727 research outputs found
Lithium colloids and color center creation in electron-irradiated Li2NH observed by electron-spin resonance
4 pagesInternational audienceWe have irradiated Li2NH powder with MeV electrons at room temperature and investigated the introduced defects with electron spin resonance. CESR indicates the presence of nanosize metallic Li colloids seen as a Lorentzian line with a g = 2.0023 and a line width DeltaH = 50 microT. A second, broader, signal (DeltaH = 3 to 4 mT) appears superimposed upon the Li line at low T (Curie-type behavior) which exhibits complex T-dependence with a break near 180 K for its g-value and DeltaH. We are suggesting for the latter a vacancy-type defect in the NH-sublattice, with freezing of its H-component below 180 K. When heated both the Li colloids and the color centers anneal around 100 C probably due to hydrogen evolution and subsequent chemical degradation
Magnetization measurements on Li2Pd3B superconductor
Magnetization in DC magnetic fields and at different temperatures have been
measured on the Li2Pd3B compound. This material was recently found to show
superconductivity at 7-8K. Critical fields Hc1(0) and Hc2(0) have been
determined to be 135Oe and 4T, respectively. Critical current density, scaling
of the pinning force within the Kramer model and the irreversibility field data
are presented. Several superconductivity parameters were deduced: x(csi)=9.1
nm, l(lamda)=194nm and k=21. The material resembles other boride
superconductors from the investigated points of view.Comment: 10 pages, 5 figure
First-principles study on the intermediate compounds of LiBH
We report the results of the first-principles calculation on the intermediate
compounds of LiBH. The stability of LiBH and LiBH has been examined with the ultrasoft pseudopotential method based on
the density functional theory. Theoretical prediction has suggested that
monoclinic LiBH is the most stable among the candidate
materials. We propose the following hydriding/dehydriding process of LiBH
via this intermediate compound : LiBHLiBH LiH HLiH B H. The hydrogen content and enthalpy of the first
reaction are estimated to be 10 mass% and 56 kJ/mol H, respectively, and
those of the second reaction are 4 mass% and 125 kJ/mol H. They are in good
agreement with experimental results of the thermal desorption spectra of
LiBH. Our calculation has predicted that the bending modes for the
-phonon frequencies of monoclinic LiBH are lower than
that of LiBH, while stretching modes are higher. These results are very
useful for the experimental search and identification of possible intermediate
compounds.Comment: 7 pages, 5 figures, submitted to PR
CANGAROO-III Observation of TeV Gamma Rays from the vicinity of PSR B1 706-44
Observation by the CANGAROO-III stereoscopic system of the Imaging Cherenkov
Telescope has detected extended emission of TeV gamma rays in the vicinity of
the pulsar PSR B170644. The strength of the signal observed as
gamma-ray-like events varies when we apply different ways of emulating
background events. The reason for such uncertainties is argued in relevance to
gamma-rays embedded in the "off-source data", that is, unknown sources and
diffuse emission in the Galactic plane, namely, the existence of a complex
structure of TeV gamma-ray emission around PSR B170644.Comment: 10 pages, 13 figures, to be published in Ap
- …