5,407 research outputs found
Phonon Band Structure and Thermal Transport Correlation in a Layered Diatomic Crystal
To elucidate the relationship between a crystal's structure, its thermal
conductivity, and its phonon dispersion characteristics, an analysis is
conducted on layered diatomic Lennard-Jones crystals with various mass ratios.
Lattice dynamics theory and molecular dynamics simulations are used to predict
the phonon dispersion curves and the thermal conductivity. The layered
structure generates directionally dependent thermal conductivities lower than
those predicted by density trends alone. The dispersion characteristics are
quantified using a set of novel band diagram metrics, which are used to assess
the contributions of acoustic phonons and optical phonons to the thermal
conductivity. The thermal conductivity increases as the extent of the acoustic
modes increases, and decreases as the extent of the stop bands increases. The
sensitivity of the thermal conductivity to the band diagram metrics is highest
at low temperatures, where there is less anharmonic scattering, indicating that
dispersion plays a more prominent role in thermal transport in that regime. We
propose that the dispersion metrics (i) provide an indirect measure of the
relative contributions of dispersion and anharmonic scattering to the thermal
transport, and (ii) uncouple the standard thermal conductivity
structure-property relation to that of structure-dispersion and
dispersion-property relations, providing opportunities for better understanding
of the underlying physical mechanisms and a potential tool for material design.Comment: 30 pages, 10 figure
Granular packings with moving side walls
The effects of movement of the side walls of a confined granular packing are
studied by discrete element, molecular dynamics simulations. The dynamical
evolution of the stress is studied as a function of wall movement both in the
direction of gravity as well as opposite to it. For all wall velocities
explored, the stress in the final state of the system after wall movement is
fundamentally different from the original state obtained by pouring particles
into the container and letting them settle under the influence of gravity. The
original packing possesses a hydrostatic-like region at the top of the
container which crosses over to a depth-independent stress. As the walls are
moved in the direction opposite to gravity, the saturation stress first reaches
a minimum value independent of the wall velocity, then increases to a
steady-state value dependent on the wall-velocity. After wall movement ceases
and the packing reaches equilibrium, the stress profile fits the classic
Janssen form for high wall velocities, while it has some deviations for low
wall velocities. The wall movement greatly increases the number of
particle-wall and particle-particle forces at the Coulomb criterion. Varying
the wall velocity has only small effects on the particle structure of the final
packing so long as the walls travel a similar distance.Comment: 11 pages, 10 figures, some figures in colo
Chandra Measurements of a Complete Sample of X-ray Luminous Galaxy Clusters: The Luminosity-Mass Relation
We present the results of work involving a statistically complete sample of
34 galaxy clusters, in the redshift range 0.15z0.3 observed with
. We investigate the luminosity-mass () relation for the cluster
sample, with the masses obtained via a full hydrostatic mass analysis. We
utilise a method to fully account for selection biases when modeling the
relation, and find that the relation is significantly different than the
relation modelled when not account for selection effects. We find that the
luminosity of our clusters is 2.20.4 times higher (when accounting for
selection effects) than the average for a given mass, its mass is 30% lower
than the population average for a given luminosity. Equivalently, using the
relation measured from this sample without correcting for selection biases
would lead to the underestimation by 40% of the average mass of a cluster with
a given luminosity. Comparing the hydrostatic masses to mass estimates
determined from the parameter, we find that they are entirely
consistent, irrespective of the dynamical state of the cluster.Comment: 31 pages, 43 figures, accepted for publication in MNRA
Plug flow and the breakdown of Bagnold scaling in cohesive granular flows
Cohesive granular media flowing down an inclined plane are studied by
discrete element simulations. Previous work on cohesionless granular media
demonstrated that within the steady flow regime where gravitational energy is
balanced by dissipation arising from intergrain forces, the velocity profile in
the flow direction scales with depth in a manner consistent with the
predictions of Bagnold. Here we demonstrate that this Bagnold scaling does not
hold for the analogous steady-flows in cohesive granular media. We develop a
generalization of the Bagnold constitutive relation to account for our
observation and speculate as to the underlying physical mechanisms responsible
for the different constitutive laws for cohesive and noncohesive granular
media.Comment: 8 pages, 10 figure
Calibration of the LIGO displacement actuators via laser frequency modulation
We present a frequency modulation technique for calibration of the
displacement actuators of the LIGO 4-km-long interferometric gravitational-wave
detectors. With the interferometer locked in a single-arm configuration, we
modulate the frequency of the laser light, creating an effective length
variation that we calibrate by measuring the amplitude of the frequency
modulation. By simultaneously driving the voice coil actuators that control the
length of the arm cavity, we calibrate the voice coil actuation coefficient
with an estimated 1-sigma uncertainty of less than one percent. This technique
enables a force-free, single-step actuator calibration using a displacement
fiducial that is fundamentally different from those employed in other
calibration methods.Comment: 10 pages, 5 figures, submitted to Classical and Quantum Gravit
Developing reverse logistics programs: A resource based view
Previous research proposes a six-process model for reverse logistics (RL) program design and execution. This manuscript advances RL related knowledge by incorporating the previous model into a broader theoretical framework, namely, the Resource Based View (RBV) of the firm. The current research employs exploratory techniques to investigate the applicability of RBV and its main tenants within the RL context. Based on in-depth interviews with 16 executives from seven different companies, the relationships among resources. RL capabilities, and RL competencies are explored
Surface complexation modeling of Cu(II) adsorption on mixtures of hydrous ferric oxide and kaolinite
<p>Abstract</p> <p>Background</p> <p>The application of surface complexation models (SCMs) to natural sediments and soils is hindered by a lack of consistent models and data for large suites of metals and minerals of interest. Furthermore, the surface complexation approach has mostly been developed and tested for single solid systems. Few studies have extended the SCM approach to systems containing multiple solids.</p> <p>Results</p> <p>Cu adsorption was measured on pure hydrous ferric oxide (HFO), pure kaolinite (from two sources) and in systems containing mixtures of HFO and kaolinite over a wide range of pH, ionic strength, sorbate/sorbent ratios and, for the mixed solid systems, using a range of kaolinite/HFO ratios. Cu adsorption data measured for the HFO and kaolinite systems was used to derive diffuse layer surface complexation models (DLMs) describing Cu adsorption. Cu adsorption on HFO is reasonably well described using a 1-site or 2-site DLM. Adsorption of Cu on kaolinite could be described using a simple 1-site DLM with formation of a monodentate Cu complex on a variable charge surface site. However, for consistency with models derived for weaker sorbing cations, a 2-site DLM with a variable charge and a permanent charge site was also developed.</p> <p>Conclusion</p> <p>Component additivity predictions of speciation in mixed mineral systems based on DLM parameters derived for the pure mineral systems were in good agreement with measured data. Discrepancies between the model predictions and measured data were similar to those observed for the calibrated pure mineral systems. The results suggest that quantifying specific interactions between HFO and kaolinite in speciation models may not be necessary. However, before the component additivity approach can be applied to natural sediments and soils, the effects of aging must be further studied and methods must be developed to estimate reactive surface areas of solid constituents in natural samples.</p
An integrative SDT-based investigation of the relation between financial incentives, motivation, and performance
To this day, researchers are debating the adequacy of using financial incentives to bolster performance in work settings. Our goal was to contribute to current understanding by considering the moderating role of distributive justice in the relation between financial incentives, motivation, and performance. Based on self-determination theory, we hypothesized that when bonuses are fairly distributed, using financial incentives makes employees feel more competent and autonomous, which in turn fosters greater autonomous motivation and lower controlled motivation, and better work performance. Results from path analyses in three samples supported our hypotheses, suggesting that the effect of financial incentives is contextual, and that compensation plans using financial incentives and bonuses can be effective when properly managed
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