Influence of the flow on the anchoring of nematic liquid crystals on a Langmuir-Blodgett monolayer studied by optical second-harmonic generation

The influence of capillary flow on the alignment of the nematic liquid crystal MBBA on fatty acid Langmuir-Blodgett monolayers was studied by optical second-harmonic generation. The surface dipole sensitivity of the technique allows probing the orientation of the first liquid crystal monolayer in the presence of the liquid crystal bulk. It was found that capillary flow causes the first monolayer of liquid crystal molecules in contact with the fatty acid monolayer to be oriented in the flow direction with a large pretilt (78 degrees), resulting in a quasi-planar alignment with splay-bend deformation of the nematic director in the bulk. itself is affected by the flow. The quasi-planar flow-induced alignment was found to be metastable. Once the flow ceases, circular domains of homeotropic orientation nucleate in the sample and expand until the whole sample becomes homeotropic. This relaxation process from flow-induced quasi-planar to surface-induced homeotropic alignment was also monitored by SHG. It was found that in the homeotropic state the first nematic layer presents a pretilt of 38 degrees almost isotropically distributed in the plane of the cell, with a slight preference for the direction of the previous flow.Comment: LaTeX2e article, 11 figures, 17 EPS files, submitte

Telephone-cord instabilities in thin smectic capillaries

Telephone-cord patterns have been recently observed in smectic liquid crystal capillaries. In this paper we analyse the effects that may induce them. As long as the capillary keeps its linear shape, we show that a nonzero chiral cholesteric pitch favors the SmA*-SmC* transition. However, neither the cholesteric pitch nor the presence of an intrinsic bending stress are able to give rise to a curved capillary shape. The key ingredient for the telephone-cord instability is spontaneous polarization. The free energy minimizer of a spontaneously polarized SmA* is attained on a planar capillary, characterized by a nonzero curvature. More interestingly, in the SmC* phase the combined effect of the molecular tilt and the spontaneous polarization pushes towards a helicoidal capillary shape, with nonzero curvature and torsion.Comment: Submitte

Nonlinear optical properties of a channel waveguide produced with crosslinkable ferroelectric liquid crystals

A binary mixture of ferroelectric liquid crystals (FLCs) was used for the design of a channel waveguide. The FLCs possess two important functionalities: a chromophore with a high hyperpolarizability $\beta$ and photoreactive groups. The smectic liquid crystal is aligned in layers parallel to the glass plates in a sandwich geometry. This alignment offers several advantages, such as that moderate electric fields are sufficient to achieve a high degree of polar order. The arrangement was then permanently fixed by photopolymerization which yielded a polar network possessing a high thermal and mechanical stability which did not show any sign of degradation within the monitored period of several months. The linear and nonlinear optical properties have been measured and all four independent components of the nonlinear susceptibility tensor $\bar d$ have been determined. The off-resonant $d$-coefficients are remarkably high and comparable to those of the best known inorganic materials. The alignment led to an inherent channel waveguide for p-polarized light without additional preparation steps. The photopolymerization did not induce scattering sites in the waveguide and the normalized losses were less than 2 dB/cm. The material offers a great potential for the design of nonlinear optical devices such as frequency doublers of low power laser diodes.Comment: LaTeX2e article, 15 pages, 10 figures, 11 EPS files, submitted to Physical Review

Phase-matched second-harmonic generation in a ferroelectric liquid crystal waveguide

True phase-matched second-harmonic generation in a waveguide of crosslinkable ferroelectric liquid crystals is demonstrated. These materials allow the formation of macroscopically polar structures whose order can be frozen by photopolymerization. Homeotropic alignment was chosen which offers decisive advantages compared to other geometries. All parameters contributing to the conversion efficiency are maximized by deliberately controlling the supramolecular arrangement. The system has the potential to achieve practical level of performances as a frequency doubler for low power laser diodes.Comment: 4 pages, LaTeX2e article, 3 figures, 4 EPS files, submitted to Physical Review Letter

Effects of weak anchoring on C1 and C2 chevron structures

We present a theoretical study of the effect of weak anchoring on the transition between C1 and C2 chevron structures in smectic C liquid crystals. We employ a continuum theory which allows for variable cone, azimuthal and layer tilt angles. Equilibrium profiles for the director cone and azimuthal angles in the C1 and C2 states are calculated from the standard Euler-Lagrange minimisation of the total energy of the system. By comparing the total energies of the C1 and C2 states we can determine the globally stable chevron profile and calculate the critical temperature for the C1-C2 transition, which depends on anchoring strength and pretilt angle variations

Synthesis and Properties of High Tilted Antiferroelectric Esters with Partially Fluorinated Alkoxyalkoxy Terminal Chains

Novel chiral esters with partially fluorinated alkoxyalkoxy terminal chains are described. Their phase transition temperatures, enthalpies, and electrooptical properties are reported. A helical pitch in pure compounds and their mixtures based on selective reflection of light is also characterized

A mini-review on household solid waste management systems in low-income developing countries: A case study of urban Harare City, Zimbabwe

Among other African cities, in terms of solid waste management (SWM), Harare has been ranked as one of the poorest. The municipality struggles to efficiently provide SWM services to its residents. Considering that SWM systems are complex, the individual behaviour of its components (waste generation, collection, and disposal) determines the overall performance of the system. This mini-review thus aims to understand the management system of the urban city’s biggest source of solid waste which is household solid waste (HSW). The systematic literature review methodology using NVIVO was used to analyse the literature. Out of a selected sample size of 500 journal articles, 26 were selected based on their relevance to the study. The uncertainty of the data provided by the Harare City Council (HCC) and of HSW generation data harvested in the literature was calculated. According to the HCC data records, Harare has an average daily waste generation per capita of on average 0.38±0.1 kg producing about 207, 635, 294±56, 027, 040 kg of HSW generated annually. With the waste collection efficiency in Harare at about 72.4%±7.5%, the city collects approximately 170, 385, 600±33 384 209 kg of HSW annually. All the collected HSW is disposed of in the city’s major MSW dumpsite called Pomona and only about 23, 498, 400±3, 988, 817 kg MSW is recovered annually with the average recovery efficiency at around 9.5%±2.8%, where most of the waste recovery is done by the waste pickers