452 research outputs found
Resolving the controversy on the glass transition temperature of water?
We consider experimental data on the dynamics of water (1) in glass-forming
aqueous mixtures with glass transition temperature Tg approaching the putative
Tg=136 K of water from above and below, (2) in confined spaces of nanometer in
size and (3) in the bulk at temperatures above the homogeneous nucleation
temperature. Altogether, the considered relaxation times from the data range
nearly over 15 decades from 10-12 to 103 s. Assisted by the various features in
the isothermal spectra and theoretical interpretation, these considerations
enable us to conclude that relaxation of un-crystallized water is highly
non-cooperative. The exponent Beta_K of its Kohlrausch stretched exponential
correlation function is not far from having the value of one, and hence the
deviation from exponential time decay is slight. Albeit the temperature
dependence of its alpha-relaxation time being non-Arrhenius, the corresponding
Tg-scaled temperature dependence has small steepness index m, likely less than
44 at Tg, and hence water is not 'fragile' as a glassformer. The separation in
time scale of the alpha- and the beta-relaxations is small at Tg, becomes
smaller at higher temperatures, and they merge together shortly above Tg. From
all these properties and by inference, water is highly non-cooperative as a
glass-former, it has short cooperative length-scale, and possibly minimal
configurational entropy and small change of heat capacity at Tg compared with
other organic glass-formers. This conclusion is perhaps unsurprising because
water is the smallest molecule. Our deductions from the data rule out that the
Tg of water is higher than 160 K, and suggest that it is close to the
traditional value of 136 K.Comment: 22 pages, 7 figure
On the unification of dwarf and giant elliptical galaxies
The near orthogonal distributions of dwarf elliptical (dE) and giant
elliptical (E) galaxies in the mu_e-Mag and mu_e-log(R_e) diagrams have been
interpreted as evidence for two distinct galaxy formation processes. However,
continuous, linear relationships across the alleged dE/E boundary at M_B = -18
mag - such as those between central surface brightness (mu_0) and (i) galaxy
magnitude and (ii) light-profile shape (n) - suggest a similar, governing
formation mechanism. Here we explain how these latter two linear trends
necessitate a different behavior for dE and E galaxies, exactly as observed, in
diagrams involving mu_e (and also _e). A natural consequence is that the
distribution of dEs and Es in Fundamental Plane type analyses that use the
associated intensity I_e, or _e, are expected to appear different. Together
with other linear trends across the alleged dE/E boundary, such as those
between luminosity and color, metallicity, and velocity dispersion, it appears
that the dEs form a continuous extension to the E galaxies. The presence of
partially depleted cores in luminous (M_B < -20.5 mag) Es does however signify
the action of a different physical process at the centers (< ~300 pc) of these
galaxies.Comment: 5 pages from the proceedings of the 2004 conference "Penetrating bars
through masks of cosmic dust: the Hubble tuning fork strikes a new note".
Edited by D. L. Block, I. Puerari, K. C. Freeman, R. Groess, and E. K. Bloc
Surface Brightness Fluctuations from archival ACS images: a stellar population and distance study
We derive Surface Brightness Fluctuations (SBF) and integrated magnitudes in
the V- and I-bands using Advanced Camera for Surveys (ACS) archival data. The
sample includes 14 galaxies covering a wide range of physical properties:
morphology, total absolute magnitude, integrated color. We take advantage of
the latter characteristic of the sample to check existing empirical
calibrations of absolute SBF magnitudes both in the I- and V-passbands.
Additionally, by comparing our SBF and color data with the Teramo-SPoT simple
stellar population models, and other recent sets of population synthesis
models, we discuss the feasibility of stellar population studies based on
fluctuation magnitudes analysis. The main result of this study is that
multiband optical SBF data and integrated colors can be used to significantly
constrain the chemical composition of the dominant stellar system in the
galaxy, but not the age in the case of systems older than 3 Gyr.
SBF color gradients are also detected and analyzed. These SBF gradient data,
together with other available data, point to the existence of mass dependent
metallicity gradients in galaxies, with the more massive objects showing a
non--negligible SBF versus color gradient. The comparison with models suggests
that such gradients imply more metal rich stellar populations in the galaxies'
inner regions with respect to the outer ones.Comment: ApJ Accepte
Coincident correlation between vibrational dynamics and primary relaxation of polymers with strong or weak johari-goldstein relaxation
The correlation between the vibrational dynamics, as sensed by the Debye-Waller factor, and the primary relaxation in the presence of secondary Johari-Goldstein (JG) relaxation, has been investigated through molecular dynamics simulations. Two melts of polymer chains with different bond length, resulting in rather different strength of the JG relaxation are studied. We focus on the bond-orientation correlation function, exhibiting higher JG sensitivity with respect to alternatives provided by torsional autocorrelation function and intermediate scattering function. We find that, even if changing the bond length alters both the strength and the relaxation time of the JG relaxation, it leaves unaffected the correlation between the vibrational dynamics and the primary relaxation. The finding is in harmony with previous studies reporting that numerical models not showing secondary relaxations exhibit striking agreement with experimental data of polymers also where the presence of JG relaxation is known
Lateral resolution of electrostatic force microscopy for mapping of dielectric interfaces in ambient conditions
The attainable lateral resolution of electrostatic force microscopy (EFM) in an ambient air environment on dielectric materials was characterized on a reference sample comprised of two distinct, immiscible glassy polymers cut in a cross-section by ultramicrotomy. Such a sample can be modeled as two semi-infinite dielectrics with a sharp interface, presenting a quasi-ideal, sharp dielectric contrast. Electric polarizability line profiles across the interface were obtained, in both lift-mode and feedback-regulated dynamic mode EFM, as a function of probe/surface separation, for different cases of oscillation amplitudes. We find that the results do not match predictions for dielectric samples, but comply well or are even better than predicted for conductive interfaces. A resolution down to 3 nm can be obtained by operating in feedback-regulated EFM realized by adopting constant-excitation frequency-modulation mode. This suggests resolution is ruled by the closest approach distance rather than by average separation, even with probe oscillation amplitudes as high as 10 nm. For better comparison with theoretical predictions, effective probe radii and cone aperture angles were derived from approach curves, by also taking into account the finite oscillation amplitude of the probe, by exploiting a data reduction procedure previously devised for the derivation of interatomic potentials
High Field Studies of the Hidden Order Transition in URuSi
We studied in detail the low temperature/high magnetic field phases of
URuSi single crystals with specific heat, magnetocaloric effect,
and magnetoresistance in magnetic fields up to 45 T. Data obtained down to 0.5
K, and extrapolated to T = 0, show a suppression of the hidden order phase at
H(0) = 35.9 0.35 T and the appearance of a new phase for magnetic
fields in excess of H(0) = 36.1 0.35 T observed \textit{only} at
temperatures lower than 6 K. In turn, complete suppression of this high field
state is attained at a critical magnetic field H(0) = 39.7 0.35 T.
No phase transitions are observed above 40 T. We discuss our results in the
context of itinerant vs. localized \textit{f}-electron behavior and consider
the implications for the hidden order phase.Comment: 4 pages, 3 figures Submitted May 10, 2002. Revised Sep 17, 200
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