4,229 research outputs found
Electronic structure of single-crystalline MgAlB probed by x-ray diffraction multipole refinements and polarization-dependent x-ray absorption spectroscopy
X-ray diffraction multipole refinements of single-crystalline
MgAlB and polarization-dependent near-edge x-ray absorption
fine structure at the B 1 edge reveal a strongly anisotropic electronic
structure. Comparing the data for superconducting compounds (, 1.0)
with those for the non-superconductor () gives direct evidence for a
rearrangement of the hybridizations of the boron bonds and underline the
importance of holes in the -bonded covalent states for the
superconducting properties of the diborides. The data indicate that Mg is
approximately divalent in MgB and suggest predominantly ionic bonds between
the Mg ions and the two-dimensional B rings. For AlB (), on the other
hand, about 1.5 electrons per Al atom are transferred to the B sheets while the
residual 1.5 electrons remain at the Al site which suggests significant
covalent bonding between the Al ions and the B sheets. This finding together
with the static electron deformation density points to almost equivalent
electron counts on B sheets of MgB and AlB\@, yet with a completely
different electron/hole distribution between the and bonds
Multi-agent system for dynamic manufacturing system optimization
This paper deals with the application of multi-agent system concept for optimization of dynamic uncertain process. These problems are known to have a computationally demanding objective function, which could turn to be infeasible when large problems are considered. Therefore, fast approximations to the objective function are required. This paper employs bundle of intelligent systems algorithms tied together in a multi-agent system. In order to demonstrate the system, a metal reheat furnace scheduling problem is adopted for highly demanded optimization problem. The proposed multi-agent approach has been evaluated for different settings of the reheat furnace scheduling problem. Particle Swarm Optimization, Genetic Algorithm with different classic and advanced versions: GA with chromosome differentiation, Age GA, and Sexual GA, and finally a Mimetic GA, which is based on combining the GA as a global optimizer and the PSO as a local optimizer. Experimentation has been performed to validate the multi-agent system on the reheat furnace scheduling problem
Suppression of spin-state transition in epitaxially strained LaCoO_{3}
Epitaxial thin films of LaCoO_{3} (E-LCO) exhibit ferromagnetic order with a
transition temperature T_c = 85 K, while polycrystalline thin LaCoO_{3} films
(P-LCO) remain paramagnetic. The temperature-dependent spin-state structure for
both E-LCO and P-LCO was studied by x-ray absorption spectroscopy at the Co
L_{2,3} and O K edges. Considerable spectral redistributions over temperature
are observed for P-LCO. The spectra for E-LCO, on the other hand, do not show
any significant changes for temperatures between 30 K and 450 K at both edges,
indicating that the spin state remains constant and that the epitaxial strain
inhibits any population of the low-spin (S = 0) state with decreasing
temperature. This observation identifies an important prerequisite for
ferromagnetism in E-LCO thin films.Comment: 5 pages, 5 figures, submitted to Physical Review
Electronic Scattering Effects in Europium-Based Iron Pnictides
In a comprehensive study, we investigate the electronic scattering effects in
EuFe(AsP) by using Fourier-transform infrared
spectroscopy. In spite of the fact that Eu local moments order around
\,K, the overall optical response is strikingly similar
to the one of the well-known Ba-122 pnictides. The main difference lies within
the suppression of the lower spin-density-wave gap feature. By analysing our
spectra with a multi-component model, we find that the high-energy feature
around 0.7\,eV -- often associated with Hund's rule coupling -- is highly
sensitive to the spin-density-wave ordering, this further confirms its direct
relationship to the dynamics of itinerant carriers. The same model is also used
to investigate the in-plane anisotropy of magnetically detwinned
EuFeAs in the antiferromagnetically ordered state, yielding a
higher Drude weight and lower scattering rate along the crystallographic
-axis. Finally, we analyse the development of the room temperature spectra
with isovalent phosphor substitution and highlight changes in the scattering
rate of hole-like carriers induced by a Lifshitz transition
Crystal and magnetic structure of La_{1-x}Sr_{1+x}MnO_{4} : role of the orbital degree of freedom
The crystal and magnetic structure of La_{1-x}Sr_{1+x}MnO_4 (0<x<0.7) has
been studied by diffraction techniques and high resolution capacitance
dilatometry. There is no evidence for a structural phase transition like those
found in isostructural cuprates or nickelates, but there are significant
structural changes induced by the variation of temperature and doping which we
attribute to a rearrangement of the orbital occupation.Comment: 8 pages, 6 figures, submitted to PR
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