Are there localized saddles behind the heterogeneous dynamics of supercooled liquids?

We numerically study the interplay between heterogeneous dynamics and properties of negatively curved regions of the potential energy surface in a model glassy system. We find that the unstable modes of saddles and quasi-saddles undergo a localization transition close to the Mode-Coupling critical temperature. We also find evidence of a positive spatial correlation between clusters of particles having large displacements in the unstable modes and dynamical heterogeneities.Comment: 7 pages, 3 figures, submitted to Europhys. Let

Growing Correlation Length on Cooling Below the Onset of Caging in a Simulated Glass-Forming Liquid

We present a calculation of a fourth-order, time-dependent density correlation function that measures higher-order spatiotemporall correlations of the density of a liquid. From molecular dynamics simulations of a glass-forming Lennard-Jones liquid, we find that the characteristic length scale of this function has a maximum as a function of time which increases steadily beyond the characteristic length of the static pair correlation function $g(r)$ in the temperature range approaching the mode coupling temperature from above

Damage spreading and dynamic stability of kinetic Ising models

We investigate how the time evolution of different kinetic Ising models depends on the initial conditions of the dynamics. To this end we consider the simultaneous evolution of two identical systems subjected to the same thermal noise. We derive a master equation for the time evolution of a joint probability distribution of the two systems. This equation is then solved within an effective-field approach. By analyzing the fixed points of the master equation and their stability we identify regular and chaotic phases.Comment: 4 pages RevTeX, 2 Postscript figure

Crystalline Assemblies and Densest Packings of a Family of Truncated Tetrahedra and the Role of Directional Entropic Forces

Polyhedra and their arrangements have intrigued humankind since the ancient Greeks and are today important motifs in condensed matter, with application to many classes of liquids and solids. Yet, little is known about the thermodynamically stable phases of polyhedrally-shaped building blocks, such as faceted nanoparticles and colloids. Although hard particles are known to organize due to entropy alone, and some unusual phases are reported in the literature, the role of entropic forces in connection with polyhedral shape is not well understood. Here, we study thermodynamic self-assembly of a family of truncated tetrahedra and report several atomic crystal isostructures, including diamond, {\beta}-tin, and high- pressure lithium, as the polyhedron shape varies from tetrahedral to octahedral. We compare our findings with the densest packings of the truncated tetrahedron family obtained by numerical compression and report a new space filling polyhedron, which has been overlooked in previous searches. Interestingly, the self-assembled structures differ from the densest packings. We show that the self-assembled crystal structures can be understood as a tendency for polyhedra to maximize face-to-face alignment, which can be generalized as directional entropic forces.Comment: Article + supplementary information. 23 pages, 10 figures, 2 table

Dynamics of particles and cages in an experimental 2D glass former

We investigate the dynamics of a glass forming 2D colloidal mixture and show the existence of collective motions of the particles. We introduce a mean square displacement MSD with respect to the nearest neighbors which shows remarkable deviations from the usual MSD quantifying the individual motion of our particles. Combined with the analysis of the self part of the Van Hove function this indicates a coupled motion of particles with their cage as well as intra cage hopping processes.Comment: Submitted to EP

Scaling in Late Stage Spinodal Decomposition with Quenched Disorder

We study the late stages of spinodal decomposition in a Ginzburg-Landau mean field model with quenched disorder. Random spatial dependence in the coupling constants is introduced to model the quenched disorder. The effect of the disorder on the scaling of the structure factor and on the domain growth is investigated in both the zero temperature limit and at finite temperature. In particular, we find that at zero temperature the domain size, $R(t)$, scales with the amplitude, $A$, of the quenched disorder as $R(t) = A^{-\beta} f(t/A^{-\gamma})$ with $\beta \simeq 1.0$ and $\gamma \simeq 3.0$ in two dimensions. We show that $\beta/\gamma = \alpha$, where $\alpha$ is the Lifshitz-Slyosov exponent. At finite temperature, this simple scaling is not observed and we suggest that the scaling also depends on temperature and $A$. We discuss these results in the context of Monte Carlo and cell dynamical models for phase separation in systems with quenched disorder, and propose that in a Monte Carlo simulation the concentration of impurities, $c$, is related to $A$ by $A \sim c^{1/d}$.Comment: RevTex manuscript 5 pages and 5 figures (obtained upon request via email [email protected]

Heterogeneous slow dynamics in a two dimensional doped classical antiferromagnet

We introduce a lattice model for a classical doped two dimensional antiferromagnet which has no quenched disorder, yet displays slow dynamics similar to those observed in supercooled liquids. We calculate two-time spatial and spin correlations via Monte Carlo simulations and find that for sufficiently low temperatures, there is anomalous diffusion and stretched-exponential relaxation of spin correlations. The relaxation times associated with spin correlations and diffusion both diverge at low temperatures in a sub-Arrhenius fashion if the fit is done over a large temperature-window or an Arrhenius fashion if only low temperatures are considered. We find evidence of spatially heterogeneous dynamics, in which vacancies created by changes in occupation facilitate spin flips on neighbouring sites. We find violations of the Stokes-Einstein relation and Debye-Stokes-Einstein relation and show that the probability distributions of local spatial correlations indicate fast and slow populations of sites, and local spin correlations indicate a wide distribution of relaxation times, similar to observ ations in other glassy systems with and without quenched disorder.Comment: 12 pages, 17 figures, corrected erroneous figure, and improved quality of manuscript, updated reference

Arrested States formed on Quenching Spin Chains with Competing Interactions and Conserved Dynamics

We study the effects of rapidly cooling to T = 0 a spin chain with conserved dynamics and competing interactions. Depending on the degree of competition, the system is found to get arrested in different kinds of metastable states. The most interesting of these has an inhomogeneous mixture of interspersed active and quiescent regions. In this state, the steady-state autocorrelation function decays as a stretched exponential $\sim \exp(-{(t/\tau_{o})}^{{1}\over{3}})$, and there is a two-step relaxation to equilibrium when the temperature is raised slightly.Comment: 4 pages, Latex, 3 postscript figures. Phys. Rev. E to appear (1999

Damage spreading in random field systems

We investigate how a quenched random field influences the damage spreading transition in kinetic Ising models. To this end we generalize a recent master equation approach and derive an effective field theory for damage spreading in random field systems. This theory is applied to the Glauber Ising model with a bimodal random field distribution. We find that the random field influences the spreading transition by two different mechanisms with opposite effects. First, the random field favors the same particular direction of the spin variable at each site in both systems which reduces the damage. Second, the random field suppresses the magnetization which, in turn, tends to increase the damage. The competition between these two effects leads to a rich behavior.Comment: 4 pages RevTeX, 3 eps figure

Heterogeneities in systems with quenched disorder

We study the strong role played by structural (quenched) heterogeneities on static and dynamic properties of the Frustrated Ising Lattice Gas in two dimensions, already in the liquid phase. Differently from the dynamical heterogeneities observed in other glass models in this case they may have infinite lifetime and be spatially pinned by the quenched disorder. We consider a measure of local frustration, show how it induces the appearance of spatial heterogeneities and how this reflects in the observed behavior of equilibrium density distributions and dynamic correlation functions.Comment: 8 page