8,875 research outputs found
Thermal analysis of submicron nanocrystalline diamond films
The thermal properties of sub-μm nanocrystalline diamond films in the range of 0.37–1.1 μm grown by hot filament CVD, initiated by bias enhanced nucleation on a nm-thin Si-nucleation layer on various substrates, have been characterized by scanning thermal microscopy. After coalescence, the films have been outgrown with a columnar grain structure. The results indicate that even in the sub-μm range, the average thermal conductivity of these NCD films approaches 400 W m− 1 K− 1. By patterning the films into membranes and step-like mesas, the lateral component and the vertical component of the thermal conductivity, k<sub>lateral</sub> and k<sub>vertical</sub>, have been isolated showing an anisotropy between vertical conduction along the columns, with k<sub>vertical</sub> ≈ 1000 W m− 1 K− 1, and a weaker lateral conduction across the columns, with k<sub>lateral</sub> ≈ 300 W m− 1 K− 1
The Decay Properties of the Finite Temperature Density Matrix in Metals
Using ordinary Fourier analysis, the asymptotic decay behavior of the density
matrix F(r,r') is derived for the case of a metal at a finite electronic
temperature. An oscillatory behavior which is damped exponentially with
increasing distance between r and r' is found. The decay rate is not only
determined by the electronic temperature, but also by the Fermi energy. The
theoretical predictions are confirmed by numerical simulations
Lentiviral vectors with amplified beta cell-specific gene expression.
An important goal of gene therapy is to be able to deliver genes, so that they express in a pattern that recapitulates the expression of an endogenous cellular gene. Although tissue-specific promoters confer selectivity, in a vector-based system, their activity may be too weak to mediate detectable levels in gene-expression studies. We have used a two-step transcriptional amplification system to amplify gene expression from lentiviral vectors using the human insulin promoter. In this system, the human insulin promoter drives expression of a potent synthetic transcription activator (the yeast GAL4 DNA-binding domain fused to the activation domain of the Herpes simplex virus-1 VP16 activator), which in turn activates a GAL4-responsive promoter, driving the enhanced green fluorescent protein reporter gene. Vectors carrying the human insulin promoter did not express in non-beta-cell lines, but expressed in murine insulinoma cell lines, indicating that the human insulin promoter was capable of conferring cell specificity of expression. The insulin-amplifiable vector was able to amplify gene expression five to nine times over a standard insulin-promoter vector. In primary human islets, gene expression from the insulin-promoted vectors was coincident with insulin staining. These vectors will be useful in gene-expression studies that require a detectable signal and tissue specificity
Droplet activation, separation, and compositional analysis: laboratory studies and atmospheric measurements
Droplets produced in a cloud condensation nuclei chamber (CCNC) as a function of supersaturation have been separated from unactivated aerosol particles using counterflow virtual impaction. Residual material after droplets were evaporated was chemically analyzed with an Aerodyne Aerosol Mass Spectrometer (AMS) and the Particle Analysis by Laser Mass Spectrometry (PALMS) instrument. Experiments were initially conducted to verify activation conditions for monodisperse ammonium sulfate particles and to determine the resulting droplet size distribution as a function of supersaturation. Based on the observed droplet size, the counterflow virtual impactor cut-size was set to differentiate droplets from unactivated interstitial particles. Validation experiments were then performed to verify that only droplets with sufficient size passed through the counterflow virtual impactor for subsequent analysis. A two-component external mixture of monodisperse particles was also exposed to a supersaturation which would activate one of the types (hygroscopic salts) but not the other (polystyrene latex spheres or adipic acid). The mass spectrum observed after separation indicated only the former, validating separation of droplets from unactivated particles. Results from ambient measurements using this technique and AMS analysis were inconclusive, showing little chemical differentiation between ambient aerosol and activated droplet residuals, largely due to low signal levels. When employing as single particle mass spectrometer for compositional analysis, however, we observed enhancement of sulfate in droplet residuals
Droplet activation, separation, and compositional analysis: laboratory studies and atmospheric measurements [Discussion paper]
Droplets produced in a cloud condensation nucleus chamber as a function of supersaturation have been separated from unactivated aerosol particles using counterflow virtual impaction. Residual material after droplets were evaporated was chemically analyzed with an Aerodyne Aerosol Mass Spectrometer and the Particle Analysis by Laser Mass Spectrometry instrument. Experiments were initially conducted to verify activation conditions for monodisperse ammonium sulfate particles and to determine the resulting droplet size distribution as a function of supersaturation. Based on the observed droplet size, the counterflow virtual impactor cut-size was set to differentiate droplets from unactivated interstitial particles. Validation experiments were then performed to verify that only droplets with sufficient size passed through the counterflow virtual impactor for subsequent analysis. A two-component external mixture of monodisperse particles was also exposed to a supersaturation which would activate one of the types (ammonium sulfate) but not the other (polystyrene latex spheres). The mass spectrum observed after separation indicated only the former, validating separation of droplets from unactivated particles. Results from atmospheric measurements using this technique indicate that aerosol particles often activate predominantly as a function of particle size. Chemical composition is not irrelevant, however, and we observed enhancement of sulfate in droplet residuals using single particle analysis
A realistic model of superfluidity in the neutron star inner crust
A semi-microscopic self-consistent quantum approach developed recently to
describe the inner crust structure of neutron stars within the Wigner-Seitz
(WS) method with the explicit inclusion of neutron and proton pairing
correlations is further developed. In this approach, the generalized energy
functional is used which contains the anomalous term describing the pairing. It
is constructed by matching the realistic phenomenological functional by Fayans
et al. for describing the nuclear-type cluster in the center of the WS cell
with the one calculated microscopically for neutron matter. Previously the
anomalous part of the latter was calculated within the BCS approximation. In
this work corrections to the BCS theory which are known from the many-body
theory of pairing in neutron matter are included into the energy functional in
an approximate way. These modifications have a sizable influence on the
equilibrium configuration of the inner crust, i.e. on the proton charge Z and
the radius R_c of the WS cell. The effects are quite significant in the region
where the neutron pairing gap is larger.Comment: 24 pages, 14 figures; LaTeX, submitted to EPJ
Electron Localization in the Insulating State
The insulating state of matter is characterized by the excitation spectrum,
but also by qualitative features of the electronic ground state. The insulating
ground wavefunction in fact: (i) sustains macroscopic polarization, and (ii) is
localized. We give a sharp definition of the latter concept, and we show how
the two basic features stem from essentially the same formalism. Our approach
to localization is exemplified by means of a two--band Hubbard model in one
dimension. In the noninteracting limit the wavefunction localization is
measured by the spread of the Wannier orbitals.Comment: 5 pages including 3 figures, submitted to PR
Ab Initio Calculation of Impurity Effects in Copper Oxide Materials
We describe a method for calculating, within density functional theory, the
electronic structure associated with typical defects which substitute for Cu in
the CuO2 planes of high-Tc superconducting materials. The focus is primarily on
Bi2Sr2CaCu2O8, the material on which most STM measurements of impurity
resonances in the superconducting state have been performed. The magnitudes of
the effective potentials found for Zn, Ni and vacancies on the in-plane Cu
sites in this host material are remarkably consistent with phenomenological
fits of potential scattering models to STM resonance energies. The effective
potential ranges are quite short, of order 1 A with weak long range tails, in
contrast to some current models of extended potentials which attempt to fit STM
data. For the case of Zn and Cu vacancies, the effective potentials are
strongly repulsive, and states on the impurity site near the Fermi level are
simply removed. The local density of states (LDOS) just above the impurity is
nevertheless found to be a maximum in the case of Zn and a local minimum in
case of the vacancy, in agreement with experiment. The Zn and Cu vacancy
patterns are explained as due to the long-range tails of the effective impurity
potential at the sample surface. The case of Ni is richer due to the Ni atom's
strong hybridization with states near the Fermi level; in particular, the short
range part of the potential is attractive, and the LDOS is found to vary
rapidly with distance from the surface and from the impurity site. We propose
that the current controversy surrounding the observed STM patterns can be
resolved by properly accounting for the effective impurity potentials and
wave-functions near the cuprate surface. Other aspects of the impurity states
for all three species are discussed.Comment: 37 pp. pdf including figures, submitted to Phys. Rev.
Physical mechanisms of interface-mediated intervalley coupling in Si
The conduction band degeneracy in Si is detrimental to quantum computing
based on spin qubits, for which a nondegenerate ground orbital state is
desirable. This degeneracy is lifted at an interface with an insulator as the
spatially abrupt change in the conduction band minimum leads to intervalley
scattering. We present a theoretical study of the interface-induced valley
splitting in Si that provides simple criteria for optimal fabrication
parameters to maximize this splitting. Our work emphasizes the relevance of
different interface-related properties to the valley splitting.Comment: 4 pages, revised versio
- …