Hexa-μ-chlorido-hexa­chlorido(η6-hexa­methyl­benzene)trialuminium(III)lanthanum(III) benzene solvate

In the title compound, [Al3LaCl12(C12H18)]·C6H6, all mol­ecules are located on a mirror plane. Three chloridoaluminate groups and a hexa­methyl­benzene mol­ecule are bound to the central lanthanum(III) ion, forming a distorted penta­gonal bipyramid with the η6-coordinated arene located at the apical position. The hexa­methyl­benzene ligand disordered between two orientations in a 1:1 ratio is also involved in parallel-slipped π–π stacking inter­molecular inter­actions with a benzene solvent mol­ecule [centroid–centroid distance 3.612 (4) Å]

Parameter selection for the supply system in a Pilger mill

The braking chamber in the supply system of a Pilger pipe mill is modernized. The influence of constant and variable parameters of the supply system on braking is studied. © 2013 Allerton Press, Inc

Controlling circular polarization of light emitted by quantum dots using chiral photonic crystal slab

We study the polarization properties of light emitted by quantum dots that are embedded in chiral photonic crystal structures made of achiral planar GaAs waveguides. A modification of the electromagnetic mode structure due to the chiral grating fabricated by partial etching of the wave\-guide layer has been shown to result in a high circular polarization degree $\rho_c$ of the quantum dot emission in the absence of external magnetic field. The physical nature of the phenomenon can be understood in terms of the reciprocity principle taking into account the structural symmetry. At the resonance wavelength, the magnitude of $|\rho_c|$ is predicted to exceed 98%. The experimentally achieved value of $|\rho_c|=81$% is smaller, which is due to the contribution of unpolarized light scattered by grating defects, thus breaking its periodicity. The achieved polarization degree estimated removing the unpolarized nonresonant background from the emission spectra can be estimated to be as high as 96%, close to the theoretical prediction

Curing of epoxy resin DER-331by Hexakis (4-acetamidophenoxy) cyclotriphosphazene and properties of the prepared composition

The method of optical wedge revealed that the optimum temperature for compatibility of hexakis(4-acetamidophenoxy)cyclotriphosphazene (ACP) and DER-331 epoxy resin is in the range of 220–260◦C. The interdiffusion time of components at these temperatures is about 30 min. The TGA and differential scanning calorimetry (DSC) methods revealed the curing temperature of 280◦C for thiscomposition. IRspectroscopyconfirmedthatthereactionbetweentheresinandACPiscompleted within 10 mi

Assessment of radiation environment in the South-Kuril fishing area and impact of radiation pollution on pacific saury in 2011-2013

Radiation environment is assessed for the Pacific waters off Kuril Islands and effects of radiation pollution on pacific saury migrating through this area for feeding are evaluated on the samples collected by research vessels of Pacific Fisheries Research Center (TINRO) in 2011-2013 and processed in the specially equipped laboratory of this institute. Short-term increasing of the radiation background was registered in March 2011 only, and radiation pollution of the fish tissues was not detected. Obviously, the accident at the nuclear power plant Fukushima-1 had no significant effect on pacific saury. No threat to safety of the food made of pacific saury is concluded. However, a dangerous effect of the accident is possible for other commercial species of fish, in particular long-living ones that have repeated migrations through the waters adjacent to the power plant, as sardine and mackerel. These species aren’t landed by Russian fishermen now but their fishery can be resumed under growth of their populations in future