Dynamic mechanical response of polymer networks

The dynamic-mechanical response of flexible polymer networks is studied in the framework of tube model, in the limit of small affine deformations, using the approach based on Rayleighian dissipation function. The dynamic complex modulus G* is calculated from the analysis of a network strand relaxation to the new equilibrium conformation around the distorted primitive path. Chain equilibration is achieved via a sliding motion of polymer segments along the tube, eliminating the inhomogeneity of the polymer density caused by the deformation. The characteristic relaxation time of this motion separates the low-frequency limit of the complex modulus from the high-frequency one, where the main role is played by chain entanglements, analogous to the rubber plateau in melts. The dependence of storage and loss moduli, G' and G'', on crosslink and entanglement densities gives an interpolation between polymer melts and crosslinked networks. We discuss the experimental implications of the rather short relaxation time and the slow square-root variation of the moduli and the loss factor tan at higher frequencies.Comment: Journal of Chemical Physics (Oct-2000); Lates, 4 EPS figures include

Statistical Mechanics of Vibration-Induced Compaction of Powders

We propose a theory which describes the density relaxation of loosely packed, cohesionless granular material under mechanical tapping. Using the compactivity concept we develope a formalism of statistical mechanics which allows us to calculate the density of a powder as a function of time and compactivity. A simple fluctuation-dissipation relation which relates compactivity to the amplitude and frequency of a tapping is proposed. Experimental data of E.R.Nowak et al. [{\it Powder Technology} 94, 79 (1997) ] show how density of initially deposited in a fluffy state powder evolves under carefully controlled tapping towards a random close packing (RCP) density. Ramping the vibration amplitude repeatedly up and back down again reveals the existence of reversible and irreversible branches in the response. In the framework of our approach the reversible branch (along which the RCP density is obtained) corresponds to the steady state solution of the Fokker-Planck equation whereas the irreversible one is represented by a superposition of "excited states" eigenfunctions. These two regimes of response are analyzed theoretically and a qualitative explanation of the hysteresis curve is offered.Comment: 11 pages, 2 figures, Latex. Revised tex

Temperature contour maps at the strain-induced martensitic transition of a Cu–Zn–Al shape-memory single crystal

We study temperature changes at the reverse strain-induced martensitic transformation in a Cu–Zn–Al single crystal. Infrared thermal imaging reveals a markedly inhomogeneous temperature distribution. The evolution of the contour temperature maps enables information to be extracted on the kinetics of the interface motion

Tapping Spin Glasses

We consider a tapping dynamics, analogous to that in experiments on granular media, on spin glasses and ferromagnets on random thin graphs. Between taps, zero temperature single spin flip dynamics takes the system to a metastable state. Tapping, corresponds to flipping simultaneously any spin with probability $p$. This dynamics leads to a stationary regime with a steady state energy $E(p)$. We analytically solve this dynamics for the one dimensional ferromagnet and $\pm J$ spin glass. Numerical simulations for spin glasses and ferromagnets of higher connectivity are carried out, in particular we find a novel first order transition for the ferromagnetic systems.Comment: 5 pages, 3 figures, RevTe

Observing the evaporation transition in vibro-fluidized granular matter

By shaking a sand box the grains on the top start to jump giving the picture of evaporating a sand bulk, and a gaseous transition starts at the surface granular matter (GM) bed. Moreover the mixture of the grains in the whole bed starts to move in a cooperative way which is far away from a Brownian description. In a previous work we have shown that the key element to describe the statistics of this behavior is the exclusion of volume principle, whereby the system obeys a Fermi configurational approach. Even though the experiment involves an archetypal non-equilibrium system, we succeeded in defining a global temperature, as the quantity associated to the Lagrange parameter in a maximum entropic statistical description. In fact in order to close our approach we had to generalize the equipartition theorem for dissipative systems. Therefore we postulated, found and measured a fundamental dissipative parameter, written in terms of pumping and gravitational energies, linking the configurational entropy to the collective response for the expansion of the centre of mass (c.m.) of the granular bed. Here we present a kinetic approach to describe the experimental velocity distribution function (VDF) of this non-Maxwellian gas of macroscopic Fermi-like particles (mFp). The evaporation transition occurs mainly by jumping balls governed by the excluded volume principle. Surprisingly in the whole range of low temperatures that we measured this description reveals a lattice-gas, leading to a packing factor, which is independent of the external parameters. In addition we measure the mean free path, as a function of the driving frequency, and corroborate our prediction from the present kinetic theory.Comment: 6 pages, 4 figures, submitted for publication September 1st, 200

Zenithal bistability in a nematic liquid crystal device with a monostable surface condition

The ground-state director configurations in a grating-aligned, zenithally bistable nematic device are calculated in two dimensions using a Q tensor approach. The director profiles generated are well described by a one-dimensional variation of the director across the width of the device, with the distorted region near the grating replaced by an effective surface anchoring energy. This work shows that device bistability can in fact be achieved by using a monostable surface term in the one-dimensional model. This implies that is should be possible to construct a device showing zenithal bistability without the need for a micropatterned surface

Dynamical response functions in models of vibrated granular media

In recently introduced schematic lattice gas models for vibrated dry granular media, we study the dynamical response of the system to small perturbations of shaking amplitudes and its relations with the characteristic fluctuations. Strong off equilibrium features appear and a generalized version of the fluctuation dissipation theorem is introduced. The relations with thermal glassy systems and the role of Edwards' compactivity are discussed.Comment: 12 pages, 2 postscript figure

The barriers to and enablers of providing reasonably adjusted health services to people with intellectual disabilities in acute hospitals: evidence from a mixed-methods study.

OBJECTIVE: To identify the factors that promote and compromise the implementation of reasonably adjusted healthcare services for patients with intellectual disabilities in acute National Health Service (NHS) hospitals. DESIGN: A mixed-methods study involving interviews, questionnaires and participant observation (July 2011-March 2013). SETTING: Six acute NHS hospital trusts in England. METHODS: Reasonable adjustments for people with intellectual disabilities were identified through the literature. Data were collected on implementation and staff understanding of these adjustments. RESULTS: Data collected included staff questionnaires (n=990), staff interviews (n=68), interviews with adults with intellectual disabilities (n=33), questionnaires (n=88) and interviews (n=37) with carers of patients with intellectual disabilities, and expert panel discussions (n=42). Hospital strategies that supported implementation of reasonable adjustments did not reliably translate into consistent provision of such adjustments. Good practice often depended on the knowledge, understanding and flexibility of individual staff and teams, leading to the delivery of reasonable adjustments being haphazard throughout the organisation. Major barriers included: lack of effective systems for identifying and flagging patients with intellectual disabilities, lack of staff understanding of the reasonable adjustments that may be needed, lack of clear lines of responsibility and accountability for implementing reasonable adjustments, and lack of allocation of additional funding and resources. Key enablers were the Intellectual Disability Liaison Nurse and the ward manager. CONCLUSIONS: The evidence suggests that ward culture, staff attitudes and staff knowledge are crucial in ensuring that hospital services are accessible to vulnerable patients. The authors suggest that flagging the need for specific reasonable adjustments, rather than the vulnerable condition itself, may address some of the barriers. Further research is recommended that describes and quantifies the most frequently needed reasonable adjustments within the hospital pathways of vulnerable patient groups, and the most effective organisational infrastructure required to guarantee their use, together with resource implications