Fractal Dimensions of Confined Clusters in Two-Dimensional Directed Percolation

The fractal structure of directed percolation clusters, grown at the percolation threshold inside parabolic-like systems, is studied in two dimensions via Monte Carlo simulations. With a free surface at y=\pm Cx^k and a dynamical exponent z, the surface shape is a relevant perturbation when k<1/z and the fractal dimensions of the anisotropic clusters vary continuously with k. Analytic expressions for these variations are obtained using a blob picture approach.Comment: 6 pages, Plain TeX file, epsf, 3 postscript-figure

About the screening of the charge of a proton migrating in a metal

The amount of screening of a proton in a metal, migrating under the influence of an applied electric field, is calculated using different theoretical formulations. First the lowest order screening expression derived by Sham (1975) is evaluated. In addition 'exact' expressions are evaluated which were derived according to different approaches. For a proton in a metal modeled as a jellium the screening appears to be 15 +/- 10 %, which is neither negligible not reconcilable with the controversial full-screening point of view of Bosvieux and Friedel (1962). In reconsidering the theory of electromigration, a new simplified linear-response expression for the driving force is shown to lead to essentially the same result as found by Sorbello (1985), who has used a rather complicated technique. The expressions allow for a reduction such that only the scattering phase shifts of the migrating impurity are required. Finally it is shown that the starting formula for the driving force of Bosvieux and Friedel leads exactly to the zero-temperature limit of well-established linear response descriptions, by which the sting of the controversy has been removed.Comment: 14 pages, 5 figure

Surface Shape and Local Critical Behaviour in Two-Dimensional Directed Percolation

Two-dimensional directed site percolation is studied in systems directed along the x-axis and limited by a free surface at y=\pm Cx^k. Scaling considerations show that the surface is a relevant perturbation to the local critical behaviour when k<1/z where z=\nu_\parallel/\nu is the dynamical exponent. The tip-to-bulk order parameter correlation function is calculated in the mean-field approximation. The tip percolation probability and the fractal dimensions of critical clusters are obtained through Monte-Carlo simulations. The tip order parameter has a nonuniversal, C-dependent, scaling dimension in the marginal case, k=1/z, and displays a stretched exponential behaviour when the perturbation is relevant. The k-dependence of the fractal dimensions in the relevant case is in agreement with the results of a blob picture approach.Comment: 13 pages, Plain TeX file, epsf, 6 postscript-figures, minor correction

Critical behaviour near multiple junctions and dirty surfaces in the two-dimensional Ising model

We consider m two-dimensional semi-infinite planes of Ising spins joined together through surface spins and study the critical behaviour near to the junction. The m=0 limit of the model - according to the replica trick - corresponds to the semi-infinite Ising model in the presence of a random surface field (RSFI). Using conformal mapping, second-order perturbation expansion around the weakly- and strongly-coupled planes limits and differential renormalization group, we show that the surface critical behaviour of the RSFI model is described by Ising critical exponents with logarithmic corrections to scaling, while at multiple junctions (m>2) the transition is first order. There is a spontaneous junction magnetization at the bulk critical point.Comment: Old paper, for archiving. 6 pages, 1 figure, IOP macro, eps

Nonequilibrium critical dynamics of the two-dimensional Ising model quenched from a correlated initial state

The universality class, even the order of the transition, of the two-dimensional Ising model depends on the range and the symmetry of the interactions (Onsager model, Baxter-Wu model, Turban model, etc.), but the critical temperature is generally the same due to self-duality. Here we consider a sudden change in the form of the interaction and study the nonequilibrium critical dynamical properties of the nearest-neighbor model. The relaxation of the magnetization and the decay of the autocorrelation function are found to display a power law behavior with characteristic exponents that depend on the universality class of the initial state.Comment: 6 pages, 5 figures, submitted to Phys. Rev.

Quantum first order phase transitions

The scaling theory of critical phenomena has been successfully extended for classical first order transitions even though the correlation length does not diverge in these transitions. In this paper we apply the scaling ideas to quantum first order transitions. The usefulness of this approach is illustrated treating the problems of a superconductor coupled to a gauge field and of a biquadratic Heisenberg chain, at zero temperature. In both cases there is a latent energy associated with their discontinuous quantum transitions. We discuss the effects of disorder and give a general criterion for it's relevance in these transitions.Comment: 6 pages, 2 figures, misprints corrected and a reference added. Version published in PHYSICA

Anomalous Diffusion in Aperiodic Environments

We study the Brownian motion of a classical particle in one-dimensional inhomogeneous environments where the transition probabilities follow quasiperiodic or aperiodic distributions. Exploiting an exact correspondence with the transverse-field Ising model with inhomogeneous couplings we obtain many new analytical results for the random walk problem. In the absence of global bias the qualitative behavior of the diffusive motion of the particle and the corresponding persistence probability strongly depend on the fluctuation properties of the environment. In environments with bounded fluctuations the particle shows normal diffusive motion and the diffusion constant is simply related to the persistence probability. On the other hand in a medium with unbounded fluctuations the diffusion is ultra-slow, the displacement of the particle grows on logarithmic time scales. For the borderline situation with marginal fluctuations both the diffusion exponent and the persistence exponent are continuously varying functions of the aperiodicity. Extensions of the results to disordered media and to higher dimensions are also discussed.Comment: 11 pages, RevTe

Anisotropic Scaling in Layered Aperiodic Ising Systems

The influence of a layered aperiodic modulation of the couplings on the critical behaviour of the two-dimensional Ising model is studied in the case of marginal perturbations. The aperiodicity is found to induce anisotropic scaling. The anisotropy exponent z, given by the sum of the surface magnetization scaling dimensions, depends continuously on the modulation amplitude. Thus these systems are scale invariant but not conformally invariant at the critical point.Comment: 7 pages, 2 eps-figures, Plain TeX and epsf, minor correction

Tuning the role of charge-transfer states in intramolecular singlet exciton fission through side-group engineering

Understanding the mechanism of singlet exciton fission, in which a singlet exciton separates into a pair of triplet excitons, is crucial to the development of new chromophores for efficient fission-sensitized solar cells. The challenge of controlling molecular packing and energy levels in the solid state precludes clear determination of the singlet fission pathway. Here, we circumvent this difficulty by utilizing covalent dimers of pentacene with two types of side groups. We report rapid and efficient intramolecular singlet fission in both molecules, in one case via a virtual charge-transfer state and in the other via a distinct charge-transfer intermediate. The singlet fission pathway is governed by the energy gap between singlet and charge-transfer states, which change dynamically with molecular geometry but are primarily set by the side group. These results clearly establish the role of charge-transfer states in singlet fission and highlight the importance of solubilizing groups to optimize excited-state photophysics.S.L. thanks AGS(O) Scholarship support from A*STAR Singapore. J.W. acknowledges financial support from MOE Tier 3 grant (MOE2014-T3-1-004). This work was supported by the Engineering and Physical Sciences Research Council, U.K. (Grant numbers EP/M005143/1 and EP/G060738/1). D.H.P.T. and N.D.M.H. acknowledge the Winton Programme for the Physics of Sustainability. K.C. and J.M.H. acknowledge support from a Rutherford Discovery Fellowship to J.M.H