Density Variations over Subparsec Scales in Diffuse Molecular Gas

We present high-resolution observations of interstellar CN, CH, CH^{+}, \ion{Ca}{1}, and \ion{Ca}{2} absorption lines toward the multiple star systems HD206267 and HD217035. Substantial variations in CN absorption are observed among three sight lines of HD206267, which are separated by distances of order 10,000 AU; smaller differences are seen for CH, CH^{+}, and \ion{Ca}{1}. Gas densities for individual velocity components are inferred from a chemical model, independent of assumptions about cloud shape. While the component densities can differ by factors of 5.0 between adjacent sightlines, the densities are always less than 5000 cm^{-3}. Calculations show that the derived density contrasts are not sensitive to the temperature or reaction rates used in the chemical model. A large difference in the CH^{+} profiles (a factor of 2 in column density) is seen in the lower density gas toward HD217035.Comment: 9 pages, 2 figures. Accepted for publication in ApJ

OH+ in Diffuse Molecular Clouds

Near ultraviolet observations of OH+ and OH in diffuse molecular clouds reveal a preference for different environments. The dominant absorption feature in OH+ arises from a main component seen in CH+ (that with the highest CH+/CH column density ratio), while OH follows CN absorption. This distinction provides new constraints on OH chemistry in these clouds. Since CH+ detections favor low-density gas with small fractions of molecular hydrogen, this must be true for OH+ as well, confirming OH+ and H2O+ observations with the Herschel Space Telescope. Our observed correspondence indicates that the cosmic ray ionization rate derived from these measurements pertains to mainly atomic gas. The association of OH absorption with gas rich in CN is attributed to the need for high enough density and molecular fraction before detectable amounts are seen. Thus, while OH+ leads to OH production, chemical arguments suggest that their abundances are controlled by different sets of conditions and that they coexist with different sets of observed species. Of particular note is that non-thermal chemistry appears to play a limited role in the synthesis of OH in diffuse molecular clouds.Comment: 15 pages, 4 figures, to appear in ApJ Letter

Variable Interstellar Absorption toward the Halo Star HD 219188 - Implications for Small-Scale Interstellar Structure

Within the last 10 years, strong, narrow Na I absorption has appeared at v_sun ~ -38 km/s toward the halo star HD 219188; that absorption has continued to strengthen, by a factor 2-3, over the past three years. The line of sight appears to be moving into/through a relatively cold, quiescent intermediate velocity (IV) cloud, due to the 13 mas/yr proper motion of HD 219188; the variations in Na I probe length scales of 2-38 AU/yr. UV spectra obtained with the HST GHRS in 1994-1995 suggest N(H_tot) ~ 4.8 X 10^{17} cm^{-2}, ``halo cloud'' depletions, n_H ~ 25 cm^{-3}, and n_e ~ 0.85-6.2 cm^{-3} (if T ~ 100 K) for the portion of the IV cloud sampled at that time. The relatively high fractional ionization, n_e/n_H >~ 0.034, implies that hydrogen must be partially ionized. The N(Na I)/N(H_tot) ratio is very high; in this case, the variations in Na I do not imply large local pressures or densities.Comment: 12 pages; aastex; to appear in ApJ

Monitoring the Variable Interstellar Absorption toward HD 219188 with HST/STIS

We discuss the results of continued spectroscopic monitoring of the variable intermediate-velocity (IV) absorption at v = -38 km/s toward HD 219188. After reaching maxima in mid-2000, the column densities of both Na I and Ca II in that IV component declined by factors >= 2 by the end of 2006. Comparisons between HST/STIS echelle spectra obtained in 2001, 2003, and 2004 and HST/GHRS echelle spectra obtained in 1994--1995 indicate the following: (1) The absorption from the dominant species S II, O I, Si II, and Fe II is roughly constant in all four sets of spectra -- suggesting that the total N(H) and the (mild) depletions have not changed significantly over a period of nearly ten years. (2) The column densities of the trace species C I (both ground and excited fine-structure states) and of the excited state C II* all increased by factors of 2--5 between 1995 and 2001 -- implying increases in the hydrogen density n_H (from about 20 cm^{-3} to about 45 cm^{-3}) and in the electron density n_e (by a factor >= 3) over that 6-year period. (3) The column densities of C I and C II* -- and the corresponding inferred n_H and n_e -- then decreased slightly between 2001 and 2004. (4) The changes in C I and C II* are very similar to those seen for Na I and Ca II. The relatively low total N(H) and the modest n_H suggest that the -38 km/s cloud toward HD 219188 is not a very dense knot or filament. Partial ionization of hydrogen appears to be responsible for the enhanced abundances of Na I, C I, Ca II, and C II*. In this case, the variations in those species appear to reflect differences in density and ionization [and not N(H)] over scales of tens of AU.Comment: 33 pages, 6 figures, aastex, accepted to Ap

Interstellar absorptions towards the LMC: Small-scale density variations in Milky Way disc gas

Observations show that the ISM contains sub-structure on scales less than 1 pc, detected in the form of spatial and temporal variations in column densities or optical depth. Despite the number of detections, the nature and ubiquity of the small-scale structure in the ISM is not yet fully understood. We use UV absorption data mainly from FUSE and partly from STIS of six LMC stars (Sk-67{\deg}111, LH54-425, Sk-67{\deg}107, Sk-67{\deg}106, Sk-67{\deg}104, and Sk-67{\deg}101), all located within 5 arcmin of each other, and analyse the physical properties of the Galactic disc gas in front of the LMC on sub-pc scales. We analyse absorption lines of a number of ions within the UV spectral range. Most importantly, interstellar molecular hydrogen, neutral oxygen, and fine-structure levels of neutral carbon have been used in order to study changes in the density and the physical properties of the Galactic disc gas over small angular scales. While most species do not show any significant variation in their column densities, we find an enhancement of almost 2 dex for H_2 from Sk-67{\deg}111 to Sk-67{\deg}101, accompanied by only a small variation in the OI column density. Based on the formation-dissociation equilibrium, we trace these variations to the actual density variations in the molecular gas. On the smallest spatial scale of < 0.08 pc, between Sk-67{\deg}107 and LH54-425, we find a gas density variation of a factor of 1.8. The line of sight towards LH54-425 does not follow the relatively smooth change seen from Sk-67{\deg}101 to Sk-67{\deg}111, suggesting that sub-structure might exist on a smaller spatial scale than the linear extent of our sight-lines. Our observations suggest that the detected H_2 in these six lines of sight is not necessarily physically connected, but that we are sampling molecular cloudlets with pathlengths < 0.1-1.8 pc and possibly different densities.Comment: 17 pages, 8 figures. Accepted for publication in A&

Observation of interstellar lithium in the low-metallicity Small Magellanic Cloud

The primordial abundances of light elements produced in the standard theory of Big Bang nucleosynthesis (BBN) depend only on the cosmic ratio of baryons to photons, a quantity inferred from observations of the microwave background. The predicted primordial 7Li abundance is four times that measured in the atmospheres of Galactic halo stars. This discrepancy could be caused by modification of surface lithium abundances during the stars' lifetimes or by physics beyond the Standard Model that affects early nucleosynthesis. The lithium abundance of low-metallicity gas provides an alternative constraint on the primordial abundance and cosmic evolution of lithium that is not susceptible to the in situ modifications that may affect stellar atmospheres. Here we report observations of interstellar 7Li in the low-metallicity gas of the Small Magellanic Cloud, a nearby galaxy with a quarter the Sun's metallicity. The present-day 7Li abundance of the Small Magellanic Cloud is nearly equal to the BBN predictions, severely constraining the amount of possible subsequent enrichment of the gas by stellar and cosmic-ray nucleosynthesis. Our measurements can be reconciled with standard BBN with an extremely fine-tuned depletion of stellar Li with metallicity. They are also consistent with non-standard BBN.Comment: Published in Nature. Includes main text and Supplementary Information. Replaced with final title and abstrac

Field evaluation of application variables and plant density for bell pepper pest management

Bell peppers are a valuable vegetable crop in the U.S. Management of pepper insects and diseases relies on chemical control options. Because there are relatively few chemical options available for pepper pest management, it is critical to make efficacious application of pesticides. Foliar spray coverage and spray retention in the middle and bottom of bell pepper canopies were compared using fluorescent dyes and food coloring, respectively. Several delivery systems were evaluated, including air-induction and twin-fan nozzles, air-assisted delivery with conventional hydraulic nozzles, and pneumatic atomization nozzles producing electrically charged sprays. Plant spacing between and within rows was evaluated in the second year of the application trial. Travel speeds of 6.4 and 12.9 km h^-1 were also evaluated. Faster travel speeds did not significantly affect spray retention in twin-row canopies. The electrostatic sprayer produced the greatest differences in deposits between the middle and bottom of the canopy. Although there was no more than a 25 cm difference between leaves sampled from the middle and bottom canopy locations, spray retention on foliage in the bottom canopy locations had significantly lower retention than the middle canopy for almost all sprayer types. Despite differences in atomization characteristics, the performance of the twin-fan nozzle and the air-induction nozzle treatments were similar. Air-assisted delivery provided no advantage in the amount of spray retained on the foliage, but it produced more desirable spray quality on foliage and resulted in more spray retained on whole fruit

Key signal contributions in photothermal deflection spectroscopy

We report on key signal contributions in photothermal deflection spectroscopy (PDS) of semiconductors at photon energies below the bandgap energy and show how to extract the actual absorption properties from the measurement data. To this end, we establish a rigorous computation scheme for the deflection signal including semi-analytic raytracing to analyze the underlying physical effects. The computation takes into account linear and nonlinear absorption processes affecting the refractive index and thus leading to a deflection of the probe beam. We find that beside the linear mirage effect, nonlinear absorption mechanisms make a substantial contribution to the signal for strongly focussed pump beams and sample materials with high two-photon absorption coefficients. For example, the measured quadratic absorption contribution exceeds 5% at a pump beam intensity of about ${1.3}\times{10^{5}}\;{W}/{cm^{2}}$ in Si and at ${5}\times{10^{4}}\;{W}/{cm^{2}}$ in GaAs. In addition, our method also includes thermal expansion effects as well as spatial gradients of the attenuation properties. We demonstrate that these effects result in an additional deflection contribution which substantially depends on the distance of the photodetector from the readout point. This distance dependent contribution enhances the surface related PDS signal up to two orders of magnitude and may be misinterpreted as surface absorption if not corrected in the analysis of the measurement data. We verify these findings by PDS measurements on crystalline silicon at a wavelength of 1550 nm and provide guidelines how to extract the actual attenuation coefficient from the PDS signal.Comment: 10 pages, 16 figures, submitted to Journal of Applied Physiv

Revisiting the Chlorine Abundance in Diffuse Interstellar Clouds from Measurements with the Copernicus Satellite

We reanalyzed interstellar Cl I and Cl II spectra acquired with the Copernicus satellite. The directions for this study come from those of Crenny & Federman and sample the transition from atomic to molecular rich clouds where the unique chemistry leading to molecules containing chlorine is initiated. Our profile syntheses relied on up-to-date laboratory oscillator strengths and component structures derived from published high-resolution measurements of K I absorption that were supplemented with Ca II and Na I D results. We obtain self-consistent results for the Cl I lines at 1088, 1097, and 1347 A from which precise column densities are derived. The improved set of results reveals clearer correspondences with H2 and total hydrogen column densities. These linear relationships arise from rapid conversion of Cl^+ to Cl^0 in regions where H2 is present.Comment: 17 pp, 2 tables, and 3 figures, to appear in The Astrophysical Journa