Absolute configuration sensing of chiral aryl-and aryloxy-propionic acids by biphenyl chiroptical probes

The absolute configuration of chiral 2-aryl and 2-aryloxy propionic acids, which are among the most common chiral environmental pollutants, has been readily and reliably established by either electronic circular dichroism spectroscopy or optical rotation measurements employing suitably designed 4,4′-disubstituted biphenyl probes. In fact, the 4,4′-biphenyl substitution gives rise to a red shift of the diagnostic electronic circular dichroism signal of the biphenyl A band employed for the configuration assignment, removing its overlap with other interfering dichroic bands and allowing its clear sign identification. The largest A band red shift, and thus the most reliable results, are obtained by employing as a probe the 4,4′-dinitro substituted biphenylazepine 3c. The method was applied to the absolute configuration assignment of 2-arylpropionic acids ibuprofen (1a), naproxen (1b), ketoprofen (1c) and flurbiprofen (1d), as well as to the 2-aryloxypropionic acids 2-phenoxypropionic acid (2a) and 2-naphthoxypropionic acid (2b). This approach, allowing us to reveal the sample’s absolute configuration by simple optical rotation measurements, is potentially applicable to online analyses of both the enantiomeric composition and absolute configuration of these chiral pollutants

Photo-fenton degradation of pentachlorophenol l: competition between additives and photolysis

[EN] In the present work, the photo-Fenton degradation of pentachlorophenol (PCP, 1 mg/L) has been studied under simulated and natural solar irradiation; moreover, the effect on the process efficiency of urban waste-derived soluble bio-based substances (SBO), structurally comparable to humic acids, has been investigated. Experiments showed a crucial role of PCP photolysis, present in the solar pilot plant and hindered by the Pyrex (R) filter present in the solar simulator. Indeed, the SBO screen negatively affects PCP degradation when working under natural solar light, where the photolysis of PCP is relevant. In contrast, in the absence of PCP photolysis, a significant improvement of the photo-Fenton process was observed when added to SBO. Furthermore, SBO were able to extend the application of the photo-Fenton process at circumneutral pH values, due to their ability to complex iron, avoiding its precipitation as oxides or hydroxides. This positive effect has been observed at higher concentration of Fe(II) (4 mg/L), whereas at 1 mg/L, the degradation rates of PCP were comparable in the presence and absence of SBO.This work was realized with the financial support of the academic interchange from the Marie Sklodowska-Curie Research and Innovation Staff Exchange project, funded by the European Commission H2020-MSCA-RISE-2014 within the framework of the research project Mat4treaT (Project number: 645551).Vergura, EP.; García-Ballesteros, S.; Vercher Pérez, RF.; Santos-Juanes Jordá, L.; Bianco Prevot, A.; Arqués Sanz, A. (2019). Photo-Fenton Degradation of Pentachlorophenol: Competition between Additives and Photolysis. Nanomaterials. 9(8):1-8. https://doi.org/10.3390/nano9081157S189

Role of molecular imaging in the management of patients affected by inflammatory bowel disease: State-of-the-art

To present the current state-of-the art of molecular imaging in the management of patients affected by inflammatory bowel disease (IBD)

Artificial intelligence for photovoltaic systems

Photovoltaic systems have gained an extraordinary popularity in the energy generation industry. Despite the benefits, photovoltaic systems still suffer from four main drawbacks, which include low conversion efficiency, intermittent power supply, high fabrication costs and the nonlinearity of the PV system output power. To overcome these issues, various optimization and control techniques have been proposed. However, many authors relied on classical techniques, which were based on intuitive, numerical or analytical methods. More efficient optimization strategies would enhance the performance of the PV systems and decrease the cost of the energy generated. In this chapter, we provide an overview of how Artificial Intelligence (AI) techniques can provide value to photovoltaic systems. Particular attention is devoted to three main areas: (1) Forecasting and modelling of meteorological data, (2) Basic modelling of solar cells and (3) Sizing of photovoltaic systems. This chapter will aim to provide a comparison between conventional techniques and the added benefits of using machine learning methods

Renewable Energy and Power Quality Journal (RE&PQJ) Smart City, Sustainable Mobility, Home-Work Mobility:Data Analysis and Actions

Abstract. The paper deals with the issue related to the homework mobility of the employees. This issue is very important because many employees have similar working hours, starting at the same hour and finishing at the same hour. The result is a significant increase of traffic congestion and pollution in these hours. Similar situation occurs for students who have to go to school or go home. The previous cases coexist very often and are related each other. The aim of this paper is to present the results of a survey about the home-work mobility of the municipality employees of three medium cities located in the South of Italy. It results that the car is the privileged vehicle for the home-work transfer, independently from the costs of the transfer and from the time needed to reach the nearest stop of public transport vehicle. In a relevant number of cases the car is also the essential vehicle, because of intermediate mandatory stops or to the need to limit the transfer time. In these cases, the use of an electrical car could be an effective solution to join the need to use a car with the need to limit the pollution

La mobilità del consumatore tra formati distributivi nel settore dell’abbigliamento: un’indagine empirica.

Lo studio indaga la mobilità del consumatore tra formati distributivi con riferimento all’acquisto di prodotti di abbigliamento. L’obiettivo è di mettere in relazione il numero di formati frequentati con un insieme di caratteristiche riferite al consumatore. I risultati di un’indagine condotta su un campione di 951 consumatori indicano che solo alcune caratteristiche della domanda impattano sui modelli di frequentazione dei punti vendita. Tra le caratteristiche socio-demografiche, solo lo stato occupazionale influenza significativamente il numero di formati frequentati. Inoltre, la tipologia di formato preferito e la propensione al risparmio risultano essere importanti ai fini della mobilità. Le implicazioni manageriali sono discusse con indicazioni per la ricerca futura