results
Novel phase diagram for antiferromagnetism and superconductivity in pressure-induced heavy-fermion superconductor CeRhIn probed by In-NQR
We present a novel phase diagram for the antiferromagnetism and
superconductivity in CeRhIn probed by In-NQR studies under pressure
(). The quasi-2D character of antiferromagnetic spin fluctuations in the
paramagnetic state at = 0 evolves into a 3D character because of the
suppression of antiferromagnetic order for 1.36 GPa (QCP:
antiferromagnetic quantum critical point). Nuclear-spin-lattice-relaxation rate
measurements revealed that the superconducting order occurs in the
range 1.36 -- 1.84 GPa, with maximum 0.9 K around
1.36 GPa.Comment: 5 pages, 5 figures, submitted to PR
High-Tc Nodeless s_\pm-wave Superconductivity in (Y,La)FeAsO_{1-y} with Tc=50 K: 75As-NMR Study
We report 75As-NMR study on the Fe-pnictide high-Tc superconductor
Y0.95La0.05FeAsO_{1-y} (Y0.95La0.051111) with Tc=50 K that includes no magnetic
rare-earth elements. The measurement of the nuclear-spin lattice-relaxation
rate 75(1/T1) has revealed that the nodeless bulk superconductivity takes place
at Tc=50 K while antiferromagnetic spin fluctuations (AFSFs) develop moderately
in the normal state. These features are consistently described by the multiple
fully-gapped s_\pm-wave model based on the Fermi-surface (FS) nesting.
Incorporating the theory based on band calculations, we propose that the reason
that Tc=50 K in Y0.95La0.051111 is larger than Tc=28 K in La1111 is that the FS
multiplicity is maximized, and hence the FS nesting condition is better than
that in La1111.Comment: 4 pages, 3 figures, accepted for publication in Phys Rev. Let
Possibility of valence-fluctuation mediated superconductivity in Cd-doped CeIrIn probed by In-NQR
We report on a pressure-induced evolution of exotic superconductivity and
spin correlations in CeIr(InCd) by means of
In-Nuclear-Quadrupole-Resonance (NQR) studies. Measurements of an NQR spectrum
and nuclear-spin-lattice-relaxation rate have revealed that
antiferromagnetism induced by the Cd-doping emerges locally around Cd dopants,
but superconductivity is suddenly induced at = 0.7 and 0.9 K at 2.34 and
2.75 GPa, respectively. The unique superconducting characteristics with a large
fraction of the residual density of state at the Fermi level that increases
with differ from those for anisotropic superconductivity mediated by
antiferromagnetic correlations. By incorporating the pressure dependence of the
NQR frequency pointing to the valence change of Ce, we suggest that
unconventional superconductivity in the CeIr(InCd) system may
be mediated by valence fluctuations.Comment: Accepted for publication in Physical Review Letter
Synthesis of H<sub>x</sub>Li<sub>1-x</sub>LaTiO<sub>4</sub> from quantitative solid-state reactions at room temperature
The layered perovskite HLaTiO4 reacts stoichiometrically with LiOH·H2O at room temperature to give targeted compositions in the series HxLi1-xLaTiO4. Remarkably, the Li+ and H+ ions are quantitatively exchanged in the solid state and this allows stoichiometric control of ion exchange for the first time in this important series of compounds
Furthering the understanding of silicate-substitution in α-tricalcium phosphate : an X-ray diffraction, X-ray fluorescence and solid-state nuclear magnetic resonance study
High-purity (SupT) and reagent-grade (ST), stoichiometric and silicate-containing α-tricalcium phosphate (α-TCP: ST0/SupT0 and Si-TCP x = 0.10: ST10/SupT10) were prepared by solid-state reaction based on the substitution mechanism Ca3(PO4)(2-x)(SiO4)x. Samples were determined to be phase pure by X-ray diffraction (XRD), and Rietveld analysis performed on the XRD data confirmed inclusion of Si in the α-TCP structure as determined by increases in unit cell parameters; particularly marked increases in the b-axis and ÎČ-angle were observed. X-ray fluorescence (XRF) confirmed the presence of expected levels of Si in Si-TCP compositions as well as significant levels of impurities (Mg, Al and Fe) present in all ST samples; SupT samples showed both expected levels of Si and a high degree of purity. Phosphorus (31P) magic-angle-spinning solid-state nuclear magnetic resonance (MAS NMR) measurements revealed that the high-purity reagents used in the synthesis of SupT0 can resolve the 12 expected peaks in the 31P spectrum of α-TCP compared to the low-purity ST0 that showed significant spectral line broadening; line broadening was also observed with the inclusion of Si which is indicative of induced structural disorder. Silicon (29Si) MAS NMR was also performed on both Si-TCP samples which revealed Q0 species of Si with additional Si Q1/Q2 species that may indicate a potential charge-balancing mechanism involving the inclusion of disilicate groups; additional Q4 Si species were also observed, but only for ST10. Heating and cooling rates were briefly investigated by 31P MAS NMR which showed no significant line broadening other than that associated with the emergence of ÎČ-TCP which was only realised with the reagent-grade sample ST0. This study provides an insight into the structural effects of Si-substitution in α-TCP and could provide a basis for understanding how substitution affects the physicochemical properties of the material
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